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Title:
NANOPOROUS DETECTORS OF MONOCYCLIC AROMATIC COMPOUNDS AND OTHER POLLUTANTS
Document Type and Number:
WIPO Patent Application WO/2010/004225
Kind Code:
A3
Abstract:
Porous sol-gel material essentially consisting of units of one or more first polyalkoxysilanes chosen from the following compounds: (chloro­methyl)triethoxysilane; 1,3-dimethyltetramethoxydisiloxane; ethyltri­methoxysilane; triethoxy(ethyl)silane; triethoxymethylsilane; triethoxy­(vinyl)silane; trimethoxymethylsilane; trimethoxy(vinyl)silane; tetra­ethoxysilane or tetramethoxysilane (TMOS) and of units of one or more second polyalkoxysilanes chosen from the following compounds: (N‑(3-(trimethoxysilyl)propyl)ethylenediamine; 3‑aminopropyltriethoxysilane (APTES) and 3-aminopropyltrimethoxysilane, in a first polyalkoxy­silane/second polyalkoxysilane molar ratio of 1/0.01 to 1/1, optionally comprising a probe molecule, method of preparation and applications in the trapping of monocyclic aromatic hydrocarbons and other pollutants or in their detection.

Inventors:
CRUNAIRE SABINE (FR)
TRAN-THI THU-HOA (FR)
Application Number:
PCT/FR2009/051376
Publication Date:
May 06, 2010
Filing Date:
July 10, 2009
Export Citation:
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Assignee:
COMMISSARIAT ENERGIE ATOMIQUE (FR)
CRUNAIRE SABINE (FR)
TRAN-THI THU-HOA (FR)
International Classes:
C08L83/04; B01J20/10; B01J20/26; B01J20/283; C03B19/12; C03C1/00; C08J3/075; G01N1/22; G01N21/33; G01N21/64; G01N21/78; G01N21/79; G01N33/00
Domestic Patent References:
WO2006094392A12006-09-14
Foreign References:
US20030180964A12003-09-25
US4017528A1977-04-12
US6667016B12003-12-23
US20030231984A12003-12-18
EP1566213A12005-08-24
FR2890745A12007-03-16
Other References:
KUNZELMANN U ET AL: "Biosensor properties of glucose oxidase immobilized within SiO2 gels", SENSORS AND ACTUATORS B, ELSEVIER SEQUOIA S.A., LAUSANNE, CH, vol. 39, no. 1-3, 1 March 1997 (1997-03-01), pages 222 - 228, XP004087746, ISSN: 0925-4005
CALVO-MUNOZ M-L ET AL: "Chemical sensors of monocyclic aromatic hydrocarbons based on sol-gel materials: kinetics of trapping of the pollutants and sensitivity of the sensor", SENSORS AND ACTUATORS B, ELSEVIER SEQUOIA S.A., LAUSANNE, CH, vol. 87, no. 1, 15 November 2002 (2002-11-15), pages 173 - 183, XP004391091, ISSN: 0925-4005
Attorney, Agent or Firm:
PERIN, Georges et al. (52 rue de la Victoire, Paris Cedex 09, FR)
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