Title:
AMORPHOUS TRIBOLUMINESCENT MATERIAL, METHOD FOR PRODUCING THE SAME, METHOD FOR GENERATING LIGHT EMISSION IN AMORPHOUS TRIBOLUMINESCENT LAYER, AND MECHANORESPONSIVE SENSOR
Document Type and Number:
WIPO Patent Application WO/2023/032921
Kind Code:
A1
Abstract:
Triboluminescent materials that produce light emission in response to mechanical action attract significant interest due to their wide range of potential utilization for mechanoresponsive sensors, light emitting devices and stimuli-induced glowing fibers, dyes, particles, paste, and films, etc. Here, we would like to disclose a general method of generating triboluminescent polymer materials blended with wide range of luminophores that emit light in response to mechanical action emitting light in a wide range of spectrum. The light generation is achieved via a non-destructive method even in the absence of direct contact with the polymer (e.g. through the layer of another polymer). Biocompatible luminophores can be easily utilized. Light emission is also observed under dry air.
Inventors:
KARIMATA AYUMU (JP)
KHUSNUTDINOVA JULIA (JP)
KHUSNUTDINOVA JULIA (JP)
Application Number:
PCT/JP2022/032429
Publication Date:
March 09, 2023
Filing Date:
August 29, 2022
Export Citation:
Assignee:
OKINAWA INST SCIENCE & TECH SCHOOL CORP (JP)
International Classes:
C09K11/02; C09K11/00; C09K11/06
Domestic Patent References:
| WO2015053326A1 | 2015-04-16 |
Foreign References:
| CN111628087A | 2020-09-04 | |||
| JPH10130639A | 1998-05-19 |
Other References:
İNCEL ANIL, EMIRDAG-EANES MEHTAP, MCMILLEN COLIN D., DEMIR MUSTAFA M.: "Integration of Triboluminescent EuD 4 TEA Crystals to Transparent Polymers: Impact Sensor Application", APPLIED MATERIALS & INTERFACES, AMERICAN CHEMICAL SOCIETY, US, vol. 9, no. 7, 22 February 2017 (2017-02-22), US , pages 6488 - 6496, XP093042377, ISSN: 1944-8244, DOI: 10.1021/acsami.6b16330
HASEGAWA YASUCHIKA: "Photofunctional Lanthanoid Complexes, Coordination Polymers, and Nanocrystals for Future Photonic Applications", BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, CHEMICAL SOCIETY OF JAPAN,NIPPON KAGAKUKAI, JP, vol. 87, no. 10, 15 October 2014 (2014-10-15), JP , pages 1029 - 1057, XP093042378, ISSN: 0009-2673, DOI: 10.1246/bcsj.20140155
ELISEEVA SVETLANA V., PLESHKOV DMITRY N., LYSSENKO KONSTANTIN A., LEPNEV LEONID S., BÜNZLI JEAN-CLAUDE G., KUZMINA NATALIA P.: "Highly Luminescent and Triboluminescent Coordination Polymers Assembled from Lanthanide β-Diketonates and Aromatic Bidentate O -Donor Ligands", INORGANIC CHEMISTRY, AMERICAN CHEMICAL SOCIETY, EASTON , US, vol. 49, no. 20, 18 October 2010 (2010-10-18), Easton , US , pages 9300 - 9311, XP093042380, ISSN: 0020-1669, DOI: 10.1021/ic100974e
TAO PENG, LIU SHU‐JUAN, WONG WAI‐YEUNG: "Phosphorescent Manganese(II) Complexes and Their Emerging Applications", ADVANCED OPTICAL MATERIALS, WILEY, DE, vol. 8, no. 20, 1 October 2020 (2020-10-01), DE , pages 2000985, XP093042385, ISSN: 2195-1071, DOI: 10.1002/adom.202000985
GEORGE T.M., SAJAN M.J., GOPAKUMAR N., REDDY M.L.P.: "Bright red luminescence and triboluminescence from PMMA-doped polymer film materials supported by Eu 3+ -triphenylphosphine based β-diketonate and 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene oxide", JOURNAL OF PHOTOCHEMISTRY, ELSEVIER, AMSTERDAM, NL, vol. 317, 1 February 2016 (2016-02-01), AMSTERDAM, NL, pages 88 - 99, XP093042388, ISSN: 1010-6030, DOI: 10.1016/j.jphotochem.2015.11.016
FONTENOT ROSS S, HOLLERMAN WILLIAM A, BHAT KAMALA N, AGGARWAL MOHAN D, PENN BENJAMIN G: "Incorporating strongly triboluminescent europium dibenzoylmethide triethylammonium into simple polymers", POLYMER JOURNAL, NATURE PUBLISHING GROUP UK, LONDON, vol. 46, no. 2, 1 February 2014 (2014-02-01), London , pages 111 - 116, XP093042389, ISSN: 0032-3896, DOI: 10.1038/pj.2013.78
İNCEL ANIL, VARLIKLI CANAN, MCMILLEN COLIN D., DEMIR MUSTAFA M.: "Triboluminescent Electrospun Mats with Blue-Green Emission under Mechanical Force", THE JOURNAL OF PHYSICAL CHEMISTRY C, AMERICAN CHEMICAL SOCIETY, US, vol. 121, no. 21, 1 June 2017 (2017-06-01), US , pages 11709 - 11716, XP093042393, ISSN: 1932-7447, DOI: 10.1021/acs.jpcc.7b02875
KARIMATA AYUMU, PATIL PRADNYA H., FAYZULLIN ROBERT R., KHASKIN EUGENE, LAPOINTE SÉBASTIEN, KHUSNUTDINOVA JULIA R.: "Triboluminescence of a new family of Cu I –NHC complexes in crystalline solid and in amorphous polymer films", CHEMICAL SCIENCE, ROYAL SOCIETY OF CHEMISTRY, UNITED KINGDOM, vol. 11, no. 39, 14 October 2020 (2020-10-14), United Kingdom , pages 10814 - 10820, XP055887496, ISSN: 2041-6520, DOI: 10.1039/D0SC04442C
"Functional Tactile Sensors - Materials, Devices and Integrations", 1 January 2021, WOODHEAD PUBLISHING, US, ISBN: 978-0-12-820633-1, article DENGFENG PENG, SICEN QU: "6 - Mechanoluminescent materials for tactile sensors", pages: 91 - 112, XP009544187, DOI: 10.1016/B978-0-12-820633-1.00007-3
HASEGAWA YASUCHIKA: "Photofunctional Lanthanoid Complexes, Coordination Polymers, and Nanocrystals for Future Photonic Applications", BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, CHEMICAL SOCIETY OF JAPAN,NIPPON KAGAKUKAI, JP, vol. 87, no. 10, 15 October 2014 (2014-10-15), JP , pages 1029 - 1057, XP093042378, ISSN: 0009-2673, DOI: 10.1246/bcsj.20140155
ELISEEVA SVETLANA V., PLESHKOV DMITRY N., LYSSENKO KONSTANTIN A., LEPNEV LEONID S., BÜNZLI JEAN-CLAUDE G., KUZMINA NATALIA P.: "Highly Luminescent and Triboluminescent Coordination Polymers Assembled from Lanthanide β-Diketonates and Aromatic Bidentate O -Donor Ligands", INORGANIC CHEMISTRY, AMERICAN CHEMICAL SOCIETY, EASTON , US, vol. 49, no. 20, 18 October 2010 (2010-10-18), Easton , US , pages 9300 - 9311, XP093042380, ISSN: 0020-1669, DOI: 10.1021/ic100974e
TAO PENG, LIU SHU‐JUAN, WONG WAI‐YEUNG: "Phosphorescent Manganese(II) Complexes and Their Emerging Applications", ADVANCED OPTICAL MATERIALS, WILEY, DE, vol. 8, no. 20, 1 October 2020 (2020-10-01), DE , pages 2000985, XP093042385, ISSN: 2195-1071, DOI: 10.1002/adom.202000985
GEORGE T.M., SAJAN M.J., GOPAKUMAR N., REDDY M.L.P.: "Bright red luminescence and triboluminescence from PMMA-doped polymer film materials supported by Eu 3+ -triphenylphosphine based β-diketonate and 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene oxide", JOURNAL OF PHOTOCHEMISTRY, ELSEVIER, AMSTERDAM, NL, vol. 317, 1 February 2016 (2016-02-01), AMSTERDAM, NL, pages 88 - 99, XP093042388, ISSN: 1010-6030, DOI: 10.1016/j.jphotochem.2015.11.016
FONTENOT ROSS S, HOLLERMAN WILLIAM A, BHAT KAMALA N, AGGARWAL MOHAN D, PENN BENJAMIN G: "Incorporating strongly triboluminescent europium dibenzoylmethide triethylammonium into simple polymers", POLYMER JOURNAL, NATURE PUBLISHING GROUP UK, LONDON, vol. 46, no. 2, 1 February 2014 (2014-02-01), London , pages 111 - 116, XP093042389, ISSN: 0032-3896, DOI: 10.1038/pj.2013.78
İNCEL ANIL, VARLIKLI CANAN, MCMILLEN COLIN D., DEMIR MUSTAFA M.: "Triboluminescent Electrospun Mats with Blue-Green Emission under Mechanical Force", THE JOURNAL OF PHYSICAL CHEMISTRY C, AMERICAN CHEMICAL SOCIETY, US, vol. 121, no. 21, 1 June 2017 (2017-06-01), US , pages 11709 - 11716, XP093042393, ISSN: 1932-7447, DOI: 10.1021/acs.jpcc.7b02875
KARIMATA AYUMU, PATIL PRADNYA H., FAYZULLIN ROBERT R., KHASKIN EUGENE, LAPOINTE SÉBASTIEN, KHUSNUTDINOVA JULIA R.: "Triboluminescence of a new family of Cu I –NHC complexes in crystalline solid and in amorphous polymer films", CHEMICAL SCIENCE, ROYAL SOCIETY OF CHEMISTRY, UNITED KINGDOM, vol. 11, no. 39, 14 October 2020 (2020-10-14), United Kingdom , pages 10814 - 10820, XP055887496, ISSN: 2041-6520, DOI: 10.1039/D0SC04442C
"Functional Tactile Sensors - Materials, Devices and Integrations", 1 January 2021, WOODHEAD PUBLISHING, US, ISBN: 978-0-12-820633-1, article DENGFENG PENG, SICEN QU: "6 - Mechanoluminescent materials for tactile sensors", pages: 91 - 112, XP009544187, DOI: 10.1016/B978-0-12-820633-1.00007-3
Attorney, Agent or Firm:
SIKs & Co. (JP)
Download PDF:
Previous Patent: POLYESTER RESIN
Next Patent: DRIVE CIRCUIT FOR LIGHT-EMITTING ELEMENT, ACTIVE SENSOR, AND OBJECT IDENTIFICATION SYSTEM
Next Patent: DRIVE CIRCUIT FOR LIGHT-EMITTING ELEMENT, ACTIVE SENSOR, AND OBJECT IDENTIFICATION SYSTEM