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Title:
【発明の名称】重合触媒
Document Type and Number:
Japanese Patent JP2002528573
Kind Code:
A
Abstract:
The present invention relates to a process for the polymerization and copolymerization of 1-olefins and to a catalyst to be used in said process wherein the catalyst comprises (1) a complex having formula (I) wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the metal M; T is the oxidation state of the metal; b is the valency of the atom or group X; and R 1 to R 7 are each independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl, substituted heterohydrocarbyl or SiR' 3 where each R' is independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl, substituted heterohydrocarbyl; and when any two or more of R 1 to R 7 are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; (2) an activator which is an alkylalumoxane; and (3) a support material, wherein the atomic ratio of aluminium in the alkylalumoxane (2) to transition metal M in (1) is from 6:1 to 25:1.

Inventors:
Belaldi, Alan
Speakman, John, Gabriel
Application Number:
JP2000578357A
Publication Date:
September 03, 2002
Filing Date:
October 21, 1999
Export Citation:
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Assignee:
BP Chemicals Limited
International Classes:
C08F4/70; C08F10/00; C08F4/60; C08F110/02; (IPC1-7): C08F4/60; C08F10/00
Domestic Patent References:
JP2000516295A2000-12-05
JP2001508107A2001-06-19
JP2001515930A2001-09-25
JPH09505848A1997-06-10
Attorney, Agent or Firm:
Haruo Hamada