Title:
HYDRODESULFURIZATION CATALYST FOR HYDROCARBON OILS
Document Type and Number:
WIPO Patent Application WO/2011/049134
Kind Code:
A1
Abstract:
Provided is a hydrodesulfurization catalyst for hydrocarbon oils which exhibits an excellent hydrodesulfurization performance and has a long life.
The hydrodesulfurization catalyst for hydrocarbons contains a carrier formed of a composite oxide and a catalytic component, said catalytic component being held on said carrier and comprising sulfide of a metal belonging to Group 6A in the periodic table, sulfide of a metal belonging to Group 8 in the periodic table and a carbonaceous material, the average face distance of the face (002) of the sulfide of the metal belonging to Group 6A in the periodic table, that is observed in a transmission electron microscopic photograph, being 5 nm or less, and said sulfide of the metal belonging to Group 6A in the periodic table consisting of 3 or less layers on average, wherein said carrier satisfies the following requirements in ammonia adsorption calorimetry: (1) the content of an acid having an ammonia adsorption energy of 90 kJ/mol or more being 0.32 mmol/g or less; and (2) the ratio of the content of an acid having an ammonia adsorption energy of 90 kJ/mol or more to the content of an acid having an ammonia adsorption energy of 70 kJ/mol or more being 60% or less.
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Inventors:
ISHIHARA HISAYA (JP)
MORITA YOSHIHIRO (JP)
YOSHIMURA YUJI (JP)
TOBA MAKOTO (JP)
MORITA YOSHIHIRO (JP)
YOSHIMURA YUJI (JP)
TOBA MAKOTO (JP)
Application Number:
PCT/JP2010/068502
Publication Date:
April 28, 2011
Filing Date:
October 20, 2010
Export Citation:
Assignee:
JGC CATALYSTS & CHEMICALS LTD (JP)
NAT INST OF ADVANCED IND SCIEN (JP)
ISHIHARA HISAYA (JP)
MORITA YOSHIHIRO (JP)
YOSHIMURA YUJI (JP)
TOBA MAKOTO (JP)
NAT INST OF ADVANCED IND SCIEN (JP)
ISHIHARA HISAYA (JP)
MORITA YOSHIHIRO (JP)
YOSHIMURA YUJI (JP)
TOBA MAKOTO (JP)
International Classes:
B01J27/051; B01J37/02; B01J37/20; C10G45/08
Domestic Patent References:
WO2001015805A1 | 2001-03-08 |
Foreign References:
JP2000342976A | 2000-12-12 | |||
JP2005013848A | 2005-01-20 | |||
JP2005230622A | 2005-09-02 | |||
JPH06198174A | 1994-07-19 |
Attorney, Agent or Firm:
SSINPAT PATENT FIRM (JP)
Patent business corporation SSINPAT (JP)
Patent business corporation SSINPAT (JP)
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