Title:
METHOD FOR SYNTHESIZING HOMOALLYL ALCOHOL
Document Type and Number:
Japanese Patent JP2004331559
Kind Code:
A
Abstract:
To provide a method for synthesizing a homoallyl alcohol by a one-stage reaction in a high yield.
The method for synthesizing the homoallyl alcohol represented by general formula (2) (R1 and R2 each may be the same or different and are each a substituted or nonsubstituted 6-10C aryl group; the aryl group may be substituted with a 1-6C alkyl group, a 1-6C alkoxy group or a halogen atom) comprises reacting an alkylidene cyclopropane represented by general formula (1) with water in the presence of Cu(OTf)2 in an inert gas atmosphere at 70-90 °C in a liquid state for 3-4 days.
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Inventors:
YAMAMOTO YOSHINORI
NAKAMURA TATSU
AMAL SIRIWARDANA
NAKAMURA TATSU
AMAL SIRIWARDANA
Application Number:
JP2003129067A
Publication Date:
November 25, 2004
Filing Date:
May 07, 2003
Export Citation:
Assignee:
JAPAN SCIENCE & TECH AGENCY
International Classes:
C07C29/48; C07B61/00; C07C33/025; C07C41/26; C07C43/23; (IPC1-7): C07C29/48; C07C33/025; C07C41/26; C07C43/23
Attorney, Agent or Firm:
Takehiko Suzue
Satoshi Kono
Makoto Nakamura
Kurata Masatoshi
Takashi Mine
Yoshihiro Fukuhara
Sadao Muramatsu
Ryo Hashimoto
Satoshi Kono
Makoto Nakamura
Kurata Masatoshi
Takashi Mine
Yoshihiro Fukuhara
Sadao Muramatsu
Ryo Hashimoto