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Title:
OPTICAL ANALYSIS REAGENT INCLUDING FLUORINE
Document Type and Number:
Japanese Patent JPS6058538
Kind Code:
A
Abstract:

PURPOSE: To provide an optical analysis function such as sufficient shifting action even on a sample having unsaturated bonding, by forming an optical analysis reagent including fluorine by a lanthanide chelate compound of fluoro-β- diketone and a metal salt of fatty acid.

CONSTITUTION: A compound, wherein chiral carbon C is present as shown in a general formula, such as fluoro-β-diketone, is effective in forming a shifting reagent comprising lanthanide chelate such as europium chelate. Namely, owing to fluorine atoms, the shifting effect is excellent, overlap with the signal of a substrate is less, solubility for a solvent is increased, and the shifting reagent is stabilized by a cubic effect. A metal salt of fatty acid, which is expressed by a general formula (R"fCOO)nM is used together with a chelate. The metal salt effectively yields a relative action between an unsaturated compound such as olefin and the chelate through the metal element, and a composite compound is formed. This compound provides the shift of NMR spectrum.


Inventors:
ISHIKAWA NOBUO
Application Number:
JP16718283A
Publication Date:
April 04, 1985
Filing Date:
September 09, 1983
Export Citation:
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Assignee:
DAIKIN IND LTD
International Classes:
C07C45/00; C07C49/92; C07C67/00; C07F5/00; G01R33/28; (IPC1-7): C07C49/92; C07F5/00; G01N24/02
Attorney, Agent or Firm:
Hiroshi Osaka



 
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