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Title:
NEW BENZENE DERIVATIVE AND INSECTICIDE
Document Type and Number:
Japanese Patent JP3710506
Kind Code:
B2
Abstract:

PURPOSE: To obtain a new benzene derivative having an extremely strong insecticidal activity against Hemiptera insect pests such as Nilaparvata lugens or Nephotettix cincticeps and useful for insecticides.
CONSTITUTION: The benzene derivative of formula I (R1 is H, amino, cyano, hydroxymethyl, etc.; R2 is 3,3-dimethylbuty, 3,3-dimethyl-1-butenyl, 3,3-dimethyl-1- butynyl, etc.; X is H, F, but X and R1 are simultaneously not H). For example, 5-(3,3-dimethylbutyl)-2-fluorovenzonitrile. The compound of formula I is obtained e.g. by reacting a compound of formula II (R5 is cyano, etc.; Z is halogen) with neopentylmagnesium bromide at an arbitrary temperature of -75°C to the refluxing temperature with stirring, and subsequently hydrolyzing the obtained compound of formula III.


Inventors:
Keiji Toriyabe
Tomomi Usami
Takayoshi Takehi
Toshihiro Nagata
Yuki Nakano
Ryo Kudo
Hiroshi Kurihara
Application Number:
JP30570694A
Publication Date:
October 26, 2005
Filing Date:
November 16, 1994
Export Citation:
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Assignee:
Kumiai Chemical Industry Co., Ltd.
Ihara Chemical Industry Co., Ltd.
International Classes:
C07C25/13; A01N31/04; A01N33/06; A01N35/04; A01N35/08; A01N37/10; A01N37/18; A01N37/34; A01N37/52; C07C25/24; C07C33/22; C07C33/46; C07C47/542; C07C47/548; C07C63/04; C07C63/64; C07C63/74; C07C69/76; C07C211/45; C07C211/52; C07C255/50; C07C259/18; (IPC1-7): C07C33/22; A01N31/04; A01N37/10; A01N37/34; A01N37/52; C07C33/46; C07C63/04; C07C63/64; C07C63/74; C07C69/76; C07C255/50; C07C259/18
Domestic Patent References:
JP641086A
Attorney, Agent or Firm:
Akira Inoue