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Title:
ハロゲン化メタロセン化合物の製造方法
Document Type and Number:
Japanese Patent JP2006525264
Kind Code:
A
Abstract:
Process for preparing halide metallocene compounds comprising the step of reacting the dialkyl derivative with a halogenating agent of formula R3xTLw wherein: L is chlorine, iodine or bromine; R3 is hydrogen or a hydrocarbon group; T is a metal of groups 2-14 of the periodic table of the elements; and x is >=1 so that x+w is equal to the oxidation state of the metal T.

Inventors:
Guide stitch, Simona
Barboni, David
Application Number:
JP2006505316A
Publication Date:
November 09, 2006
Filing Date:
April 29, 2004
Export Citation:
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Assignee:
BASELL POLYOLEFINE GMBH
International Classes:
C07F17/00; C07F7/00
Domestic Patent References:
JPH09509149A1997-09-16
Foreign References:
WO2002083699A22002-10-24
Other References:
JPN6009041157, Colin L. Beswick and Tobin J. Marks, "Metal−Alkyl Group Effects on the Thermodynamic Stability and Stereochemical Mobility of B(C6F5)3−Der", Journal of the American Chemical Society, 2000, Vol.122, No.42, p.10358−10370
JPN6009041154, Joon T. Park et al., "An efficient synthetic method of ansa−zirconocene dimethyl complexes via Me2ZrCl2", Journal of Organometallic Chemistry, 1997, Vol.535, No.1−2, p.29−32
JPN6009041151, Markus Ringwald et al., "Asymmetric Thermal Transformation, a New Way to Enantiopure Biphenyl−Bridged Titanocene and Zirconoc", Journal of the American Chemical Society, 1999, Vol.121, No.7, p.1524−1527
JPN6009041150, Robert Choukroun et al., "Substituted Cyclopentadienyl Phosphinomethyl Complexes of Zirconium. Synthesis, Chemical Characteris", Organometallics, 1990, Vol.9, No.6, p.1982−1987
Attorney, Agent or Firm:
Shintaro Nogawa