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Title:
METHOD FOR PRODUCING CONJUGATE UNSATURATED CARBONYL COMPOUND
Document Type and Number:
Japanese Patent JP2001354611
Kind Code:
A
Abstract:

To produce a conjugate unsaturated carbonyl compound under a mild condition in good production efficiency.

This method for producing the conjugate unsaturated carbonyl compound comprises reacting an unsaturated compound having a methylene group at the vicinal position of a carbon-carbon double bond with oxygen in the presence of a catalyst constituted of an imide compound represented by formula (1), wherein, R1 and R2 are each a hydrogen atom, a halogen atom, an alkyl group, an aryl group or the like, and can form a double bond or an aromatic or nonaromatic ring by binding to each other; X is an oxygen atom or a hydroxyl group and a cobalt (II) salt of an acid having pKa ≥8.0 to provide the objective corresponding conjugate unsaturated carbonyl compound having an oxo group introduced to the carbon atom of the methylene group. For example, a monocyclic or polycyclic compound having the carbon-carbon double bond in the ring can be used as the unsaturated compound having the methylene group at the vicinity position of the carbon-carbon double bond.


Inventors:
KITAYAMA KENJI
Application Number:
JP2000176494A
Publication Date:
December 25, 2001
Filing Date:
June 13, 2000
Export Citation:
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Assignee:
DAICEL CHEM
International Classes:
C07D207/416; B01J31/22; C07B61/00; C07C45/33; C07C49/653; C07D209/48; (IPC1-7): C07C49/653; B01J31/22; C07B61/00; C07C45/33; C07D207/416
Domestic Patent References:
JPH09327626A1997-12-22
JPH0216739B21990-04-18
Attorney, Agent or Firm:
Yukihisa Goto



 
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