Title:
スピロケタール化合物、アルキンジオール化合物及びこのアルキンジオール化合物を用いたスピロケタール化合物の製造法
Document Type and Number:
Japanese Patent JP4662094
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide an optimum monomer capable of producing a polymer expressing a small volume change through polymerization and having hydrolysis resistance, to provide a raw material for the monomer, a method for producing the material and a composition by using the monomer. SOLUTION: This spiroketal compound is expressed by general formula (I) (wherein Ar expresses a substituted or nonsubstituted 6-20C aryl). Alkynediol is expressed by general formula (V) (wherein Ar expresses a substituted or nonsubstituted 6-20C aryl). The method for producing the spiroketal compound is to doubly cyclize the alkynediol compound. The objective composition contains the spirolketal compound.
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Inventors:
Iwao Fukuchi
Takeshi Endo
Fumio Mita
Takeshi Endo
Fumio Mita
Application Number:
JP2000324857A
Publication Date:
March 30, 2011
Filing Date:
October 25, 2000
Export Citation:
Assignee:
Hitachi Chemical Co., Ltd.
International Classes:
C07D303/14; C07D493/10; C07C33/30; C07C33/48; C08K5/151; C08K5/1535; C08L63/00
Domestic Patent References:
| JP2002121275A |
Other References:
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TAKANO,S. et al,Enantiocontrolled approach to natural products utilizing (S)-O-benzylglycidol as a common chiral precursor,Heterocycles,1989年,Vol.29, No.3,pp.445-448
OCCHIATO,E.G. et al,Synthesis of enantiopure 2,7-diaryl-1,6-dioxaspiro[4.4]nonanes via enantioselective reduction of prochiral γ-nitro ketones by diisopinocampheylchloroborane (DIP-Cl),Tetrahedron: Asymmetry,1996年,Vol.7, No.7,pp.1929-1942
DANISHEFSKY,S.J. et al,A new strategy for the synthesis of spiro ketals,Journal of Organic Chemistry,1983年,Vol.48, No.21,pp.3865-3866
BALLINI,R. et al,New and efficient synthesis of ω-nitro alcohols and spiroketals by chemo- and regioselective reductive cleavage of 2-nitro cycloalkanones,Tetrahedron,1990年,Vol.46, No.21,pp.7531-7538
TAKANO,S. et al,Enantiocontrolled approach to natural products utilizing (S)-O-benzylglycidol as a common chiral precursor,Heterocycles,1989年,Vol.29, No.3,pp.445-448
OCCHIATO,E.G. et al,Synthesis of enantiopure 2,7-diaryl-1,6-dioxaspiro[4.4]nonanes via enantioselective reduction of prochiral γ-nitro ketones by diisopinocampheylchloroborane (DIP-Cl),Tetrahedron: Asymmetry,1996年,Vol.7, No.7,pp.1929-1942
DANISHEFSKY,S.J. et al,A new strategy for the synthesis of spiro ketals,Journal of Organic Chemistry,1983年,Vol.48, No.21,pp.3865-3866