PERFLUOROALKYLATION OF NUCLEOPHILIC SUBSTRATE

Title:

PERFLUOROALKYLATION OF NUCLEOPHILIC SUBSTRATE

Document Type and Number:

Japanese Patent JPH09263548

Kind Code:

A

Abstract:

To provide a method for perfluoroalkylating a nucleophilic substrate, especially a mono/polyperfluoroalkylating a compound having many electrons by a perfluoroalkane sulfinic acid in an oxidizing medium under a moderate condition.

This method for perfluoroalkylating a nucleophilic substrate comprises the steps of bringing the substrate into contact with a reagent of either (1) or (2). (1) A perfluoroalkylating reagent containing (a) a perfluoroalkane sulfinic acid ion and (b) an oxidizing agent consisting of a hydroxy radical generated from a Fenton's reagent. (2) A perfluoroalkylating reagent containing (a) a perfluoroalkane sulfinic acid ion, (b) an oxidizing agent consisting of a persulfuric acid salt, a hydroperoxide or a cerium nitrate (IV) ammonium complex salt and (c) a catalyst consisting of iron (II), MoO2(acac)2, Mo(CO)6, VO(acac)2, OsO4 or SeO2.

Inventors:

JIYANNRUISU KUREBEERU
BERUNAADO RANGUROWA
ERIAN ROOREN
NAZARII ROIDO

Application Number:

JP2822296A

Publication Date:

October 07, 1997

Filing Date:

February 15, 1996

Export Citation:

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Assignee:

RHONE POULENC CHIMIE

International Classes:

B01J23/46; B01J23/745; B01J27/057; B01J31/02; B01J31/20; C07B37/04; C07B45/06; C07B61/00; C07C37/11; C07C37/62; C07C39/24; C07C41/30; C07C43/225; C07C45/41; C07C45/54; C07C45/68; C07C49/167; C07C67/343; C07C209/74; C07C231/12; C07C319/14; C07C319/20; C07C323/03; C07C323/04; C07C323/52; C07D207/32; C07D231/44; C07D309/36; C07D309/38; (IPC1-7): C07B37/04; B01J23/46; B01J23/745; B01J27/057; B01J31/02; B01J31/20; C07C319/14; C07C323/03; C07C323/04; C07C323/52; C07D231/44; C07D309/38

Attorney, Agent or Firm:

Takashi Ishida (3 others)

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