Title:
ポリマーの製造方法
Document Type and Number:
Japanese Patent JP5182439
Kind Code:
B1
Abstract:
PROBLEM TO BE SOLVED: To solve a problem in which a long time is required to a polymerization reaction when a ring-opening polymerization monomer of lactide or the like is polymerized by using an organic catalyst such as 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) that does not contain a metal atom as a catalyst by using a compressible fluid such as supercritical carbon dioxide as a solvent.SOLUTION: A method of manufacturing a polymer includes a polymerization process in which a ring-opening polymerizable monomer and a compressible fluid at least are continuously contacted, and the ring-opening polymerizable monomer is performed by ring-opening polymerization under the existence of an organic catalyst that does not contain a metal atom. Thereby, there is an effect in which a required time for a polymerization reaction can be shortened comparing with a case in which a ring-opening polymerizable monomer is performed by ring-opening polymerization without using a metal catalyst by a past manufacturing method.
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Inventors:
Taichi Nemoto
Chiaki Tanaka
Yoshitaka Yamauchi
Chiaki Tanaka
Yoshitaka Yamauchi
Application Number:
JP2012065605A
Publication Date:
April 17, 2013
Filing Date:
March 22, 2012
Export Citation:
Assignee:
株式会社リコー
International Classes:
C08G63/78
Domestic Patent References:
| JP2004277698A | 2004-10-07 | |||
| JP2004277698A | 2004-10-07 |
Other References:
JPN6012023371; Ｉｄｒｉｓｓ Ｂｌａｋｅｙ: 'Ｃｏｎｔｒｏｌｌｅｄ ｐｏｌｙｍｅｒｉｓａｔｉｏｎ ｏｆ ｌａｃｔｉｄｅ ｕｓｉｎｇ ａｎ ｏｒｇａｎｏ-ｃａｔａｌｙｓｔ ｉｎ ｓｕｐｅｒｃｒｉｔｉｃａｌ ｃａｒｂｏｎ ｄｉｏｘｉｄｅ' Ｇｒｅｅｎ Ｃｈｅｍｉｓｔｒｙ １３, 2011, ２０３２-２０３７
JPN6012023371; Ｉｄｒｉｓｓ Ｂｌａｋｅｙ: 'Ｃｏｎｔｒｏｌｌｅｄ ｐｏｌｙｍｅｒｉｓａｔｉｏｎ ｏｆ ｌａｃｔｉｄｅ ｕｓｉｎｇ ａｎ ｏｒｇａｎｏ-ｃａｔａｌｙｓｔ ｉｎ ｓｕｐｅｒｃｒｉｔｉｃａｌ ｃａｒｂｏｎ ｄｉｏｘｉｄｅ' Ｇｒｅｅｎ Ｃｈｅｍｉｓｔｒｙ １３, 2011, ２０３２-２０３７
JPN6012023371; Ｉｄｒｉｓｓ Ｂｌａｋｅｙ: 'Ｃｏｎｔｒｏｌｌｅｄ ｐｏｌｙｍｅｒｉｓａｔｉｏｎ ｏｆ ｌａｃｔｉｄｅ ｕｓｉｎｇ ａｎ ｏｒｇａｎｏ-ｃａｔａｌｙｓｔ ｉｎ ｓｕｐｅｒｃｒｉｔｉｃａｌ ｃａｒｂｏｎ ｄｉｏｘｉｄｅ' Ｇｒｅｅｎ Ｃｈｅｍｉｓｔｒｙ １３, 2011, ２０３２-２０３７