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Patent Searching and Data


Title:
SILACYCLOHEXANE COMPOUND, PRODUCTION THEREOF AND LIQUID CRYSTAL COMPOSITION CONTAINING THE SAME
Document Type and Number:
Japanese Patent JPH07324089
Kind Code:
A
Abstract:

PURPOSE: To obtain a new compound, having a high nematic-isotropic transition temperature and a great refractive index anisotropy and effectively usable as an on-vehicle liquid crystal panel composition, etc.

CONSTITUTION: This compound of formula I [R is a 1-10C linear alkyl or a 1-10C fluoroalkyl in which 1 or 2 H atoms thereof are substituted with F, a 3-8C branched chain alkyl, etc.; formula II is trans-1(or 4)-sila-1,4-cyclohexylene in which Si at the 1- or the 4-position has a substituent group of H, F, Cl or CH3; L1 and L2 are each H or F; L3 and L4 are each H, F or Cl; (n) is 0, 1 or 2; X is H, CN, F, etc.], e.g. 4-(trans-4-n-pentyl-4-silacyclohexyl)-4"- fluoroterphenyl. The compound is obtained by carrying out the reaction for forming C-Si bond including reaction for removing MQ of an oreganometallic reagent of the formula R-M [M is MgP (P is a halogen), ZnP or Li] with a silacyclohexane compound of formula III (W is H, F, Cl or CH3; Q is a halogen or an alkoxy).


Inventors:
SHIMIZU TAKAAKI
KANOU TAKESHI
OGIWARA TSUTOMU
KANEKO TATSUSHI
NAKAJIMA MUTSUO
KURIHARA HIDESHI
Application Number:
JP10169895A
Publication Date:
December 12, 1995
Filing Date:
April 03, 1995
Export Citation:
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Assignee:
SHINETSU CHEMICAL CO
International Classes:
C07F7/12; C09K19/40; G02F1/13; (IPC1-7): C07F7/12; C09K19/40; G02F1/13
Attorney, Agent or Firm:
High Toshihiko No (1 person outside)