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Title:
ヘキサフルオロプロピレンオキシドの重合
Document Type and Number:
Japanese Patent JP5774470
Kind Code:
B2
Abstract:
Process for the oligomerization of hexafluoropropylene oxide (HFPO) in which the sum of the dimers, trimers, tetramers, pentamers and hexamers represents less than 20% of the weight of the polymerized HFPO, the oligomers other than the dimers, trimers, tetramers, pentamers and hexamers (the remaining oligomers) having an average molecular weight ranging between 1100 and 4000 g/mol, characterized in that the process comprises the steps of contacting hexafluoropropylene oxide (HFPO) at a temperature between -30° C. to +50° C. with a catalyst system selected from potassium fluoride and di-, tri- or tetraethyleneglycol-dimethylether in the presence of a solvent which is selected from perfluorinated aliphatic or aromatic hydrocarbon with more than 3 and less than 12 C-atoms and optionally a polar group but not comprising chlorine or bromine partially fluorinated aliphatic or aromatic hydrocarbon with more than 3 and less than 12 C-atoms and optionally a polar group but not comprising chlorine or bromine at a pressure of less than 3 bars by controlled monomer addition continuous feeding or by adding the monomer in one or two portions (shots).

Inventors:
Dannes Bernard
Application Number:
JP2011501223A
Publication Date:
September 09, 2015
Filing Date:
March 25, 2009
Export Citation:
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Assignee:
Clariant Finance (BV) Limited
International Classes:
C08G65/22
Domestic Patent References:
JP60156726A
JP10101788A
JP2008531815A
JP2097526A
Foreign References:
WO2006093885A1
Attorney, Agent or Firm:
Mitsufumi Esaki
Blacksmith
Katsunori Uenishi
Ichiro Torayama