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Title:
METHOD FOR PREPARING 2-NAPHTHOL DERIVATIVE
Document Type and Number:
Japanese Patent JP2005097189
Kind Code:
A
Abstract:

To provide a simple and inexpensive method for preparing a 2-naphthol derivative without using a fluorination agent which previously required a long reaction step in its preparation and the use of the expensive fluorination agent multi-times.

The method for preparing a 2-naphthol derivative represented by formula (2) comprises reacting a phenylacetic acid halide derivative represented by formula (1) with acetylene in the present of a Lewis acid. Specifically, for example, the reaction of formula (3) can be illustrated. The 2-naphthol derivative is useful as a production intermediate of fluorine substituted naphthalene derivatives useful as liquid crystal materials.


Inventors:
MATSUMOTO TAKASHI
KUSUMOTO TETSUO
Application Number:
JP2003333450A
Publication Date:
April 14, 2005
Filing Date:
September 25, 2003
Export Citation:
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Assignee:
DAINIPPON INK & CHEMICALS
International Classes:
C07C37/14; C07B61/00; C07C39/38; (IPC1-7): C07C37/14; C07C39/38
Domestic Patent References:
JP2001010995A2001-01-16
JP2001010995A2001-01-16
Other References:
JPN6009022515, Haack,R.A., "SYNTHESIS OF SUBSTITUTED SPIRO[4.5]DECA−3,6,9−TRIENE−2,8−DIONES: AN EXPEDITIOUS ROUTE TO THE SPIRO[4", Tetrahedron Letters, 1989, Vol.30, No.13, p.1605−1608
Attorney, Agent or Firm:
Takahashi victory