Title:
触媒組成物及びこれを使用する、芳香族炭化水素をアルコール又はアルコールとオレフィンとの混合物でアルキル化するための方法
Document Type and Number:
Japanese Patent JP6488289
Kind Code:
B2
Abstract:
The invention relates to a new catalytic composition for the alkylation of aromatic compounds with alcohols, or mixtures of alcohols and corresponding olefins, wherein said composition comprises a zeolite of the MTW type and is characterized in that it contains one or more alkaline metals in a total quantity which is less than or equal to 0.02% by weight. The use of said catalyst in the alkylation of aromatic compounds with alcohols, in particular benzene with isopropanol or ethanol, allows the formation, as by-product, of the aldehyde or ketone corresponding to the alcohol used, to be minimized: the formation of reaction by-products of said aldehydes or ketones having a boiling point very close to that of polyalkylation products, is therefore significantly reduced. This provides a considerable advantage in the subsequent transalkylation step for the recovery of said polyalkylates by transformation into the corresponding monoalkylates.
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Inventors:
Bencini Elena
Fois Giovanni Antonio
Butuzzoni roberto
Fois Giovanni Antonio
Butuzzoni roberto
Application Number:
JP2016521779A
Publication Date:
March 20, 2019
Filing Date:
October 14, 2014
Export Citation:
Assignee:
Versalis Societa Peratini
International Classes:
B01J29/70; B01J35/02; B01J35/10; C07C2/86; C07C15/085
Domestic Patent References:
| JP2007534578A | ||||
| JP2002102714A | ||||
| JP2009090285A |
Attorney, Agent or Firm:
Takaki Nishijima
Disciple Maru Ken
Shinichiro Tanaka
Atsushi Hakoda
Kenji Asai
Kazuo Yamazaki
Satsuki Ichikawa
Hironobu Hattori
Disciple Maru Ken
Shinichiro Tanaka
Atsushi Hakoda
Kenji Asai
Kazuo Yamazaki
Satsuki Ichikawa
Hironobu Hattori