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Title:
芳香族化合物の製造方法
Document Type and Number:
Japanese Patent JP5305303
Kind Code:
B2
Abstract:
A problem of the present invention is to provide an economical process with minimized toxicity for producing an aromatic compound having a variety of substituents such as various alkyl groups, and the problem is solved by a process for production of an aromatic compound represented by formula (1) below, which comprises reacting a compound represented by formula (2) below with an aromatic magnesium reagent represented by formula (3a) below in the presence of an iron catalyst and a diamine compound: wherein R is an optionally substituted hydrocarbon group or a C 3 - C 10 saturated or unsaturated ring group; A is an optionally substituted C 4 - C 20 aromatic group or an optionally substituted heteroaromatic group; X is a halogen atom or a sulfonic acid ester; and Y 1 is bromine, iodine, chlorine or a carbanion ligand.

Inventors:
Masaharu Nakamura
Eiichi Nakamura
Keiko Matsuo
Shinko Ito
Application Number:
JP2010164070A
Publication Date:
October 02, 2013
Filing Date:
July 21, 2010
Export Citation:
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Assignee:
Japan Science and Technology Agency
International Classes:
C07C1/32; B01J27/128; B01J31/20; B01J31/22; C07B37/04; C07B49/00; C07C13/28; C07C41/30; C07C43/21; C07C67/293; C07C67/343; C07C69/03; C07C69/157; C07C69/612; C07C69/76; C07C253/30; C07C255/37; C07C255/41; C07C255/50; C07D209/08; C07D211/16; C07D211/34; C07D213/16; C07D307/20; C07D407/06; C07F7/08; C07H7/06; C07H17/04; C07J9/00; C07B61/00
Domestic Patent References:
JP2000229243A
Foreign References:
US20030220498
Other References:
Masaharu NAKAMURA et al.,Journal of the American Chemical Society,2004年,126,pp.3686-3687
Attorney, Agent or Firm:
Hiroshi Kobayashi
Eiji Katayama
Yoshimitsu Maki
Yasuhito Suzuki