BACKGROUND OF THE INVENTION Field of the Invention This invention relates to methods and catalysts to generate a hydrogen-rich gas from gas mixtures containing carbon monoxide and water, such as water-containing syngas mixtures. More particularly, the invention includes methods using both precious metal-and non-precious metal-containing catalysts. The catalysts may be supported on a variety of catalyst support materials. Catalysts of the invention exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation.

Discussion of the Related Art Numerous chemical and energy-producing processes require a hydrogen-rich composition (e. g. feed stream). A hydrogen-rich feed stream is typically combined with other reactants to carry out various processes. Nitrogen fixation processes, for example, produce ammonia by reacting feed streams containing hydrogen and nitrogen under high pressures and temperatures in the presence of a catalyst. In other processes, the hydrogen-rich feed stream should not contain components detrimental to the process.

Fuel cells such as polymer electrode membrane (PEM) fuel cells, produce energy from a hydrogen-rich feed stream. PEM fuel cells typically operate with a feed stream gas inlet temperature of less than 450°C. Carbon monoxide is excluded from the feed stream to the extent possible to prevent poisoning of the electrode catalyst, which is typically a platinum-containing catalyst. See U. S. Patent No. 6,299, 995.

One route for producing a hydrogen-rich gas is hydrocarbon steam reforming. In a hydrocarbon steam reforming process steam is reacted with a hydrocarbon fuel, such as methane, iso-octane, toluene, etc., to produce hydrogen gas and carbon dioxide. The reaction, shown below with methane (CH4), is strongly endothermic ; it requires a significant amount of heat.

CH4 + 2H20 o 4H2 +CO2 In the petrochemical industry, hydrocarbon steam reforming of natural gas is typically performed at temperatures in excess of 900°C. Even for catalyst assisted hydrocarbon steam reforming the temperature requirement is often still above 700°C. See, for example, U. S. Patent No. 6,303, 098. Steam reforming of hydrocarbons, such as methane, using nickel-and gold-containing catalysts and temperatures greater than 450°C is described in U. S. Patent No. 5,997, 835. The catalyzed process forms a hydrogen-rich gas, with depressed carbon formation.

One example of effective hydrocarbon steam reforming catalysts is the Sinfelt compositions which are composed of Pt, a Group 11 metal, and a Group 8-10 metal.

Group 11 metals include Cu, Ag and Au while Group 8-10 metals include the other noble metals. These catalyst formulations are well known in the promotion of hydrogenation, hydrogenolysis, hydrocracking, dealkylation of aromatics, and naphtha reforming processes. See, for example, U. S. Patent Nos. 3,567, 625 and 3,953, 368. The application of catalysts based on the Sinfelt model to water gas shift ("WGS") reaction, in particular at conditions suitable for lower temperature WGS applications such as PEM fuel cells, has not been previously reported.

Purified hydrogen-containing feed streams have also been produced by filtering the gas mixture produced by hydrocarbon steam reformation through hydrogen- permeable and hydrogen-selective membranes. See, for example, U. S. Patent No.

6,221, 117. Such approaches suffer from drawbacks due to the complexity of the system and slow flow rates through the membranes.

Another method of producing a hydrogen-rich gas such as a feed stream starts with a gas mixture containing hydrogen and carbon monoxide with the absence of any substantial amount of water. For instance, this may be the product of reforming of a hydrocarbon or an alcohol, and selectively removes the carbon monoxide from that gas mixture. The carbon monoxide can be removed by absorption of the carbon monoxide

and/or by its oxidation to carbon dioxide. Such a process utilizing a ruthenium based catalyst to remove and oxidize the carbon monoxide is disclosed in U. S. Patent No.

6,190, 430.

The water gas shift reaction is another mechanism for producing a hydrogen-rich gas but from water (steam) and carbon monoxide. An equilibrium process, the water gas shift reaction, shown below, converts water and carbon monoxide to hydrogen and carbon dioxide, and vice versa.

H20 + CO r--H2 + C°2 Various catalysts have been developed to catalyze the WGS reaction. These catalysts are typically intended for use at temperatures greater than 450°C and/or pressures above 1 bar. For instance, U. S. Patent No. 5,030, 440 relates to a palladium and platinum- containing catalyst formulation for catalyzing the shift reaction at 550-650°C. See also U. S. Patent No. 5,830, 425 for an iron/copper based catalyst formulation.

Catalytic conversion of water and carbon monoxide under water gas shift reaction conditions has been used to produce hydrogen-rich and carbon monoxide-poor gas mixtures. Existing WGS catalysts, however, do not exhibit sufficient activity at a given temperature to reach thermodynamic equilibrium concentrations of hydrogen and carbon monoxide such that the product gas may subsequently be used as a hydrogen feed stream. Specifically, existing catalyst formulations are not sufficiently active at low temperatures, that is, below about 450°C. See U. S. Patent No. 5,030, 440.

Platinum (Pt) is a well-known catalyst for both hydrocarbon steam reforming and water gas shift reactions. Under typical hydrocarbon steam reforming conditions, high temperature (above 850°C) and high pressure (greater than 10 bar), the WGS reaction may occur post-reforming over the hydrocarbon steam reforming catalyst due to the high temperature and generally unselective catalyst compositions. See, for instance, U. S.

Patent Nos. 6,254, 807,5, 368,835, 5,134, 109, and 5,030, 440 for a variety of catalyst compositions and reaction conditions under which the water gas shift reaction may occur post-reforming.

Metals such as cobalt (Co), ruthenium (Ru), palladium (Pd), rhodium (Rh) and nickel (Ni) have also been used as WGS catalysts but are normally too active for the selective WGS reaction and cause methanation of CO to CH4 under typical reaction

conditions. In other words, the hydrogen produced by the water gas shift reaction is consumed as it reacts with the CO present in the presence of such catalysts to yield methane. This methanation reaction activity has limited the utility of metals such as Co, Ru, Pd, Rh and Ni as water gas shift catalysts.

A need exists, therefore, for a method to produce a hydrogen-rich syngas, and catalysts which are highly active and highly selective for both hydrogen generation and carbon monoxide oxidation at moderate temperatures (e. g. below about 450 °C) to provide a hydrogen-rich syngas from a gas mixture containing hydrogen and carbon monoxide.

SUMMARY OF THE INVENTION The invention meets the need for highly active and selective catalysts for the generation of hydrogen and the oxidation of carbon monoxide and to thereby provide a hydrogen-rich gas, such as a hydrocarbon-rich syngas, from a gas mixture of at least carbon monoxide and water. Accordingly, the invention provides methods and catalysts for producing a hydrogen-rich gas.

The invention is, in a first general embodiment, a method for producing a hydrogen-rich gas (e. g. , syngas) by contacting a CO-containing gas, such as a syngas mixture with a water gas shift catalyst in the presence of water at a temperature of not more than 450 °C. In the first general embodiment, the water gas shift catalyst comprises a) Pt, its oxides or mixtures thereof; b) at least one of Fe and Rh, their oxides, and mixtures thereof, and c) at least one member selected from the group consisting of Sc, Y, Ti, Zr, V, Nb, Ta, Mo, Re, Co, Ni, Pd, Ge, Sn, Sb, La, Ce, Pr, Nd, Sm, and Eu, their oxides and mixtures thereof.

In one preferred embodiment, the water gas shift catalyst comprises Pt, its oxides and mixtures thereof, Rh, its oxides and mixtures thereof, and at least one member selected from the group consisting of Ti, Zr, Mo, Co, Ge, Sb, La, and Ce, their oxides, and mixtures thereof. In another preferred embodiment, the water gas shift catalyst comprises Pt, its oxides and mixtures thereof, Rh, its oxides and mixtures thereof, Fe, its oxides and mixtures thereof, and at least one member selected from the group consisting of Co, Pd, Ge, Sb, La, and Ce, their oxides and mixtures thereof. The catalyst may be supported on a carrier, for example, at least one member selected from the group consisting of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite,

perovskite, silica clay, yttria and iron oxide and mixtures thereof. The method of the invention may be conducted at a temperature ranging from about 150 °C to about 450 °C.

In a second general embodiment, the invention relates to the water gas shift catalysts themselves-both supported and unsupported catalysts. The inventive water gas shift catalyst comprises, in a first, general embodiment, Pt, its oxides and mixtures thereof, at least one of Fe and Rh, their oxides, and mixtures thereof, and at least one member selected from the group consisting of Na, K, Sc, Y, Ti, Zr, V, Nb, Ta, Mo, Re, Co, Ni, Pd, Ge, Sn, Sb, La, Ce, Pr, Nd, Sm, and Eu, their oxides and mixtures thereof.

The catalyst may be supported on a carrier comprising at least one member selected from the group consisting of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, yttria and iron oxide and mixtures thereof.

In a third general embodiment, the invention is directed to the aforementioned water gas shift catalysts of the second general embodiment in an apparatus for generating a hydrogen gas containing stream from a hydrocarbon or substituted hydrocarbon feed stream. The apparatus further comprises, in addition to the WGS catalyst, a fuel reformer, a water gas shift reactor, and a temperature controller. Such a specific WGS apparatus may be located within another larger apparatus, either stationary or otherwise, for generating energy, or a desired product or feed stream, either gaseous or liquid.

The following described preferred embodiments of the WGS catalyst can be used in each one of the first, second, and third general embodiments or in specific, related embodiments (e. g., fuel cell reactors, fuel processors, hydrocarbon steam reformers.) In one preferred embodiment the water gas shift catalyst comprises Pt, its oxides and mixtures thereof, Rh, its oxides and mixtures thereof ; and at least one member selected from the group consisting of Ti, Zr, Mo, Co, Ge, Sb, La, and Ce, their oxides and mixtures thereof.

In a second preferred embodiment the water gas shift catalyst may be formulated from Pt, its oxides and mixtures thereof, Rh, its oxides and mixtures thereof, Fe, its oxides and mixtures thereof, and at least one of Co, Pd, Ge, Sb, La, and Ce, their oxides and mixtures thereof.

A person of skill in the art will understand and appreciate that with respect to each of the preferred catalyst embodiments as described in the preceding paragraphs, the

particular components of each embodiment can be present in their elemental state, or in one or more oxide states, or mixtures thereof.

BRIEF DESCRIPTION OF THE DRAWINGS The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate preferred embodiments of the invention and together with the detailed description serve to explain the principles of the invention. In the drawings: Figs. lA-1D, illustrate the process of producing a library test wafer, and Figs. lE-lI, illustrate SpotFire plots of the CO conversion versus C02 production for the wafer under WGS conditions at various temperatures.

Figs. 2A-2D illustrate the process of producing a library test wafer.

Figs. 3A-3C illustrate the process of producing a library test wafer.

Figs. 4A-4C illustrate the process of producing a library test wafer, and Figs. 4D-4H, illustrate SpotFire plots of the CO conversion versus C02 production for the wafer under WGS conditions at various temperatures.

Figs. 5A-5G illustrate the process of producing a library test wafer, and Figs. 5H-5J, illustrate SpotFire plots of the CO conversion versus'C02 production for the wafer under WGS conditions at various temperatures.

Figs. 6A-6 F, illustrate the process of producing a library test wafer and Figs. 6G, 6H, and 6I, illustrate SpotFire plots of the CO conversion versus C02 production for the wafer under WGS conditions at various temperatures.

Fig. 7 illustrates plots of CO concentration versus temperature for scaled-up catalyst samples under WGS conditions.

Figs. 8A-8F, illustrate the compositional make-up of various exemplary library test wafers.

Fig. 9A illustrates a representative plot of CO conversion versus C02 production for a prototypical library test wafer at various temperatures, Fig. 9B illustrates the effect of catalyst selectivity and activity versus the WGS mass balance, and Fig. 9C illustrates the effect of temperature on catalyst performance under WGS conditions.

Figs. 10A-lOC illustrate plots of CO concentration versus temperature for scaled- up catalyst samples under WGS conditions.

Figs. 11A-11B illustrate plots of CO concentration versus temperature for scaled- up catalyst samples under WGS conditions.

DETAILED DESCRIPTION OF THE INVENTION The invention relates to a method for producing a hydrogen-rich gas, such as a hydrogen-rich syngas. According to the method a CO-containing gas such as a syngas contacts a water gas shift catalyst, in the presence of water, preferably a stoichiometric excess of water, preferably at a temperature of less than about 450 °C to produce a hydrogen-rich gas such as a hydrogen-rich syngas. The reaction pressure is preferably not more than about 10 bar. The invention also relates to a water gas shift catalyst itself and to apparatus such as water gas shift reactors and fuel processing apparatus comprising such WGS catalysts.

A water gas shift catalyst according to the invention comprises: a) Pt, its oxides or mixtures thereof ; b) at least one of Fe and Rh, their oxides and mixtures thereof ; and c) at least one member selected from the group consisting of Na, K, Sc, Y, Ti, Zr, V, Nb, Ta, Mo, Re, Co, Ni, Pd, Ge, Sn, Sb, La, Ce, Pr, Nd, Sm, and Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide.

In one preferred embodiment, the water gas shift catalyst may be comprised of Pt, its oxides and mixtures thereof, Rh, its oxides and mixtures thereof, and at least one member selected from the group consisting of Ti, Zr, Mo, Co, Ge, Sb, La, and Ce, their oxides and mixtures thereof. In another preferred embodiment, the water gas shift catalyst may be comprised of Pt, its oxides and mixtures thereof, Rh, its oxides and mixtures thereof, Fe, its oxides and mixtures thereof, and at least one member selected from the group consisting of Co, Pd, Ge, Sb, La, and Ce, their oxides and mixtures thereof.

The catalyst may be supported on a carrier, for example, at least one member selected from the group consisting of alumina, zirconia, titania, ceria, magnesia,

lanthania, niobia, yttria and iron oxide and mixtures thereof. The method of the invention may be conducted at a temperature ranging from about 150 °C to about 450 °C.

The WGS catalysts of the invention comprise combinations of at least three metals or metalloids, selected from at least three groups a), b), and c) indicated above, in each and every possible permutation and combination, except as specifically and expressly excluded. Although particular subgroupings of preferred combinations of metals or metalloids are also presented, the present invention is not limited to the particularly recited subgroupings.

Discussion regarding the particular function of various components of catalysts and catalyst systems is provided herein solely to explain the advantage of the invention, and is not limiting as to the scope of the invention or the intended use, function, or mechanism of the various components and/or compositions disclosed and claimed. As such, any discussion of component and/or compositional function is made, without being bound by theory and by current understanding, unless and except such requirements are expressly recited in the claims. Generally, for example, and without being bound by theory, the metals, Pt, component a), and Fe and Rh, component b), have activity as WGS catalysts. The metals or metalloids of component c) may themselves have activity as WGS catalysts, such as Co, but function in combination with Pt and one of Fe and Rh to impart beneficial properties to the catalyst of the invention.

Catalysts of the invention can catalyze the WGS reaction at varying temperatures, avoid or attenuate unwanted side reactions such as methanation reactions, as well as generate a hydrogen-rich gas, such as a hydrogen-rich syngas. The composition of the WGS catalysts of the invention and their use in WGS reactions are discussed below.

1. Definitions Water gas shift ("WGS") reaction : Reaction which produces hydrogen and carbon dioxide from water and carbon monoxide, and vice versa: H20 + CO-H2 + C°2 Generally, and unless explicitly stated to the contrary, each of the WGS catalysts of the invention can be advantageously applied both in connection with the forward reaction as shown above (i. e. , for the production of H2), or alternatively, in connection

with the reverse reaction as shown above (i. e. , for the production of CO). As such, the various catalysts disclosed herein can be used to specifically control the ratio of Ha to CO in a gas stream.

Methanation reaction : Reaction which produces methane and water from a carbon source, such as carbon monoxide or carbon dioxide, and hydrogen: C0+3 H2 o CH4+H2O<BR> <BR> CO2 + 4 H2 # CH4 + 2 H2O "Syngas" (also called synthesis gas) : Gaseous mixture comprising hydrogen (H2) and carbon monoxide (CO) which may also contain other gas components such as carbon dioxide (C02), water (H20), methane (CH4) and nitrogen (N2).

LTS : Refers to"low temperature shift"reaction conditions where the reaction temperature is less than about 250°C, preferably ranging from about 150°C to about 250°C.

MTS : Refers to"medium temperature shift"reaction conditions where the reaction temperature ranges from about 250°C and up to about 350°C.

HTS : Refers to"high temperature shift"reaction conditions where the reaction temperature is more than about 350°C and up to about 450°C.

Hydrocarbon : Compound containing hydrocarbon, carbon, and, optionally, oxygen.

The Periodic Table of the Elements is based on the present IUPAC convention, thus, for example, Group 8 comprises Fe, Ru, and Os. (See http://www. iupac. org dated May 30,2002.) As discussed herein, the catalyst composition nomenclature uses a dash (i. e.,"-") to separate catalyst component groups where a catalyst may contain one or more of the catalyst components listed for each component group, brackets (i. e.," {}") are used to enclose the members of a catalyst component group," {two of...}"is used if two or more members of a catalyst component group are required to be present in a catalyst composition, "blank"is used with the" {}" to indicate the possible choice that no additional element is added, and a slash (i. e. ,"/") is used to separate supported catalyst

components from their support material, if any. Additionally, the elements within catalyst composition formulations include all possible oxidation states, including oxides, or salts, or mixtures thereof.

Using this shorthand nomenclature in this specification, for example,"Pt- {Rh, Ni}- {Na, K, Fe, Os}/ZrO2"would represent catalyst compositions containing Pt, one or more of Rh and Ni, and one or more of Na, K, Fe, and Os supported on ZrO2 ; all of the catalyst elements may be in any possible oxidation state, unless explicitly indicated otherwise."Pt-Rh-Ni- {two of Na, K, Fe, Os}"would represent a supported or unsupported catalyst composition containing Pt, Rh, and Ni, and two or more of Na, K, Fe, and Os."Rh- {Cu, Ag, Au}- {Na, K, blank}/Ti02"would represent Ti02 supported catalyst compositions containing Rh, one or more of Cu, Ag and Au, and, optionally, one or more of Na or K.

2. WGS Catalyst A water gas shift catalyst of the invention comprises: a) Pt, its oxides or mixtures thereof ; b) at least one of Fe and Rh, their oxides and mixtures thereof ; and c) at least one member selected from the group consisting of Na, K, Sc, Y, Ti, Zr, V, Nb, Ta, Mo, Re, Co, Ni, Pd, Ge, Sn, Sb, La, Ce, Pr, Nd, Sm, and Eu, their oxides and mixtures thereof. Suitable carriers for supported catalysts are discussed below.

The catalyst components are typically present in a mixture of the reduced or oxide forms ; typically one of the forms will predominate in the mixture. A WGS catalyst of the invention may be prepared by mixing the metals and/or metalloids in their elemental forms or as oxides or salts to form a catalyst precursor. This catalyst precursor mixture generally undergoes a calcination and/or reductive treatment, which may be in- situ (within the reactor), prior to use as a WGS catalyst. Without being bound by theory, the catalytically active species are generally understood to be species which are in the reduced elemental state or in other possible higher oxidation states. The catalyst precursor species are believed to be substantially completely converted to the catalytically active species by the pre-use treatment. Nonetheless, the catalyst component species present after calcination and/or reduction may be a mixture of catalytically active species such as the reduced metal or other possible higher oxidation

states and uncalcined or unreduced species depending on the efficiency of the calcination and/or reduction conditions.

A. Catalyst Compositions As discussed above, one embodiment of the invention is a catalyst for catalyzing the water gas shift reaction (or its reverse reaction). According to the invention, a WGS catalyst may have the following composition: a) Pt, its oxides or mixtures thereof; b) at least one of Fe and Rh, their oxides and mixtures thereof ; and c) at least one member selected from the group consisting of Na, K, Sc, Y, Ti, Zr, V, Mo, Re, Co, Ni, Pd, Ge, Sn, Sb, La, Ce, Pr, Nd, Sm, and Eu, their oxides and mixtures thereof. The amount of each component present in a given catalyst according to the present invention may vary depending on the reaction conditions under which the catalyst is intended to operate. Generally, a Group 8,9 or 10 metal component may be present in an amount ranging from about 0.01 wt. % to about 10 wt. %, preferably about 0.01 wt. % to about 2 wt. %, and more preferably about 0.05 wt. % to about 0.5 wt. %.

The lanthanide elements may be present, typically, in amounts ranging from about 0.05 wt. % to about 20 wt. %, preferably about 0.1 wt. % to about 15 wt. %. The main group and metalloid elements may be present in amounts ranging, generally, from about 0.01 wt. % to about 15 wt. %, preferably about 0.02 wt. % to about 10 wt. %.

The above weight percentages are calculated on the total weight of the catalyst component in its final state in the catalyst composition after the final catalyst preparation step (i. e. , the resulting oxidation state or states) with respect to the total weight of all catalyst components plus the support material, if any. The presence of a given catalyst component in the support material and the extent and type of its interaction with other catalyst components may effect the amount of a component needed to achieve the desired performance effect.

Other WGS catalysts which embody the invention are listed below. Utilizing the shorthand notation discussed above, where each metal may be present in its reduced form or in a higher oxidation state, the following compositions are examples of preferred catalyst compositions: Pt-Rh- {Ge, Sb}.

Pt-Rh-Mo.

Pt-Rh-Co- {La, Ce}.

Pt-Rh- {Ti, Zr, Ce}.

Pt- {Rh, Fe}- {Ge, Sb}.

Pt- {Rh, Fe}- {Co, La, Ce}.

Pt- {Rh, Fe} -Pd.

Some catalysts may be more advantageously applied in specific operating temperature ranges. For instance, Pt-Rh-Fe-SbGe and Pt-Rh-{Ce, Ti} provide high activity in the HTS temperature range; other formulations that are particularly preferred for HTS temperature conditions are Pt-Rh- {Ti, Zr} ; Pt-Rh- {Ce, Zr} ; and Pt-Rh-Fe- {La, Ce, Co}.

B. Catalyst Component a): Pt A first component in a catalyst of the invention is Pt, component a). Pt, like all metal components, may be present in a combination of its reduced forms and its oxides.

Catalysts of the invention may contain mixtures of these metal states.

Pt is known to catalyze the WGS reaction. Typically Pt alone is too active and unselective towards the formation of hydrogen under typical WGS conditions. However, as demonstrated here, properly modified Pt containing catalyst formulations may provide both increased selectivity to hydrogen generation at high activity levels under WGS reaction conditions.

C. Catalyst Component b): Fe and/or Rh Rhodium and other metals including, for instance, ruthenium, cobalt, palladium, and nickel have been used as WGS catalysts but are normally too active for the selective WGS reaction and cause methanation of CO to CH4 under typical WGS reaction conditions. In other words, the hydrogen produced by the water gas shift reaction is consumed as it reacts with the CO present in the presence of such catalysts to yield methane. This methanation reaction activity has limited the utility of such metals as water gas shift catalysts.

Unmodified Rh has been shown to catalyze the methanation reaction under WGS conditions. However, according to the present invention, Rh may be converted to a highly active and selective WGS catalyst by adjusting the Rh loading and alloying with other catalyst components which may moderate the activity of Rh for the methanation reaction. In one preferred combination, Pt was found to efficiently alter the selectivity of

unmodified Rh. According to the present invention, various dopants may be added to the Pt and Rh containing catalyst formulations and some preferred catalysts include, for example, Pt-Rh-Pd, Pt-Rh-Pd-Fe, Pt-Rh-Fe and Pt-Rh-Fe-{Ge, Sb}. The resulting catalyst compositions are highly active and selective WGS catalysts, and exhibit increased selectivity for the WGS reaction over the competing methanation reaction.

Pt-Rh compositions can also be gradually moderated, while enhancing WGS selectivity at the expense of activity, by adding additional catalyst components such as, for instance, main group metals, rare earth metals and lanthanides.

Iron itself is recognized as a selective HTS conventional syngas catalyst but, typically needing temperature in excess of 400 °C, is not active enough for most desired applications. Iron does not reduce to the metal state in the presence of water but stays in an oxidized state. Hence, doping iron with noble metals, preferably Pt or Rh, maintains the selectivity while increasing the activity. Adding Ru tends to provide a less selective composition in contrast to the Pt-Fe or Rh-Fe compositions. Pt-Rh-Fe tends to provide high activity and selectivity under WGS reaction conditions.

D. Catalyst Component c):"Functional"Metals or Metalloids The WGS catalysts of the invention comprise at least three metals or metalloids.

In addition to the first two components, discussed above, a WGS catalyst comprises metals or metalloids which, when used in combination with Pt, its oxides and mixtures thereof, and at least one of Fe and Rh, their oxides and mixtures thereof, function to impart beneficial properties to the catalyst of the invention. A catalyst of the invention, then, further comprises at least one member of Sc, Y, Ti, Zr, V, Nb, Ta, Mo, Re, Co, Ni, Pd, Ge, Sn, Sb, La, Ce, Pr, Nd, Sm, and Eu, their oxides, and mixtures thereof, component c).

Pt-Rh containing catalysts may further include activity-or selectivity-enhancing promoters such as Ti, Zr, Mo, Co, Ge, Sb, La, and Ce, their oxides and mixtures thereof.

Preferred carriers include, for instance, zirconia, ceria and titania. One preferred supported catalyst includes, for example, Pt-Rh-Mo on Zr02.

Pt-Rh-Fe containing catalyst compositions may preferably further comprise one or more of Co, Pd, Ge, Sb, La, and Ce, their oxides and mixtures thereof.

E. Functional Classification of Catalyst Components

Without limiting the scope of the invention, discussion of the functions of the various catalyst components is offered, along with a template for composing catalyst compositions according to the invention. The following classification of catalyst components will direct one of skill in the art in the selection of various catalyst components to formulate WGS catalyst compositions according to the present invention and depending on the reaction conditions of interest.

Furthermore, according to the invention, there are several classes of catalyst components and metals which may be incorporated into a water gas shift catalyst.

Hence, the various elements recited as components in any of the described embodiments (e. g., as component (c) ), may be included in any various combination and permutation to achieve a catalyst composition that is coarsely or finely tuned for a specific application (e. g. including for a specific set of conditions, such as, temperature, pressure, space velocity, catalyst precursor, catalyst loading, catalyst surface area/presentation, reactant flow rates, reactant ratios, etc. ). In some cases, the effect of a given component may vary with the operating temperature for the catalyst. These catalyst components may function as, for instance, activators or moderators depending upon their effect on the performance characteristics of the catalyst. For example, if greater activity is desired, an activator may be incorporated into a catalyst, or a moderator may be replaced by at least one activator or, alternatively, by at least one moderator one step further up the"activity ladder. "An"activity ladder"ranks secondary or added catalyst components, such as activators or moderators, in order of the magnitude of their respective effect on the performance of principal catalyst constituent. Conversely, if WGS selectivity of a catalyst needs to be increased (e. g. , decrease the occurrence of the competing methanation reaction), then either an activator may be removed from the catalyst or, alternatively, the current moderator may be replaced by at least one moderator one step down the"activity ladder. "The function of these catalyst component may be further described as"hard"or"soft"depending on the relative effect obtained by incorporating a given component into a catalyst. The catalyst components may be metals, metalloids, or even non-metals.

For instance, typically, a WGS catalyst according to the invention suitable for use under LTS conditions employs activators and may only be minimally moderated, if at all, because activation is generally the important parameter to be considered under LTS

conditions. Such LTS catalysts also may preferably employ high surface area carriers to enhance catalyst activity. Conversely, WGS catalysts used in HTS conditions may benefit from the catalyst being moderated because selectivity and methanation are parameters to be considered. Such HTS catalysts may use, for example, low surface area carriers. Accordingly, operating temperature may be considered in selecting a WGS catalyst according to the present invention for a particular operating environment.

Activators according to the present invention may include Pd and Co as active and selective WGS-promoting metals. Activators may include, but are not limited to, Ti, Zr, V, Mo, La and Ce. Ce may be the most active rare earth metal for activating the WGS reaction. La, Pr, Sm and Eu may also be active, particularly at lower temperatures.

For HTS, Pr and Sm are preferred soft moderators enhancing selectivity without sacrificing much activity. For LTS, La and Eu may be useful activators. In general, all lanthanides, other than Ce, show comparable performance and tend to moderate rather than activate noble metal containing catalyst systems. Y is a highly selective moderator for HTS systems whereas La and Eu are active and comparable to Ce for LTS. La is only slightly moderating when doping Ce and may therefore be used to adjust the selectivity of Ce containing catalyst systems.

Catalyst components that are slightly moderating and highly selective over a broad temperature range (e. g., a temperature range of at least about 50 °C, preferably at least about 75 °C, and most preferably a temperature range of at least about 100°C), where such temperature range is included within the overall preferred temperature ranges of up to about 450 °C include Y, Mo, Fe, Pr and Sm; these tend to be selective but not very active at low temperatures, about 250°C. The redox dopants Mo, Fe, Pr and Sm generally lose activity with increasing pre-reduction temperatures while Fe becomes moderately active on its own at high WGS reaction temperatures.

Moderators may also include Ge, Sn and Sb. Typically, for moderators to exert a moderating function, they should be substantially in the reduced or metallic state. Ge alloyed with Sn is an example of an alloy that was found to be highly active, even for low temperature systems, when in the fully oxidized state that is when treated at a pre- reduction temperature of about 300 °C which reduces the noble metals selectively but does not change the active oxidized state of the redox dopants.

F. Supports

The support or carrier may be any support or carrier used with the catalyst which allows the water gas shift reaction to proceed. The support or carrier may be a porous, adsorptive, high surface area support with a surface area of about 25 to about 500 m2/g.

The porous carrier material may be relatively inert to the conditions utilized in the WGS process, and may include carrier materials that have traditionally be utilized in hydrocarbon steam reforming processes, such as, (1) activated carbon, coke, or charcoal; (2) silica or silica gel, silicon carbide, clays, and silicates including those synthetically prepared and naturally occurring, for example, china clay, diatomaceous earth, fuller's earth, kaolin, etc.; (3) ceramics, porcelain, bauxite; (4) refractory inorganic oxides such as alumina, titanium dioxide, zirconium oxide, magnesia, etc.; (5) crystalline and amorphous aluminosilicates such as naturally occurring or synthetically prepared mordenite and/or faujasite; and, (6) combinations of these groups.

When a WGS catalyst of the invention is a supported catalyst, the support utilized may contain one or more of the metals (or metalloids) of the catalyst. The support may contain sufficient or excess amounts of the metal for the catalyst such that the catalyst may be formed by combining the other components with the support. Examples of such supports include ceria which can contribute cerium, Ce, (component c) ) to a catalyst, or iron oxide which can contribute iron, Fe, (component b)). When such supports are used the amount of the catalyst component in the support typically may be far in excess of the amount of the catalyst component needed for the catalyst. Thus the support may act as both an active catalyst component and a support material for the catalyst. Alternatively, the support may have only minor amounts of a metal making up the WGS catalyst such that the catalyst may be formed by combining all desired components on the support.

Carrier screening with catalysts containing Pt as the only active noble metal revealed that a water gas shift catalyst may also be supported on a carrier comprising alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide. Perovskite may also be utilized as a support for the inventive catalyst formulations.

Zirconia, titania and ceria may be supports for the present invention and provide high activity for the WGS reaction. Preferably, zirconia is in the monoclinic phase.

Niobia, yttria and iron oxide carriers provide high selectivity but are also less active which is believed to be due to a lack of surface area. Pt on magnesia carriers formulated

to have high surface areas (approximately 100 m2/g) exhibit high selectivity but also exhibit activity which decreases rapidly with falling reaction temperature.

Iron, yttrium and magnesium oxides may be utilized as primary layers on zirconia carriers to provide both higher surface area and low moderator concentration.

In general, alumina has been found to be an active but unselective carrier for Pt only containing WGS catalysts. However, the selectivity of gamma alumina may be improved by doping with Y, Zr, Co, or one of the rare earth elements, such as, for example, La and Ce. This doping may be accomplished by addition of the oxides or other salts such as nitrates, in either liquid or solid form, to the alumina. Other possible dopants to increase the selectivity include redox dopants, such as for instance, Re, Mo, Fe and basic dopants. Preferred is an embodiment of gamma alumina combined with yttria or with both Zr and/or Co which exhibit both high activity and selectivity over a broad temperature range.

High surface area aluminas, such as gamma-, delta-, or theta-alumina are preferred alumina carriers. Other alumina carriers, such as mixed silica alumina, sol-gel alumina, as well as sol-gel or co-precipitated alumina-zirconia carriers may be used.

Alumina typically has a higher surface area and a higher pore volume than carriers such as zirconia and offers a price advantage over other more expensive carriers.

G. Methods of Making a WGS Catalyst As set forth above, a WGS catalyst of the invention may be prepared by mixing the metals and/or metalloids in their elemental forms or as oxides or salts to form a catalyst precursor, which generally undergoes a calcination and/or reductive treatment.

Without being bound by theory, the catalytically active species are generally understood to be species which are in the reduced elemental state or in other possible higher oxidation states.

The WGS catalysts of the invention may be prepared by any well known catalyst synthesis processes. See, for example, U. S. Patent Nos. 6,299, 995 and 6,293, 979. Spray drying, precipitation, impregnation, incipient wetness, ion exchange, fluid bed coating, physical or chemical vapor deposition are just examples of several methods that may be utilized to make the present WGS catalysts. Preferred approaches, include, for instance, impregnation or incipient wetness. The catalyst may be in any suitable form, such as, pellets, granular, bed, or monolith. See also the co-pending PCT International Patent

Application No. filed on the same date as the present application titled "Methods For The Preparation Of Catalysts For Hydrogen Generation"to Hagemeyer et al. under Attorney Docket No. 708001101PCT for further details on methods of catalyst preparation and catalyst precursors. The complete disclosure of the above mentioned application and all other references cited herein are incorporated herein in their entireties for all purposes.

The WGS catalyst of the invention may be prepared on a solid support or carrier material. Preferably, the support or carrier is, or is coated with, a high surface area material onto which the precursors of the catalyst are added by any of several different possible techniques, as set forth above and as known in the art. The catalyst of the invention may be employed in the form of pellets, or on a support, preferably a monolith, for instance a honeycomb monolith.

Catalyst precursor solutions are preferably composed of easily decomposable forms of the catalyst component in a sufficiently high enough concentration to permit convenient preparation. Examples of easily decomposable precursor forms include the nitrate, amine, and oxalate salts. Typically chlorine containing precursors are avoided to prevent chlorine poisoning of the catalyst. Solutions can be aqueous or non-aqueous solutions. Exemplary non-aqueous solvents can include polar solvents, aprotic solvents, alcohols, and crown ethers, for example, tetrahydrofuran and ethanol. Concentration of the precursor solutions generally may be up to the solubility limitations of the preparation technique with consideration given to such parameters as, for example, porosity of the support, number of impregnation steps, pH of the precursor solutions, and so forth. The appropriate catalyst component precursor concentration can be readily determined by one of ordinary skill in the art of catalyst preparation.

Li-The acetate, hydroxide, nitrate and formate salts are both possible catalyst precursors for lithium.

Na-Sodium acetate, alkoxides including methoxide, propoxide, and ethoxide, bicarbonate, carbonate, citrate, formate, hydroxide, nitrate, nitrite and oxalate may be used to prepare WGS catalysts of the invention.

Mg-Water soluble magnesium precursors include the nitrate, acetate, lactate and formate salts.

K-Potassium nitrate, acetate, carbonate, hydroxide and formate are possible potassium catalyst precursors. The KOAc salt is volatile with possible potassium losses when heating up to calcination temperature.

Ca-The nitrate, acetate and hydroxide salts, preferable salts highly soluble in water, may be used to prepare catalysts of the invention.

Sc-The nitrate salt, Sc (N03) 3 may be a precursor for scandium.

Ti-Titanium precursors which may be utilized in the present invention include ammonium titanyl oxalate, (NH4) 2TiO (C204) 2, available from Aldrich, and titanium (IV) bis (ammonium lactato) dihydroxide, 50 wt% solution in water, [CH3CH (O-) C02NH4] 2Ti (OH) 2, available from Aldrich. Other titanium containing precursors include Ti oxalate prepared by dissolving a Ti (IV) alkoxide, such as Ti (IV) propoxide, Ti (OCH2CH2CH3) 4, (Aldrich) in 1M aqueous oxalic acid at 60°C and stirring for a couple of hours, to produce a 0.72M clear colorless solution ; Ti0 (acac) oxalate prepared by dissolving Ti (IV) oxide acetylacetonate, TiO (acac) 2, (Aldrich) in 1. 5M aqueous oxalic acid at 60°C with stirring for a couple of hours, following by cooling to room temperature overnight to produce 1M clear yellow-brown solution ; Ti0 (acac) 2, may also be dissolved in dilute acetic acid (50: 50 HOAc: H20) at room temperature to produce a 1M clear yellow solution of TiO acac. Preferably, titanium dioxide in the anatase form is utilized as a catalyst precursor material.

V-Vanadium (IV) oxalate, a vanadium precursor, may be prepared from V205, (Aldrich), which is slurried in 1. 5M aqueous oxalic acid on hot plate for 1 hour until it turns dark blue due to V (V) reduction to V (IV) by oxalic acid. Ammonium metavanadate (V), (NH4) V03, (Cerac, Alfa) may be used as a precursor by dissolving it in water, preferably hot, about 80°C water. Various polycarboxylic organic acid vanadium precursors can be prepared and used as catalyst precursors, for example, citric, maleic, malonic, and tatartic. Vanadium citrate can be prepared by reacting V205 with citric acid, and heating to about 80 °C. Ammonium vanadium (V) oxalate may be prepared by reacting (NH4) V03 and NH40H in room temperature water, increasing temperature to 90°C, stirring to dissolve all solids, cooling to room temperature and adding oxalic acid ; this produces a clear orange solution, which is stable for about 2 days. Ammonium vanadium (V) citrate and ammonium vanadium (V) lactate are both prepared by shaking NH4V03 in, respectively, aqueous citric acid or aqueous lactic acid,

at room temperature. Diammonium vanadium (V) citrate may be prepared by dissolving, for instance, 0.25M NH4V03 in citric acid ammonium salt (Alfa) at room temperature.

An exemplary method of preparing ammonium vanadium (V) formate is to dissolve NH4V03 (0.25M) in water at 95 °C, react with 98% formic acid and NH40H to produce the desired ammonium vanadium (V) formate.

Cr-Both the nitrate and acetate hydroxides are possible catalyst precursors for chromium.

Mn-Manganese nitrate, manganese acetate (Aldrich) and manganese formate (Alfa) are all possible catalyst precursors for manganese.

Fe-Iron (III) nitrate, Fe (N03) 3, iron (III) ammonium oxalate, (NH4) 3 Fe (C204) 3, iron (III) oxalate, Fe2 (C204) 3, and iron (II) acetate, Fe (OAc) 2, are all water soluble; although the iron (III) oxalate undergoes thermal decomposition at only 100°C.

Potassium iron (III) oxalate, iron (III) formate and iron (III) citrate are additional iron precursors.

Co-Both cobalt nitrate and acetate are water soluble precursor solutions. The cobalt (II) formate, Co (OOCH) 2, has low solubility in cold water of about 5g/100ml, while cobalt (II) oxalate is soluble in aqueous NH40H. Another possible precursor is sodium hexanitrocobaltate (III), Na3Co (NO2) 6 which is water soluble, with gradual decomposition of aqueous solutions slowed by addition of small amounts of acetic acid.

Hexaammine Co (III) nitrate is also soluble in hot (65 °C) water and NMe40H. Cobalt citrate, prepared by dissolving Co (OH) 2 in aqueous citric acid at 80 °C for 1 to 2 hours, is another suitable cobalt precursor.

Ni-Nickel nitrate, Ni (N03) 2, and nickel formate are both possible nickel precursors. The nickel formate may be prepared by dissolving Ni (HC02) 2 in water and adding formic acid, or by dissolving in dilute formic acid, to produce clear greenish solutions.

Cu-Copper precursors include nitrate, Cu (N03) 2, acetate, Cu (OAc) 2, and formate, Cu (OOCH) 2, which are increasingly less water soluble in the order presented.

Ammonium hydroxide is used to soluble oxalate, Cu (C204) 2, and Cu (NH3) 4 (OH) 2 which is soluble in aqueous 5N NH40H. Copper citrate and copper amine carbonate may be prepared from Cu (OH) 2.

Zn-Zinc nitrate, acetate and formate are all water soluble and possible catalyst precursors. Ammonium zinc carbonate, (NH4) 2Zn (OH) 2CO3, prepared by reacting zinc hydroxide and ammonium carbonate for a week at room temperature, is another possible precursor for zinc.

Ge-Germanium oxalate may be prepared from amorphous Ge (IV) oxide, glycol- soluble GeO2, (Aldrich) by reaction with 1M aqueous oxalic acid at room temperature.

H2Ge03 may be prepared by dissolving Ge02 in water at 80°C and adding 3 drops of NH40H (25%) to produce a clear, colorless H2Ge03 solution. (NMe4) 2GeO3 may be prepared by dissolving 0.25 M Ge02 in 0.1 M NMe40H. (NH4) 2GeO3 may be prepared by dissolving 0.25 M GeO2 in 0.25M NH40H.

Rb-The nitrate, acetate, carbonate and hydroxide salts may be used as catalyst precursors to prepare the WGS catalyst of the invention. Preferred are water soluble salts.

Sr-The acetate is soluble in cold water to produce a clear colorless solution.

Y-Yttrium nitrate and acetate are both possible catalyst precursors.

Zr-Zirconyl nitrate and acetate, commercially available from Aldrich, and ammonium Zr carbonate and zirconia, available from MEI, are possible precursors for zirconium in either or both the support or catalyst formulation itself.

Nb-Niobium oxalate prepared by dissolving niobium (V) ethoxide in aqueous oxalic acid at 60 °C for 12 hours is a possible catalyst precursor. Another preparative route to the oxalate is dissolving niobic acid or niobic oxide (Nb20s) in oxalic acid at 65 °C. Ammonium Nb oxalate is also a possible catalyst precursor for niobium. Dissolving niobic oxide (0.10 M Nb) in NMe40H (0.25 M) and stirring overnight at 65 °C will produce (NMe4) 2Nb06.

Mo-Molybdenum containing precursor solutions may be derived from ammonium molybdate (NH4) 2MoO4 (Aldrich) dissolved in room temperature water ; Mo oxalate prepared by dissolving MoO3 (Aldrich) in 1. 5M aqueous oxalic acid at 60°C overnight ; and ammonium Mo oxalate prepared from (NH4) 6Mo70244H2O (Skem) dissolved in 1M aqueous oxalic acid at room temperature. (NH4) 6Mo70244H20 (Strem) may also be dissolved in water at room temperature to produce a stable solution of ammonium paramolybdate tetrahydrate. Molybdic acid, H2Mo04, (Alfa Aesar or

Aldrich) may each be dissolved in room temperature water to produce 1M Mo containing solutions.

Ru-Ru nitrosyl nitrate, Ru (NO) (N03) 3 (Aldrich), potassium ruthenium oxide, K2Ru04 H20, potassium perruthenate, KRu04, ruthenium nitrosyl acetate, Ru (NO) (OAc) 3, and tetrabutylammonium perruthenate, NBu4Ru04, are all possible ruthenium metal catalyst precursors. NMe4Ru (NO) (OH) 4 solution can be prepared by dissolving Ru (NO) (OH) 3 (0. 1 M) (H. C. Starck) in NMe40H (0. 12M) at 80 °C produces a clear dark red-brown 0. 1M Ru solution useful as a catalyst precursor solution.

Rh-A suitable rhodium catalyst precursor is Rh nitrate (Aldrich or Strem).

Pd-Catalyst compositions containing Pd can be prepared by using precursors like Pd nitrate, typically stabilized by dilute HNO3, and available as a 10 wt. % solution from Aldrich, or Pd (NH3) 2 (NO2) 2 available as a 5 wt. % Pd commercial solution, stabilized by dilute NH40H. Pd (NH3) 4 (NO3) 2 and Pd (NH3) 4 (OH) 2 are also available commercially.

Ag-Silver nitrate, silver nitrite, silver diammine nitrite, and silver acetate are possible silver catalyst precursors.

Cd-Cadmium nitrate is water soluble and a suitable catalyst precursor.

In-Indium formate and indium nitrate are preferred precursors for indium.

Sn-Tin oxalate produced by reacting the acetate with oxalic acid may be used as a catalyst precursor. Tin tartrate, SnC4H406, in NMe40H at about 0.25 M Sn concentration, and tin acetate, also dissolved in NMe40H at about 0.25 M Sn concentration, may be used as catalyst precursors.

Sb-Ammonium antimony oxalate produced by reacting the acetate with oxalic acid and ammonia is a suitable antimony precursor. Antimony oxalate, Sb2 (C204) 3, available from Pfaltz & Bauer, is a water soluble precursor. Potassium antimony oxide, KSb03, and antimony citrate, prepared by stirring antimony (II) acetate in 1 M citric acid at room temperature, are both possible catalyst precursors.

Te-Telluric acid, Te (OH) 6, may be used as a precursor for tellurium.

Cs-Cs salts including the nitrate, acetate, carbonate, and hydroxide are soluble in water and possible catalyst precursors.

Ba-Barium acetate and barium nitrate are both suitable precursors for barium catalyst components.

La-Lanthanum precursors include nitrate, La (N03) 3, acetate, La (OAc) 3, and perchlorate, La (C104) 3, all of which may be prepared as aqueous solutions.

Ce-Ce (III) and Ce (IV) solutions may be prepared from Ce (III) nitrate hexahydrate, Ce (N03) 36H20, (Aldrich) and ammonium cerium (IV) nitrate, (NH4) 2Ce (NO3) 6, (Aldrich), respectively, by dissolution in room temperature water.

Nitric acid, 5 vol. %, may be added to the Ce (III) salt to increase solubility and stability.

Ce (OAc) 3 (Alfa) or Ce (NO3) 4 (Alfa) may also be utilized as a catalyst precursor.

Pr, Nd, Sm and Eu-The nitrate, Ln (N03) 3, or acetate, Ln (02CCH3) 3, are possible catalyst precursors for these lanthanides.

Hf-Hafnoyl chloride and nitrate are both possible precursors. Preparing the hafnoyl nitrate by dissolving Hf (acac) 4 in dilute HN03 at low heat provides a clear stable solution of hafnoyl nitrate.

Ta-Tantalum oxalate solution, Ta20 (C204) 4, available from H. C. Starck, or prepared by dissolving Ta (OEt) 5 in aqueous oxalic acid at 60 °C for 12 hours, is a possible catalyst precursor.

W-Ammonium metatungstate hydrate, (NH4) 6W1203g, is water soluble and a possible tungsten catalyst precursor. H2W04 is reacted with NH40H and NMe40H, respectively, to prepare (NH4) 2WO4 and (NMe4) 2W04 which are both possible precursors.

Re-Rhenium oxide in H202, perrhenic acid, (HRe04), NaRe04 and NH4Re04 are suitable rhenium precursors.

Ir-Hexachloroiridate acid, H2lrC16, potassium hexacyanoiridate and potassium hexanitroiridate are all possible catalyst precursors for iridium.

Pt-Platinum containing catalyst compositions may be prepared by using any one of a number of precursor solutions, such as, Pt (NH3) 4 (NO3) 2 (Aldrich, Alfa, Heraeus, or Strem), Pt (NH3) 2 (NO2) 2 in nitric acid, Pt (NH3) 4 (OH) 2 (Alfa), K2Pt (N02) 4, Pt (N03) 2, PtCl4 and H2PtC16 (chloroplatinic acid). Pt (NH3) 4 (HC03) 2, Pt (NH3) 4 (HP04), (NMe4) 2Pt (OH) 6, H2Pt (OH) 6, K2Pt (OH) 6, Na2Pt (OH) 6 and K2Pt (CN) 6 are also possible choices along with Pt oxalate salts, such as K2Pt (C204) 2. The Pt oxalate salts may be prepared from Pt (NH3) 4 (OH) 2 which is reacted with 1M oxalic acid solution to produce a clear, colorless solution of the desired Pt oxalate salts.

Au-Auric acid, HAuCl4, in dilute HC1 at about 5% Au may be a gold precursor.

Gold nitrate in 0.1 M concentration may be prepared by dissolving HAu (N03) 4 (Alfa) in concentrated nitric acid, followed by stirring at room temperature for 1 week in the dark, then diluting 1: 1 with water to produce a yellow solution. It should be noted that further dilution may result in Au precipitation. More concentrated, 0.25M, for example, gold nitrate may be prepared by starting with Au (OH) 3 (Alfa). NaAu (OH) 4, KAu (OH) 4, and NMe4Au (OH) 4 may each be prepared from Au (OH) 3 dissolved in bases NaOH, KOH, or NMe40H, respectively, in base concentrations ranging from, for instance, 0.25 M or higher.

3. Producing a Hydrogen-rich Syngas The invention also relates to a method for producing a hydrogen-rich gas, such as a hydrogen-rich syngas. An additional embodiment of the invention may be directed to a method of producing a CO-depleted gas, such as a CO-depleted syngas.

A CO-containing gas, such as a syngas contacts with a water gas shift catalyst in the presence of water according to the method of the invention. The reaction preferably may occur at a temperature of less than 450 °C to produce a hydrogen-rich gas such as a hydrogen-rich syngas.

A method of the invention may be utilized over a broad range of reaction conditions. Preferably, the method is conducted at a pressure of no more than about 75 bar, preferably at a pressure of no more than about 50 bar to produce a hydrogen-rich syngas. Even more preferred is to have the reaction occur at a pressure of no more than about 25 bar, or even no more than about 15 bar, or not more than about 10 bar.

Especially preferred is to have the reaction occur at, or about atmospheric pressure.

Depending on the formulation of the catalyst according to the present invention, the present method may be conducted at reactant gas temperatures ranging from less than about 150°C to up to about 450°C. Preferably, the reaction occurs at a temperature selected from one or more temperature subranges of LTS, MTS and/or HTS as described above. Space velocities may range from about 1 hr'1 up to about 1,000, 000 hr'1. Feed ratios, temperature, pressure and the desired product ratio are factors that would normally be considered by one of skill in the art to determine a desired optimum space velocity for a particular catalyst formulation.

4. Fuel Processor Apparatus

The invention further relates to a fuel processing system for generation of a hydrogen-rich gas from a hydrocarbon or substituted hydrocarbon fuel. Such a fuel processing a system would comprise, for example, a fuel reformer, a water gas shift reactor and a temperature controller.

The fuel reformer would convert a fuel reactant stream comprising a hydrocarbon or a substituted hydrocarbon fuel to a reformed product stream comprising carbon monoxide and water. The fuel reformer may typically have an inlet for receiving the reactant stream, a reaction chamber for converting the reactant stream to the product stream, and an outlet for discharging the product stream.

The fuel processor system would also comprise a water gas shift reactor for effecting a water gas shift reaction at a temperature of less than about 450°C. This water gas shift reactor may comprise an inlet for receiving a water gas shift feed stream comprising carbon monoxide and water from the product stream of the fuel reformer, a reaction chamber having a water gas shift catalyst as described herein located therein, and an outlet for discharging the resulting hydrogen-rich gas. The water gas shift catalyst would preferable be effective for generating hydrogen and carbon dioxide from the water gas shift feed stream.

The temperature controller may be adapted to maintain the temperature of the reaction chamber of the water gas shift reactor at a temperature of less than about 450°C.

5. Industrial Applications Syngas is used as a reactant feed in number of industrial applications, including for example, methanol synthesis, ammonia synthesis, oxoaldehyde synthesis from olefins (typically in combination with a subsequent hydrogenation to form the corresponding oxoalcohol), hydrogenations and carbonylations. Each of these various industrial applications preferably includes a certain ratio of H2 to CO in the syngas reactant stream.

For methanol synthesis the ratio of H2 : CO is preferably about 2: 1. For oxosynthesis of oxoaldehydes from olefins, the ratio of H2 : CO is preferably about 1: 1. For ammonia synthesis, the ratio of H2 to N2 (e. g., supplied from air) is preferably about 3: 1. For hydrogenations, syngas feed streams that have higher ratios of H2 : CO are preferred (e. g., feed streams that are Ha enriched, and that are preferably substantially Ha pure feed streams). Carbonylation reactions are preferably effected using feed streams that have

lower ratios of H2 : CO (e. g., feed streams that are CO enriched, and that are preferably substantially CO pure feed streams).

The WGS catalysts of the present invention, and the methods disclosed herein that employ such WGS catalysts, can be applied industrially to adjust or control the relative ratio H2: CO in a feed stream for a synthesis reaction, such as methanol synthesis, ammonia synthesis, oxoaldehyde synthesis, hydrogenation reactions and carbonylation reactions. In one embodiment, for example, a syngas product stream comprising CO and H2 can be produced from a hydrocarbon by a reforming reaction in a reformer (e. g., by steam reforming of a hydrocarbon such as methanol or naphtha). The syngas product stream can then be fed (directly or indirectly after further downstream processing) as the feed stream to a WGS reactor, preferably having a temperature controller adapted to maintain the temperature of the WGS reactor at a temperature of about 450 °C or less during the WGS reaction (or at lower temperatures or temperature ranges as described herein in connection with the catalysts of the present invention). The WGS catalyst (s) employed in the WGS reactor are preferably selected from one or more of the catalysts and/or methods of the invention. The feed stream to the WGS reactor is contacted with the WGS catalyst (s) under reaction conditions effective for controlling the ratio of H2: CO in the product stream from the WGS reactor (i. e., the"shifted product stream") to the desired ratio for the downstream reaction of interest (e. g., methanol synthesis), including to ratios described above in connection with the various reactions of industrial significance. As a non-limiting example, a syngas product stream from a methane steam reformer will typically have a H2: CO ratio of about 6: 1. The WGS catalyst (s) of the present invention can be employed in a WGS reaction (in the forward direction as shown above) to further enhance the amount of H2 relative to CO, for example to more than about 10: 1, for a downstream hydrogenation reaction. As another example, the ratio of H2: CO in such a syngas product stream can be reduced by using a WGS catalyst (s) of the present invention in a WGS reaction (in the reverse direction as shown above) to achieve or approach the desired 2: 1 ratio for methanol synthesis. Other examples will be known to a person of skill in the art in view of the teachings of the present invention.

A person of skill in the art will understand and appreciate that with respect to each of the preferred catalyst embodiments as described in the preceding paragraphs, the

particular components of each embodiment can be present in their elemental state, or in one or more oxide states, or mixtures thereof.

Although the foregoing description is directed to the preferred embodiments of the invention, it is noted that other variations and modifications will be apparent to those skilled in the art, and which may be made without departing from the spirit or scope of the invention.

EXAMPLES General Small quantity catalyst composition samples are generally prepared by automated liquid dispensing robots (Cavro Scientific Instruments) on flat quartz test wafers.

Generally, supported catalysts are prepared by providing a catalyst support (e. g. alumina, silica, titania, etc.) to the wafer substrate, typically as a slurry composition using a liquid-handling robot to individual regions or locations on the substrate or by wash-coating a surface of the substrate using techniques known to those of skill in the art, and drying to form dried solid support material on the substrate. Discrete regions of the support-containing substrate are then impregnated with specified compositions intended to operate as catalysts or catalyst precursors, with the compositions comprising metals (e. g. various combinations of transition metal salts). In some circumstances the compositions are delivered to the region as a mixture of different metal-containing components and in some circumstances (additionally or alternatively) repeated or repetitive impregnation steps are performed using different metal-containing precursors.

The compositions are dried to form supported catalyst precursors. The supported catalyst precursors are treated by calcining and/or reducing to form active supported catalytic materials at discrete regions on the wafer substrate.

The catalytic materials (e. g., supported or bulk) on the substrate are tested for activity and selectivity for the WGS reaction using a scanning mass spectrometer (SMS) comprising a scanning/sniffing probe and a mass spectrometer. More details on the scanning mass spectrometer instrument and screening procedure are set forth in U. S.

Patent No. 6,248, 540, in European Patent No. EP 1019947 and in European Patent Application No. EP 1186892 and corresponding U. S. Application No. 09/652,489 filed August 31,2000 by Wang et al., the complete disclosure of each of which is incorporated herein in its entirety. Generally, the reaction conditions (e. g. contact time

and/or space velocities, temperature, pressure, etc.) associated with the scanning mass spectrometer catalyst screening reactor are controlled such that partial conversions (ie., non-equilibrium conversions, e. g., ranging from about 10% to about 40% conversion) are obtained in the scanning mass spectrometer, for discrimination and ranking of catalyst activities for the various catalytic materials being screened. Additionally, the reaction conditions and catalyst loadings are established such that the results scale appropriately with the reaction conditions and catalyst loadings of larger scale laboratory research reactors for WGS reactions. A limited set of tie-point experiments are performed to demonstrate the scalability of results determined using the scanning mass spectrometer to those using larger scale laboratory research reactors for WGS reactions. See, for example, Example 12 of U. S. Provisional Patent Application Serial No. 60/434,708 entitled"Platinum-Ruthenium Containing Catalyst Formulations for Hydrogen Generation"filed by Hagemeyer et al. on December 20,2002.

Preparative and Testing Procedures The catalysts and compositions of the present invention were identified using high-throughput experimental technology, with the catalysts being prepared and tested in library format, as described generally above, and in more detail below. Specifically, such techniques were used for identifying catalyst compositions that were active and selective as WGS catalysts. As used in these examples, a"catalyst library"refers to an associated collection of candidate WGS catalysts arrayed on a wafer substrate, and having at least two, and typically three or more common metal components (including metals in the fully reduced state, or in a partially or fully oxidized state, such as metal salts), but differing from each other with respect to relative stoichiometry of the common metal components.

Depending on the library design and the scope of the investigation with respect to a particular library, multiple (i. e. , two or more) libraries were typically formed on each wafer substrate. A first group of test wafers each comprised about 100 different catalyst compositions formed on a three-inch wafer substrate, typically with most catalysts being formed using at least three different metals. A second group of test wafers each comprised about 225 different catalyst compositions on a four-inch wafer substrate, again typically with most catalysts being formed using at least three different metals. Each test wafer itself typically comprised multiple libraries. Each library

typically comprised binary, ternary or higher-order compositions-that is, for example, as ternary compositions that comprised at least three components (e. g., A, B, C) combined in various relative ratios to form catalytic materials having a molar stoichiometry covering a range of interest (e. g., typically ranging from about 20% to about 80% or more (e. g. to about 100% in some cases) of each component). For supported catalysts, in addition to varying component stoichiometry for the ternary compositions, relative total metal loadings were also investigated.

Typical libraries formed on the first group of (three-inch) test wafers included, for example,"five-point libraries" (e. g., twenty libraries, each having five different associated catalyst compositions), or"ten-point"libraries (e. g. , ten libraries, each having ten different associated catalyst compositions), or"fifteen-point libraries" (e. g., six libraries, each having fifteen different associated catalyst compositions) or"twenty-point libraries" (e. g. , five libraries, each having twenty different associated catalyst compositions). Typical libraries formed on the second group of (four-inch) test wafers included, for example, "nine-point libraries" (e. g., twenty-five libraries, each having nine different associated catalyst compositions), or"twenty-five point"libraries (e. g., nine libraries, each having twenty-five different associated catalyst compositions). Larger compositional investigations, including"fifty-point libraries" (e. g., two or more libraries on a test wafer, each having fifty associated catalyst compositions), were also investigated. Typically, the stoichiometric increments of candidate catalyst library members ranged from about 1.5 % (e. g. for a"fifty-five point ternary") to about 15 % (e. g., for a"five-point"ternary). See, generally, for example, WO 00/17413 for a more detailed discussion of library design and array organization. Figs. 8A-8F of the instant application shows library designs for libraries prepared on a common test wafer, as graphically represented using Library Studio (Symyx Technologies, Inc. , Santa Clara, CA), where the libraries vary with respect to both stoichiometry and catalyst loading.

Libraries of catalytic materials that vary with respect to relative stoichiometry and/or relative catalyst loading can also be represented in a compositional table, such as is shown in the several examples of this application.

Referring to Fig. 8A, for example, the test wafer includes nine libraries, where each of the nine libraries comprise nine different ternary compositions of the same three- component system. In the nomenclature of the following examples, such a test wafer is

said to include nine, nine-point-ternary ("9PT") libraries. The library depicted in the upper right hand corner of this test wafer includes catalyst compositions comprising components A, B and Xi in 9 different stoichiometries. As another example, with reference to Fig. 8B, a partial test wafer is depicted that includes a fifteen-point-ternary ("15PT") library having catalyst compositions of Pt, Pd and Cu in fifteen various stoichiometries. Generally, the composition of each catalyst included within a library is graphically represented by an association between the relative amount (e. g., moles or weight) of individual components of the composition and the relative area shown as corresponding to that component. Hence, referring again to the fifteen different catalyst compositions depicted on the partial test wafer represented in Fig. 8B, it can be seen that each composition includes Pt (dark grey), Pd (light grey) and Cu (black), with the relative amount of Pt increasing from column 1 to column 5 (but being the same as compared between rows within a given column), with the relative amount of Pd decreasing from row 1 to row 5 (but being the same as compared between columns within a given row), and with the relative amount of Cu decreasing from a maximum value at row 5, column 1 to a minimum at, for example, row 1, column 1. Fig. 8C shows a test wafer that includes a fifty-point-ternary ("50PT") library having catalyst compositions of Pt, Pd and Cu in fifty various stoichiometries. This test library could also include another fifty-point ternary library (not shown), for example with three different components of interest.

Figs. 8D-8F are graphical representations of two fifty-point ternary libraries ("bis 50PT libraries") at various stages of preparation-including a Pt-Au-Ag/CeO2 library (shown as the upper right ternary library of Fig. 8E) and a Pt-Au-Ce/ZrO2 library (shown as the lower left ternary library of Fig. 8E). Note that the Pt-Au-Ag/CeO2 library also includes binary-impregnated compositions-Pt-Au/Ce02 binary catalysts (row 2) and Pt- Ag/CeOa (column 10). Likewise, the Pt-Au-Ce/ZrO2 library includes binary- impregnated compositions-Pt-Ce/Zr02 (row 11) and Au-Ce/ZrO2 (column 1). Briefly, the bis 50PT libraries were prepared by depositing Ce02 and ZrO2 supports onto respective portions of the test wafer as represented graphically in Fig. 8D. The supports were deposited onto the test wafer as a slurry in a liquid media using a liquid handling robot, and the test wafer was subsequently dried to form dried supports. Thereafter, salts of Pt, Au and Ag were impregnated onto the regions of the test wafer containing the

Ce02 supports in the various relative stoichiometries as represented in Fig. 8E (upper- right-hand library). Likewise, salts of Pt, Au and Ce were impregnated onto the regions of the test wafer containing the ZrO2 supports in the various relative stoichiometries as represented in Fig. 8E (lower-left-hand library). Fig. 8F is a graphical representation of the composite library design, including the relative amount of catalyst support.

Specific compositions of tested catalytic materials of the invention are detailed in the following examples for selected libraries.

Performance benchmarks and reference experiments (e. g. , blanks) were also provided on each quartz catalyst test wafer as a basis for comparing the catalyst compositions of the libraries on the test wafer. The benchmark catalytic material formulations included a Pt/zirconia catalyst standard with about 3% Pt catalyst loading (by weight, relative to total weight of catalyst and support). The Pt/zirconia standard was typically synthesized by impregnating 3 u, L of, for example, 1.0% or 2.5 % by weight, Pt stock solution onto zirconia supports on the wafer prior to calcination and reduction pretreatment.

Typically wafers were calcined in air at a temperature ranging from 300 °C to 500°C and/or reduced under a continuous flow of 5 % hydrogen at a temperature ranging from about 200 °C to about 500 °C (e. g., 450°C). Specific treatment protocols are described below with respect to each of the libraries of the examples.

For testing using the scanning mass spectrometer, the catalyst wafers were mounted on a wafer holder which provided movement in an XY plane. The sniffing/scanning probe of the scanning mass spectrometer moved in the Z direction (a direction normal to the XY plane of movement for the wafer holder), and approached in close proximity to the wafer to surround each independent catalyst element, deliver the feed gas and transmit the product gas stream from the catalyst surface to the quadrupole mass spectrometer. Each element was heated locally from the backside using a C02 laser, allowing for an accessible temperature range of about 200° to about 600 °C. The mass spectrometer monitored seven masses for hydrogen, methane, water, carbon monoxide, argon, carbon dioxide and krypton: 2,16, 18,28, 40,44 and 84, respectively.

Catalyst compositions were tested at various reaction temperatures, typically including for example at about 250°C, 300 °C, 350 °C and/or 400°C. Particularly for LTS formulations, testing of catalyst activity at reaction temperatures may start as low as

200°C. The feed gas typically consisted of 51.6 % H2, 7.4 % Kr, 7.4 % CO, 7.4 % C02 and 26.2 % H20. The H2, CO, C02 and Kr internal standard are premixed in a single gas cylinder and then combined with the water feed. Treated water (18.1 mega-ohms-cm at 27. 5°C) produced by a Barnstead Nano Pure Ultra Water system was used, without degassing.

Data Processing and Analysis Data analysis was based on mass balance plots where CO conversion was plotted versus C02 production. The mass spectrometer signals were uncalibrated for CO and C02 but were based on Kr-normalized mass spectrometer signals. The software package SpotFireTM (sold by SpotFire, Inc. of Somerville, Massachusetts) was used for data visualization.

A representative plot of CO conversion versus C02 production for a WGS reaction is shown in Fig. 9A involving, for discussion purposes, two ternary catalyst systems-a Pt-Au-Ag/Ce02 catalyst library and a Pt-Au-Ce/Zr02 catalyst library-as described above in connection with Figs. 8D-8F. The catalyst compositions of these libraries were screened at four temperatures: 250 °C, 300 °C, 350 °C and 400 °C. With reference to the schematic diagram shown in Fig. 9B, active and highly selective WGS catalysts (e. g., Line I of Fig. 9B) will approach a line defined by the mass balance for the water-gas-shift reaction (the"WGS diagonal") with minimal deviation, even at relatively high conversions (i. e. , at CO conversions approaching the thermodynamic equilibrium conversion (point"TE"on Fig. 9B) ). Highly active catalysts may begin to deviate from the WGS diagonal due to cross-over to the competing methanation reaction (point"M" on Fig. 9C). Catalyst compositions that exhibit such deviation may still, however, be useful WGS catalysts depending on the conversion level at which such deviation occurs.

For example, catalysts that first deviate from the WGS diagonal at higher conversion levels (e. g., Line II of Fig. 9B) can be employed as effective WGS catalysts by reducing the overall conversion (e. g., by lowering catalyst loading or by increasing space velocity) to the operational point near the WGS diagonal. In contrast, catalysts that deviate from the WGS diagonal at low conversion levels (e. g., Line III of Fig. 9B) will be relatively less effective as WGS catalysts, since they are unselective for the WGS reaction even at low conversions. Temperature affects the thermodynamic maximum CO conversion, and can affect the point of deviation from the mass-balance WGS diagonal as well as the

overall shape of the deviating trajectory, since lower temperatures will generally reduce catalytic activity. For some compositions, lower temperatures will result in a more selective catalyst, demonstrated by a WGS trajectory that more closely approximates the WGS mass-balance diagonal. (See Fig. 9C). Referring again to Fig. 9A, it can be seen that the Pt-Au-Ag/CeO2 and the Pt-Au-Ce/ZrOa catalyst compositions are active and selective WGS catalysts at each of the screened temperatures, and particularly at lower temperatures.

Generally, the compositions on a given wafer substrate were tested together in a common experimental run using the scanning mass spectrometer and the results were considered together. In this application, candidate catalyst compositions of a particular library on the substrate (e. g., ternary or higher-order catalysts comprising three or more metal components) were considered as promising candidates for an active and selective commercial catalyst for the WGS reaction based on a comparison to the Pt/ZrOa standard composition included on that wafer. Specifically, libraries of catalytic materials were deemed to be particularly preferred WGS catalysts if the results demonstrated that a meaningful number of catalyst compositions in that library compared favorably to the Pt/ZrO2 standard composition included on the wafer substrate with respect to catalytic performance. In this context, a meaningful number of compositions was generally considered to be at least three of the tested compositions of a given library. Also in this context, favorable comparison means that the compositions had catalytic performance that was as good as or better than the standard on that wafer, considering factors such as conversion, selectivity and catalyst loading. All catalyst compositions of a given library were in many cases positively identified as active and selective WGS catalysts even in situations where only some of the library members compared favorably to the Pt/Zr02 standard, and other compositions within that library compared less than favorably to the Pt/ZrOa standard. In such situations, the basis for also including members of the library that compared somewhat less favorably to the standard is that these members in fact positively catalyzed the WGS reaction (i. e. , were effective as catalysts for this reaction).

Additionally, it is noted that such compositions may be synthesized and/or tested under more optimally tuned conditions (e. g. , synthesis conditions, treatment conditions and/or testing conditions (e. g. , temperature) ) than occurred during actual testing in the library format, and significantly, that the optimal conditions for the particular catalytic materials

being tested may differ from the optimal conditions for the Pt/ZrOa standard-such that the actual test conditions may have been closer to the optimal conditions for the standard than for some of the particular members. Therefore, it was specifically contemplated that optimization of synthesis, treatment and/or screening conditions, within the generally defined ranges of the invention as set forth herein, would result in even more active and selective WGS catalysts than what was demonstrated in the experiments supporting this invention. Hence, in view of the foregoing discussion, the entire range of compositions defined by each of the claimed compositions (e. g. , each three-component catalytic material, or each four-component catalytic material) was demonstrated as being effective for catalyzing the WGS reaction. Further optimization is considered, with various specific advantages associated with various specific catalyst compositions, depending on the desired or required commercial application of interest. Such optimization can be achieved, for example, using techniques and instruments such as those described in U. S. Patent No. 6,149, 882, or those described in WO 01/66245 and its corresponding U. S. applications, U. S. Ser. No. 09/801,390, entitled"Parallel Flow Process Optimization Reactor"filed March 7,2001 by Bergh et al. , and U. S. Ser. No.

09/801,389, entitled"Parallel Flow Reactor Having Variable Feed Composition"filed March 7,2001 by Bergh et al. , each of which are incorporated herein by reference for all purposes.

Additionally, based on the results of screening of initial libraries, selective additional"focus"libraries were selectively prepared and tested to confirm the results of the initial library screening, and to further identify better performing compositions, in some cases under the same and/or different conditions. The test wafers for the focus libraries typically comprised about 225 different candidate catalyst compositions formed on a four-inch wafer substrate, with one or more libraries (e. g. associated ternary compositions A, B, C) formed on each test wafer. Again, the metal-containing components of a given library were typically combined in various relative ratios to form catalysts having stoichiometry ranging from about 0% to about 100% of each component, and for example, having stoichiometric increments of about 10 % or less, typically about 2 % or less (e. g. , for a"fifty-six point ternary"). Focus libraries are more generally discussed, for example, in WO 00/17413. Such focus libraries were evaluated according to the protocols described above for the initial libraries.

The raw residual gas analyzer ("rga") signal values generated by the mass spectrometer for the individual gases are uncalibrated and therefore different gases may not be directly compared. Methane data (mass 16) was also collected as a control. The signals are typically standardized by using the raw rga signal for krypton (mass 84) to remove the effect of gas flow rate variations. Thus, for each library element, the standardized signal is determined as, for example, sH20 = raw Ha0/raw Kr; sCO = raw CO/raw Kr; sCO2 = raw C02/raw Kr and so forth.

Blank or inlet concentrations are determined from the average of the standardized signals for all blank library elements, i. e. library elements for which the composition contains at most only support. For example, bvg H20 = average sH20 for all blank elements in the library; bavg CO = average sCO for all blank elements in the library; and so forth.

Conversion percentages are calculated using the blank averages to estimate the input level (e. g., bavg CO) and the standardized signal (e. g., sCO) as the output for each library element of interest. Thus, for each library element, COconversion = 100 x (bavg CO- sCO)/bavg CO and H20oonversion = 100 x (bavg H20-sH20)/bavg H20.

The carbon monoxide (CO) to carbon dioxide (C02) selectivity is estimated by dividing the amount of C02 produced (sCO2-bavg CO2) by the amount of CO consumed (bavg CO-sCO). The COa and CO signals are not directly comparable because the rga signals are uncalibrated. However, an empirical conversion constant (0.6 C02 units = 1 CO unit) has been derived, based on the behavior of highly selective standard catalyst compositions. The selectivity of the highly selective standard catalyst compositions approach 100 % selectivity at low conversion rates. Therefore, for each library element, estimated CO to C02 selectivity = 100 x 0.6 x (sCO2-bavg C02)/ (bavg CO-sCO). Low CO consumption rates can produce highly variable results, and thus the reproducibility of C02 selectivity values is maintained by artificially limiting the C02 selectivity to a range of 0 to 140%.

The following examples are representative of the screening of libraries that lead to identification of the particularly claimed inventions herein.

Example 1:

A 4"quartz wafer with 256 wells was precoated with zirconia carrier by repeated slurry dispensing zirconia (ZrO2 Norton XZ16052/MEI FZ0923 70: 30 mixture, 2x 4 gl = 8 ul zirconia slurry, 1 g ZrO2 mix slurried in 4 ml EG/Ha0 1: 1) onto the wafer.

The zirconia carrier-precoated wafer was dried and then impregnated with Pt by Cavro dispensing from a Pt (NH3) 2 (NO2) 2 stock solution (5 wt. % Pt) to a microtiter plate (5-point ("5P") Pt gradient) followed by transferring replicas (i. e. , repeated daughtering) of the 5P Pt gradient onto the wafer (3 gel dispense volume per well, 45 replicas = 45 identical 5-point Pt gradients on the wafer).

The wafer was dried and then impregnated with Rh by Cavro dispensing from a Rh nitrate stock solution vial (1% Rh) to a microtiter plate (5-point Rh gradient) followed by transferring replicas of the 5P Rh gradient onto the wafer (3 pi dispense volume per well, 45 replicas = 45 identical 5-point Rh gradients on the wafer).

The wafer was dried and then impregnated with nine different metals by Cavro dispensing from metal precursor stock solutions (Ag, Cu nitrate ; Sn, Sb, Ge oxalate ; Fe, Ce, Co nitrate ; Ti oxalate) to a microtiter plate (5-point metal gradients) followed by transferring replicas of the 5P metal gradients onto the wafer (3 u, l dispense volume per well, 5 replicas per metal = 5 identical 5-point metal gradients on the wafer for each of the 9 metals).

Thus, the nine 25-point ternaries Pt-Rh- {Ag, Cu, Sn, Sb, Ge, Fe, Ce, Co, Ti} are mapped out as 5 by 5 squares with orthogonal gradients. Six internal Pt/ZrO2 standards were spotted in the first row and last column (4 jj. l Zr02 slurry/dry/3 u, l Pt (NH3) 2 (N02) 2 (2.5% Pt). Commercial catalyst was slurried into five positions of the first row and last column as external standards (3 1 catalyst slurry). See Figs. lA-lD.

The wafer was dried, calcined in air at 450 °C for 2 hours and then reduced in 5% H2/Ar at 450 °C for 2 hours. The reduced library was then screened by SMS for WGS activity with a Ha/CO/COa/Ha0 mixed feed at 250 °C, 300 °C, 350 °C and 400 °C. Results at 250 °C, 300 °C, 350 °C and 400 °C are presented in Figs. lE-lI.

It was found that Rh can efficiently be moderated by Pt and that Pt-Rh forms a synergistic pair. It was realized that the activity/selectivity of Pt-Rh combination can be fine-tuned by selection of dopants among the synergistic moderators Ce, Ti, Ag, Sb, Ge and Fe. Pt-Rh-{Ce, Ti} were found to be the most active and promising for high flow

HTS application. Pt-Rh-{Ag, Au, Sb, Ge, Fe} were found to be more selective and therefore promising for MTS and/or HTS applications.

Example 2: A 4"quartz wafer with 256 wells was precoated with zirconia carrier by repeated slurry dispensing zirconia (Zr02 Norton XZ16052/MEI FZ0923 70: 30 mixture, 2x 4 = 8 u. l zirconia slurry, 1 g Zr02 mix slurried in 4 ml EG/H20 1: 1) onto the wafer.

The zirconia carrier-precoated wafer was dried and then impregnated with Pt by Cavro dispensing from a Pt (NH3) 2 (NO2) 2 stock solution (2. 5% Pt) directly onto the wafer 3 11 dispense volume/well). Six internal standards were spotted into 6 first row/last column wells (4 u, l zirconia slurry + 3 1 2. 5% Pt solution).

The wafer was dried and then impregnated with CoRu and RuPt gradients by Cavro dispensing from Co nitrate (0.5M Co), Ru nitrosyl nitrate (1% Ru) and Pt (NH3) 2 (NO2) 2 (5% Pt) stock solution vials to a microtiter plate followed by transferring replicas of the 8-point and 7-point gradients onto the wafer (3 ul dispense volume/well).

The wafer was dried and then impregnated with FeCo by Cavro dispensing from Fe nitrate (1M Fe) and Co nitrate (0. 5M Co) stock solution vials to a microtiter plate (8- point and 7-point gradients) followed by transferring replicas of the Fe-Ha0 and Fe-Co gradients onto the wafer (3 gel dispense volume per well). The wafer was dried and then impregnated with Pt by Cavro dispensing from a Pt (NH3) 2 (NO2) 2 stock solution (2.5% Pt) directly onto the wafer 3 lil dispense volume/well).

Thus four sub-libraries: 8x8 quaternary Pt-Ru-Co-Fe (Pt first) and 8x7 quaternary Pt-Ru-Co-Fe (Pt last, to check the effect of order of Pt addition) and 7x8 ternary Ru-Co- Fe and 7x7 quaternary Pt-Ru-Co-Fe are mapped out as rectangles/squares with orthogonal gradients. The wafer was dried, calcined in air at 500 °C for 1 hour and then reduced in 5% H2/Ar at 400 °C for 3 hours. Commercial catalyst was slurried into five positions of the first row and last column as external standards (3 1 catalyst slurry). See Figs. 2A-2D.

The reduced library was then screened in SMSII for WGS activity with a H2/CO/CO2/H20 mixed feed at 250°C, 300°C, 350°C and 400°C. This set of experiments demonstrated active and selective WGS catalyst formulations of various

{Pt, blank}-{Ru-Co-Fe}/ZrO2 formulations, with Pt present as either a first or last layer on the wafer.

Example 3: A 4"quartz wafer was precoated with Norton XZ 16052 Zr02, Norton XT TiO2 and Aldrich Ce02 by slurry dispensing lx 6 pL slurry, (700 mg XZ16052 and 300 mg FZO ZrO2 slurried in 4 mL EG/H20 5 : 5; 500 mg Ti02 slurried in 4 mL EG/H20 5: 5; Ig Ce02 slurried in 3 mL EG/H20 5: 5) onto the wafer. The precoated wafer has dried and then six internal standards were spotted into six first row/last column wells (4 pL zirconia slurry + 3 JAL 2.5% Pt (NH3) 2 (NO2) 2 solution). The wafer was dried and then impregnated by Cavro dispensing with gradients of Co nitrate (1M Co), Ti oxalate (1M Ti), Mo oxalate (1M Mo) from stock solutions to a microtiter plate followed by transferring 15 replicas onto the wafer (3 uL dispense volume/well).

The wafer was dried and then impregnated by Cavro dispensing with Ru nitrosylnitrate (1. 5% Ru) and Pt (NH3) 2 (NO2) 2 (5% Pt) from stock solution vials to a microtiter plate followed by transferring replicas onto the wafer (3 pL dispense volume/well). Commercial catalyst was slurried into five positions of the first row and last column as external standards (3 Rl catalyst slurry). See Figs. 3A-3C.

The wafer was dried, calcined at 450°C in air and then reduced in 5% H2/Ar at 450 °C for 2 hours. The reduced library was then screened by SMS for WGS activity with a H2/CO/CO2/H20 mixed feed at 250°C, 300°C, 350°C and 400°C. This set of experiments demonstrated active and selective WGS catalyst formulations of various {Co, Ti, Mo}- {Pt-Ru}/ {Zr02, Ti02, Ce02} formulations on the wafer.

Example 4: A 3"quartz wafer was coated with niobia, ceria and magnesia carriers by slurry- dispensing aqueous carrier slurries onto the wafer (4 u, l slurry/well, 1 g of carrier powder slurried in 2 ml H20 for niobia and ceria; 500 mg of carrier powder slurried in 2 ml H20 for magnesia). Niobia carriers were produced by Norton, product numbers 2001250214, 2000250356,2000250355, 2000250354 and 2000250351. Cerias came from Norton (product numbers 2001080053,2001080052 and 2001080051) and Aldrich (product number 21, 157-50. Magnesia was obtained from Aldrich (product number 24,338-8).

The carrier precoated wafer was then loaded with the same Pt gradient for each carrier in a single impregnation step by liquid dispensing 3 jj. l Pt (NH3) 2 (NO2) 2 solution (5 % Pt) from microtiter plate to wafer. The wafer was dried and then reduced in 5% H2/Ar at 450 °C for 2 hours. See Figs. 4A-4C.

The reduced library was then screened in SMS for WGS activity with a H2/CO/CO2/H20 mixed feed at 250 °C, 300 °C, 350 °C and 400 °C. Results at 250 °C, 300 °C, 350 °C and 400 °C are presented in Figs. 4D-4H.

This set of experiments demonstrated active and selective WGS catalyst formulations of various Pt on one of Nb oxide, Ce oxide or Mg oxide formulations on the wafer. Various Norton niobia carriers were found to be very active and selective over a broad temperature range. Norton ceria 2001080051 was found to be very selective at higher temperatures. Magnesia was less active than either of niobia or ceria but did exhibit highly selective WGS performance.

Example 5- A 4"quartz wafer was precoated with zirconia carrier by repeated slurry dispensing zirconia powder (Norton XZ16052) onto the wafer. The slurry was composed of 1. 5g zirconia powder in 4 mL of a MEO/EG/Ha0 40: 30: 30 mixture. A total of 3 uL of slurry was deposited on each spot.

The zirconia carrier precoated wafer was impregnated with a 7 point concentration gradient of Ti, Zr, V, Mo and Co and an 8 point concentration gradient of Ge, Sn, Sb, La and Ce by Cavro dispensing from metal stock solution vials to a microtiter plate (single column 7-point ("7P") and 8-point ("8P") concentration gradients, respectively followed by transferring replicas of the four 7P and 8P columns onto the wafer (2.5 p1 dispense volume per well). La, Ce, Zr and Co were provided as their nitrates, Ti as the ammonium titanyl oxalate, Sb as the ammonium antimony oxalate, Mo as molybdic acid and V, Ge and Sn as the oxalates.

The wafer was dried at 70 °C for 10 minutes and then impregnated with Fe, Ru and Rh concentration gradients by Cavro dispensing from Fe nitrate (0.5 M Fe), Ru nitrosyl nitrate (0.5 % Ru) and Rh nitrate (0.5% Rh) stock solution vials to a microtiter plate (single row 7-point and 8-point gradients) followed by transferring replicas of the three 7P and 8P rows onto the wafer (2.5 jj. l dispense volume per well). The wafer was

dried at 70 °C for 10 minutes and was then uniformly coated with 2.5 pl/well of a Pt (NH3) 2 (NO2) 2 stock solution (1% Pt). The wafer was calcined in air at 450 °C for 2 hours followed by reduction with 5% H2/N2 at 450 °C for 2 hours. Six internal standards were synthesized by spotting 3 ul Pt (NH3) 2 (NO2) 2 solution (1. 0% Pt) into the corresponding first row/last column positions. See Figs. 5A-5G.

The reduced library was then screened in SMS for WGS activity with a H2/CO/CO2/H20 mixed feed at 300 °C and 350 °C. The CO conversion versus C02 production results at 300 °C and 350 °C are presented in Figs. 5H, 51, and 5J. More detailed test results, such as, CO conversion, C02 production and CH4 production at 300 °C and 350 °C for each of the 225 individual catalyst wells on the test wafer are presented in Table 1.

This set of experiments demonstrated active and selective WGS catalyst formulations of various Pt- [Fe, Ru, Rh}-{Ti, Zr, V, Mo, Co, Ge, Sn, Sb, La, Ce}/Zr02 formulations on the wafer.

Example 6- A 4"quartz wafer was coated with fourteen different catalyst carriers by slurry- dispensing the carrier slurries onto the wafer. Each wafer column was coated with a different carrier, except for columns 14 and 15 which were both coated with gamma- alumina, described below: 1) Ceria, 99.5 % purity; 9 to 15 nm particle size; BET (m2/g) : 55-95; Alfa 43136; dispensed onto the wafer from a slurry of 0.75 g powder slurried in 4 mL ethylene glycol ("EG")/H20/MEO 40: 30: 30 mixture.

2) Ceria, produced by the low temperature calcination of precipitated Ce hydroxide ; dispensed onto the wafer from a slurry of 1.5 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

3) Zirconia; 99.8 % purity; BET (m2/g) : greater than 90; Norton XZ16052; dispensed onto the wafer from a slurry of 1.5 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

4) Zirconia; 99.8 % purity; BET (m2/g) : 269; Norton XZ16154; dispensed onto the wafer from a slurry of 1.5 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

5) Titania; BET (m2/g) : 45; Degussa Aerolyst 7708; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

6) Titania; 99 % purity; BET (m2/g) : 37; Norton XT25384; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

7) Niobia; 97 % purity; BET (m2/g) : 27; Norton 355; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

8) Lanthania; 99.999 % purity; Gemre-5N from Gemch Co. , Ltd. (Shanghai, China); dispensed onto the wafer from a slurry of 1.5 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

9) Mixed Fe-Ce-O ; coprecipitated Fe and Ce oxalate; calcined at 360 °C ; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

10) Mixed La-Ce-0 ; coprecipitated La and Ce oxalate; calcined at 760 °C ; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

11) Mixed Sb304-SnO2 carrier from Alfa; 99.5% purity; BET (m2/g) : 30-80; Sb304: SnO2 ratio is 10: 90 by weight; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

12) Mixed Fe-Cr-Al-O ; commercially available high temperature water gas shift catalyst; dispensed onto the wafer from a slurry of 1.0 powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

13) Fe203/FeOOH ; BET (m2/g) : 14; 50: 50 physical mixture of commercial powders (Bayferrox 720N: Bayoxide E3920 from Bayer); dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

14 and 15) Gamma-AI203 ; BET (m2/g) : 150; Condea Catalox Sbal50 ; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H20/MEO 40: 30: 30 mixture.

In all cases, except for carrier 1, the slurries were applied in 3 ZL per well; carrier 1 was deposited as two aliquots of 3 ul/well. The wafer was then dried at 70 °C for 10 minutes.

Columns 14 and 15 were coated with 2. 5 uL per well of zirconyl nitrate (0.25M) and lanthanum nitrate (0.25M), respectively, then dried for 10 minutes at 70 °C. The first 13 columns of the carrier coated wafer were then loaded with a 15 point Pt gradient by liquid dispensing of 3 uL Pt (NH3) 2 (NO2) 2 solution (1 % Pt) from microtiter plate to wafer. The wafer was dried at 70 °C for 10 minutes. Columns 14 and 15 were then loaded with a 15 point Pt gradient by liquid dispensing of 3 gL Pt (NH3) 2 (NO2) 2 solution (1 % Pt) from microtiter plate to wafer. The wafer was dried at 70 °C for 10 minutes, calcined in air at 350 °C for 2 hours, then reduced in 5 % H2/Ar at 450 °C for 2 hours.

Six internal standards were synthesized by spotting 3 pL PtH3) 2 (NO2) 2 solution (1.0 % Pt) into the corresponding first row/last column positions. See Figs. 6A-6F.

The reduced library was then screened in SMS for WGS activity with a H2/CO/CO2/H20 mixed feed at 250 °C and 300 °C. The CO conversion versus COa production results at 250 °C and 300 °C are presented in Figs. 6G, 6H, and 6I. More detailed test results, such as, CO conversion, C02 production and CH4 production at 250 °C and 300 °C for each of the 225 individual catalyst wells on the test wafer are presented in Table 2.

This set of experiments demonstrated active and selective WGS catalyst formulations of various Pt on various of the oxide carrier formulations on the wafer.

Example 7: Scale-up catalyst samples were prepared by using incipient wetness impregnation of 0.75 grams of Zr02 support (Norton, 80-120 mesh) which had been weighed into a 10- dram vial. Aqueous metal precursor salt solutions were then added in the order: Rh, Co, Fe, Mo, V, Pt, and finally K. The precursor salt solutions were tetraammineplatinum (II) hydroxide solution (9.09 % Pt (w/w) ), rhodium (III) nitrate (1.0 % Rh (w/w) ), cobalt (II) nitrate (1. OM), molydbic acid (1. OM), vanadium citrate (1. OM), iron (III) nitrate (1. OM), and potassium hydroxide (13.92 % K (w/w) ). All reagents were nominally research grade from Aldrich, Strem, or Alfa. Following each metal addition, the catalysts were dried at 80° C overnight and then calcined in air as follows: After Pt addition--300 °C for 3 hours After Rh, Co, or Fe addition--450 °C for 3 hours After Mo or V addition--350 °C for 3 hours.

Following K addition, the catalysts were calcined at 300 °C for 3 hours, then the catalysts were reduced in-situ at 300 °C for 3 hours in a 10% H2/N2 feed.

Catalyst Testing Conditions Catalysts were tested in a fixed bed reactor. Approximately 0.15 g of catalyst was weighed and mixed with an equivalent mass of SiC. The mixture was loaded into a reactor and heated to reaction temperature. Reaction gases were delivered via mass flow controllers (Brooks) with water introduced with a metering pump (Quizix). The composition of the reaction mixture was as follows: H2 50%, CO 10%, C02 10%, and H20 30%. The reactant mixture was passed through a pre-heater before contacting the catalyst bed. Following reaction, the product gases were analyzed using a micro gas chromatograph (Varian Instruments, or Shimadzu). Compositional data on the performance diagram (Fig. 7) is on a dry basis with water removed.

Testing Results Fig. 7 shows the CO composition in the product stream following the scale-up testing at a gas hour space velocity of 50,000 h-1.

Table 3: Catalyst Compositions (mass ratio) Row'Col Pt Co Rh K Mo V Fe A 1 0.9095 0.06 0.005 0.0005 0. 025 0 0 0 A 2 0.909 0.06 0.005 0.001 0. 025 0 0 0 A 3 0.9045 0.06 0.01 0.0005 0. 025 0 0 0 A 4 0.904 0.06 0.01 0.001 0. 025 0 0 0 A 5 0.8995 0.06 0.015 0.0005 0. 025 0 0 0 A 6 0.899 0.06 0.015 0.001 0. 025 0 0 0 B 1 0.9095 0. 06 0 0.0005 0.025 0. 005 0 0 B 2 0.909 0. 06 0 0.001 0.025 0. 005 0 0 B 3 0.9045 0. 06 0 0.0005 0.025 0. 01 0 0 B 4 0.904 0. 06 0 0.001 0.025 0. 01 0 0 B 5 0.8995 0. 06 0 0.0005 0. 025 0. 015 0 0 B 6 0.899 0. 06 0 0.001 0.025 0. 015 0 0 C 1 0.9135 0. 06 0 0.0005 0. 025 0 0. 001 0 C 2 0.913 0. 06 0 0.001 0. 025 0 0. 001 0 C 3 0.9125 0. 06 0 0.0005 0. 025 0 0. 002 0 C 4 0.912 0. 06 0 0.001 0. 025 0 0. 002 0 C 5 0.9115 0. 06 0 0.0005 0. 025 0 0. 003 0 C 6 0.911 0. 06 0 0.001 0. 025 0 0.003 0 D 1 0.9095 0. 06 0 0. 0005 0. 025 0 0 0.005 Row Col Support Pt Co Rh K Mo V Fe D 2 0.909 0. 06 0 0.001 0. 025 0 0 0.005 D 3 0.9045 0. 06 0 0.0005 0. 025 0 0 0. 01 D 4 0.904 0. 06 0 0.001 0. 025 0 0 0.01 D 5 0. 8995 0. 06 0 0.0005 0. 025 0 0 0.015 D 6 0. 899 0. 06 0 0. 001 0. 025 0 0 0. 015

Example 8: Scale-up catalyst samples were prepared by using incipient wetness impregnation of 0.75 grams of ZrO2 support (Norton, 80-120 mesh) which had been weighed into a 10- dram vial. Aqueous metal precursor salt solutions were then added in the order: Rh, Co, Fe, Mo, V, Pt, and finally Na. The precursor salt solutions were tetraammineplatinum (II) hydroxide solution (9.09 % Pt (w/w) ), rhodium (III) nitrate (1.0 % Rh (w/w) ), cobalt (II) nitrate (1. OM), molydbic acid (1. OM), vanadium citrate (1. OM), iron (III) nitrate (1. OM), and sodium hydroxide (3.0 N). All starting reagents were nominally research grade from Aldrich, Strem, or Alfa. Following each metal addition, the catalysts were dried at 80° C overnight and then calcined in air as follows: After Pt addition--300 °C for 3 hours After Rh, Co, or Fe addition--450 °C for 3 hours After Mo or V addition--350 °C for 3 hours.

Following Na addition, the catalysts were calcined at 300 °C for 3 hours, then the catalysts were reduced in-situ at 300 °C for 3 hours in a 10% H2/N2 feed.

Catalyst Testing Conditions Catalysts were tested in a fixed bed reactor. Approximately 0.15 g of catalyst was weighed and mixed with an equivalent mass of SiC. The mixture was loaded into a reactor and heated to reaction temperature. Reaction gases were delivered via mass flow controllers (Brooks) with water introduced with a metering pump (Quizix). The composition of the reaction mixture was as follows: Ha 50%, CO 10%, C02 10%, and Ha0 30%. The reactant mixture was passed through a pre-heater before contacting the catalyst bed. Following reaction, the product gases were analyzed using a micro gas chromatograph (Varian Instruments, or Shimadzu). Compositional data on the performance diagrams (Figs. 10A-10C) is on a dry basis with water removed.

Testing Results

Figs. lOA-lOC show the CO composition in the product stream following the scale-up testing at a gas hour space velocity of 50,000 h-1.

Table 4: Catalyst Compositions (mass ratio) Row Col Zr02 Co Water Rh Pt Na Fe Mo V A 1 90.90 0.50 0.00 0.10 6.00 2.50 0.00 0.00 0.00 A 2 90.80 0.50 0.00 0.20 6.00 2.50 0.00 0.00 0.00 A 3 90.40 1.00 0.00 0.10 6.00 2.50 0.00 0.00 0.00 A 4 90.30 1.00 0.00 0.20 6.00 2.50 0.00 0.00 0.00 B 1 90.90 0.00 0.00 0.10 6.00 2.50 0.50 0.00 0.00 B 2 90.80 0.00 0.00 0.20 6.00 2.50 0.50 0.00 0.00 B 3 90.40 0.00 0.00 0.10 6.00 2.50 1.00 0.00 0.00 B 4 90.30 0.00 0.00 0.20 6.00 2.50 1.00 0.00 0.00 C 1 90.90 0.00 0.00 0.10 6.00 2.50 0.00 0.50 0.00 C 2 90.80 0.00 0.00 0.20 6.00 2.50 0.00 0.50 0.00 C 3 90.40 0.00 0.00 0.10 6.00 2.50 0.00 1.00 0.00 C 4 90.30 0.00 0.00 0.20 6.00 2.50 0.00 1.00 0.00 D 1 90.40 0.00 0.00 0.10 6.00 2.50 0.00 0.00 1.00 D 2 90.30 0.00 0.00 0.20 6.00 2.50 0.00 0.00 1.00 D 3 89.40 0.00 0.00 0.10 6.00 2.50 0.00 0.00 2.00 D 4 89.30 0.00 0.00 0.20 6.00 2.50 0.00 0.00 2.00 Example 9: Scale-up catalyst samples were prepared by using incipient wetness impregnation of 0.75 grams of ZrO2 support (Norton, 80-120 mesh) which had been weighed into a 10- dram vial. Aqueous metal precursor salt solutions were then added in the order: Rh, Co, Fe, Mo, V and Pt, . The precursor salt solutions were tetraammineplatinum (II) hydroxide solution (9.09 % Pt (w/w)), rhodium (III) nitrate (1.0 % Rh (w/w) ), cobalt (II) nitrate (1. OM), molydbic acid (1. OM), vanadium citrate (1. OM), and iron (III) nitrate (1. OM). All starting reagents were nominally research grade from Aldrich, Strem, or Alfa. Following each metal addition, the catalysts were dried at 80° C overnight and then calcined in air as follows: After Pt addition--300 °C for 3 hours After Rh, Co, or Fe addition--450 °C for 3 hours After Mo or Vaddition--350 °C for 3 hours.

Following the final addition, the catalysts were reduced in-situ at 300 °C for 3 hours in a 10% H2/N2 feed.

Catalyst Testing Conditions Catalysts were tested in a fixed bed reactor. Approximately 0.15 g of catalyst was weighed and mixed with an equivalent mass of SiC. The mixture was loaded into a reactor and heated to reaction temperature. Reaction gases were delivered via mass flow controllers (Brooks) with water introduced with a metering pump (Quizix). The composition of the reaction mixture was as follows: H2 50%, CO 10%, CO2 10%, and H20 30%. The reactant mixture was passed through a pre-heater before contacting the catalyst bed. Following reaction, the product gases were analyzed using a micro gas chromatograph (Varian Instruments, or Shimadzu). Compositional data on the performance diagrams (Figs. 11A and 11B) is on a dry basis with water removed.

Testing Results Figs. l lA and B show the CO composition in the product stream following the scale-up testing at a gas hour space velocity of 50,000 h-1.

Table 5: Catalyst Compositions (mass ratio) Row Col Zr02 Co Water Rh Pt Fe Mo V B 3 92.90 0.00 0.00 0.10 6.00 1.00 0.00 0.00 B 4 92.80 0.00 0.00 0.20 6.00 1.00 0.00 0.00 C 1 93.40 0.00 0.00 0.10 6.00 0.00 0.50 0.00 C 2 93.30 0.00 0.00 0.20 6.00 0.00 0.50 0.00 C 3 92.90 0.00 0.00 0.10 6.00 0.00 1.00 0.00 C 4 92.80 0.00 0.00 0.20 6.00 0.00 1.00 0.00 D 1 92.90 0.00 0.00 0.10 6.00 0.00 0.00 1.00 D 2 92.80 0.00 0.00 0.20 6.00 0.00 0.00 1.00 D 3 91.90 0.00 0.00 0.10 6.00 0.00 0.00 2.00 D 4 91.80 0.00 0.00 0.20 6.00 0.00 0.00 2.00 Table I Temp crate e : 3*onc IN C COCON H20C0 C02PRO C02PER CH4PRO Ptl. 0% CoN03 FeN033 GeOX2 H2Mo LaN033 NH42 NH46 PtNF132 RhN03 RuNON SnOX2 VOX2 ZrONO SUM_m mol% mot% mol% mol% mol% mol% mol% mol% mol% mol% mol% mol% V NV D PROD D Er022 04 TiOOOX3 N022 3 033 32 icromol Co mol% Ge Mo La Ti Sb Pt Rh Ru Sn V Zr std X2 s Fe real réal real real real real real real real real real real real real real real real real real treat réal 1 1-25. 8564 17. 3624 0. 9641 34. 8524 0. 0188 0000) 0000 000000000000] 00000 1 3-3. 2594-1. 1661 0. 0166 0. 5998 0. 0121 00000] 0000000000000000000000 1 4-2. 9732-3. 7232 0. 008 0. 0087 0 00]) 0000000 00000000000000 3 1 5-2. 8279-4. 1686-0. 0176-0. 636 0. 0037 00) 00000000000000)] 00000000) 16-0. 8995-1. 8273 0. 0207 0. 7469 0. 007 0 000) 0) 0) 000 3000) 000000000) 1 7 29. 8929 15. 3753 0. 9475 34. 2529 0. 1713 M275) 0000000000000. 127500) 0000100 00000 180. 2455-0. 77860. 0364 1. 317 0. 0059 0] 000) 0) 00000) 000) 0000 000000 19 1. 8628 1. 8933 0. 0797 2. 8821 0. 0104 0) 000) 000] 0000000) 0000000000 1 10-1. 0457-1. 7441-0. 0214-0. 7745 0. 0034 0) 00 00) 0) 0000000) 000000000) 1 11-0. 9415-1. 632-0. 0272-0. 9819-0. 00320] 00000000000 0000]] 000000000 12-1. 4473-2. 099-0. 0436-1. 5778-0. 00670000000000000000000000000000 1 13 29. 7322 15. 3924 0. 922 33. 3294 0. 1512 0. 1275 0 0 0 0 0 0 0 0 0 0 0 0 0. 1275 0 0 0 0 0 0 0 100 0 0 0 0 0 14-0. 4246-0. 0063-0. 0224. 0, 8114-0. 005 0) 000 J0) 0) 000) 000] 000000000) 15-0. 9697-0. 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0 0. 0245 0 0 1-1. 152 0 0 0 0 0 0 0 11. 07 0 2. 13 0 0 86. 81 2 8 30. 0483 18. 2382 1. 0024 36. 2373 0. 1267 0 0 0 0 0 0 0 0-0. 1275 0 0. 0245 0 1 0 1. 152 0 0 0 0 0 0 0 11. 07 0 2. 13 10 86, 8110 1 29 S. 9325 5. 5702 0. 275 9. 9397 0. 0302 0 0 0 0 1 0 0 0 0. 1275 0 0. 0245 0 0 0 1. 152 0-0 0 86. 810 0 0 11. 07 0 2. 13 10 0 0 2 10 48. 0297-3. 6479 0. 6535 23. 624S D. 563S 01000) 000. 127500. 0245 00 0. 152 86. 81 0 0 0 0 0 0 11. 07 0 2. 13 0 0 0 2 11 33. 7357 12. 09si 0. 8374 30. 2711 0. 2395 0 0 0 0 0 0 I 0 0. 1275 0. 0243 0 0 0 0 1. 1518 0 0 0 0 0 86. 82 0 11. 072. 11 000) 2 12 25. 0I85 12. 5103 0. 7266 26. 269 0. 133 0) 0000000. 1275 0. 0243 0001. 1518000) 00011. 072. 11 0 0 0 86. 82 2 13 32. 2828 17. 7494 1. 0157 36. 7159 0. 148 0 0 0 0 0 0 0 D 0. 1275 0. 0243 0 0 1 0 1. 1518 0 0 D 0 0 0 0 11. 07 2. 11 0 0 86. 82 0 2 14 14. 7003 101762 0. 4613 16. 6741 0. 0611 0 0 0 0 1 0 0 0 0. 1275 0. 0243 0 0 0 0 1. 1518 0 0 0 86. 82 0 0 0 11. 07 2. 11 0 0 0 0 2 15 40. 9678 6. 002 0. 9233 29. 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N Oo n T N e0 sC Ov M V N N ^ 'N_ 00 N o0 N.-m--i N 00 N N Ov Ov N M 00 O n Ov N V' op O 1' n Ov n N W p vp M n 00 n N rh O O b V v1 M M D Co N rn N b Vt N Ov V ; m f^. T b, P h , r _ ? V'V h M T T N N rD Ov S O M h M Cp'MV, M tpn Vb'. Ov h tr h On vnf a0 m b O D p a0 O ^ v N n O N, O rD N at N h M ts C. ? r0 C'V o0 p vt vi G. p rD t 00 00 V.-i D vi Ov"OW . 00 V O rn V M N G IWn O r0 N rC O O cc 1 h V't .-n N N N M M N N o0 N r rn N N N N M M V N N. M O.-. V. N N N V V V M M N 'd' M N Ov M st M M O"N M V D O.-n N M rW p O N M ? h rD O N M C vW p n o0 Ov.-n.- N M'V h rD n M Qv.-i r-n N M st vf b n op Ov.-n. N M V'vf O n 0 Ov.-n N N N N N N N N N N N N M M M M M M M M M M M M M < < <h <Y V T V C T <t ? V C v1 Vo Vf W rn vf vf rn vW n rn vf vf n w A C w w s M hh pp. D o o o lo c S O S ìo S S o o o c C C 5D ii c c S S ! o o lo oLol9L91olololololòtÒIOIOlololslolOloloIt<sl91010101E10 twn M m h n pNp w b O O O O V'O O O O h O O O O 1 O O O p O'NC'p O O O O O O O b O O O O O m O O O O h O Q O O VNf O O O O O O O O O O O oi m O O O O o O d O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O N O O O O Vb1 O V V', V V V s0 D D O O O O C O O.. t yWT c'y G O O O O O O O O O O O r r O O O O O O O O O O O. . O O O O O O O O O O O N N N N N O O O O O O O O O O O D D D h tl ; V V V ; V, T V Q V ; V, V V'4''C d, O G O C p ? t Q O O O O O PIP giz ; z _ _ _ _ _ _ _ _ _ _ _ _ _ T r _ _ _ _ r r _ r _ 0 ß] I v l | { {I v t I v l S S S S c S _ _ S v S S § S2 v _ 5 St S rE S _ S S r S S S ! S r o|o|o|o| |o|o|o|o|o|o|o|o|e|eo|o|o|olo|olo|o|olo|o|o} 0 a. 1 6 o. 10 a 0101010. 10o 0 0 clo i6 a a a a ci .- O ^ O ^ N N N N N N N N N. r N N N N N N N N N N N N N N N O N ^. p w M M M N W O o O O O p o O o O o O O p o o O O O o O O O o O o O O o o O O O o o O O O O O O o O O O O O o O o O o N O O o O h w M MM hnaNO CON1D O O O O O O f O O O O t O O O O O O O O o b O p o O b p O O O O rvf O p O O O O O O O O O O O O O O O O O O O w w O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O h O O O O ci O O o o b V o O O O t o O o o h O O O o O O o O o b o O O O b O O o p O m O o O o vNf O O O O h O O o o p o O o O O N 1-5 6-1io 0. I. 0 0 0. 1 c ; to 6. (a. a a. a. 1... 0""a 0. 0 0 0 oi"o 0'0 0 0 twn M M w V V d''S V' V% Ov a N 600.... 0 0 0 O O t T tY V 1'O O O O O O O O O O O NV NV ? O O O O O O O O O O O n M M M M O O O O O O O O O O O V W O V V O O O s tM7 M r n ONO W h m r G O O O O V O O O O t O O O O h O O O O O V O O O O D O O O O b O O O O O tn O O O O vN1 O O O O h O O O O O ? O O O M w w w w w f C tY V'V w w w w M M M M O D D D D w w w w w w w w w w h 1 h h 1^ w h h h h t O O O O O h t 1 h t 00 o0 00 0o h h h t h t i h h t t N w w w Q V'V V'C'ts w N h N N N N_ N N N N O O O O O O O O O O t t t h t o0 00 00 0o a0 00 a0 ^ N N N N N t h h h t I^ t h t h 1 O Y M w M 00. t h t h h f^, t h t h o0 00 0o OG o0 w w w Ut w w w h w VW O O D O D V ? V ? V Q V ; V V C'w 1 Ov O tf O O.-i - : O O O C O O O C O O O O C O O O O O O G O O O O O O O O O O C O C O C O O O O O O O O O O O. N O O O n w u1 M M N N N O G O O O O O O O O O O O O O O p O O O O O O O O o O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O p O -. as h h h Vf w w w Vt w M M N N N O O o O O o O O O O O O P O o O O O O o O O O o O O O O O O o O O O o O O O o O O Ci O o O o C o O o O O o O o O o O N N O o O O O O o O O O o O O o O o O O O O O O o O O o 0 o O o 0 o O o O O p o O o O o O O o O O O o O o G O o O o O o Ire M M M w w w w o0 OC 00 00 V'C'V' h h t h t 00 owo 00 c0 6a Ov O O\ O N N N O O O O O O O O O O O O O O O O O O p p o o O o O O O O C O P O O O O o O o O O p O O C G O O O o O O o o O O o O o O o O O O o O O o O o O o O o o O o O O O O Q O ^ N N N N N O N 1 N N N N Vf V^1 w tp h hp 1 h vD I^ h h t h OwO OO O O O O O o P O O p O O O O O O 0 0 0 0 0 0 0 0 0 0 0 0 o c o o d o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o c o 0 0 0 0 0 0 o a w w w w w VI w w w w w w w w w h w w w w w w w w w w Vt w w w w w w w w w w w w w w w N N_ N_ N N N N_ N N _N N_ N N N_ N_ N_ N_ N_ N N_ N_ N_ N N N _N N _N N_ N_ N_ N_ N_ N N N N _N N N_ _N N N N_ N_ N N_ N_ N N N_ N_ N N O O O C O O p O O O O G O O C O C O O O O O O C O O O G O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O N N O O O O O O o O O o O o O o O o O o O o o p o O O O o O O o o O O o O O O o O o O O O o O O O O o O O O o O O p O O n t t w w w n h W M N N N O O O O O O O C O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O p O O O O O O O O O O O O O O O O O O O O O O O O p O O O O O O O O O O O O O O O O O O O O O O O O O.- O O O O n w w h h h m w w v w w M N, N N o O o O O o o b o O O o 0 o O C o O p o O O O p O o C o o O o O o O o O o O O o o O O O o O O o O O O o O O O O O O N N O O o O O O o O O O O O O O O o O O p o O O O o o o O O o O o O O O O O o O O o o O o O O O O o O O O o p p o O O O w w n n n n r w h w N w w h N w w w w w M M M M M N N N N N N C ce O O O O d p C O O O O O o O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O ^ O O O N n r n w n w v0 w w n M N N N C p O o C O o O o O o G o p p O G O p o O O O o O O O O O O o o O O O O o O O o O O o o O O O o O O O o O O ^ O O O h N O O O o C O O O o O O O o O o G o O O O o O O o O O O O O O o O o O O O O O O o O O o O O O O O O O O o O O o O O O N N a0 I o0 M D N i V'N . r D T w Ov O. t oD. 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N Ov N N ^ 00. ^ N ^. .- N N N.- w N N ^ i h.-n N ^ ^ N N ^ b M h D O t1'w b N D T w h Ov h 00 CO w b O D m N m M w O p0 N b N M w OO O. tp O Ov M w Ov M w Ov w O M w h N T h h O O h D v0 ? 00 V Ov p S ^ N O N fV n N N n vf t w M Ov p O n N ^ D V o00 00 T h Vf T O N b O t 09 O w M t $ Tq V w N G w M N N ? t w w w u1 D V1 w M ^ w w M ^ N M w'C'V ; V'M O Q w ? O O w w M D w C h, h M N N V w w p w OD C O G O O O O C O O O G O O O C O O OO O C OO OO O G O C C C O O G O O O O C O O C O G O O O O O O O b, p C O G O O O O ^ O N C7 M b M NNW 00N'V'fONhONO NhVw1^ w ? MOVMfNM00wOV6 pNONOOV'NO t^ h 00 O fV T ^ b a r y C h. t.-n O D p p N V ; N, D O Ov t0 t N Ov oo t 00 O t PJ M N v0 t w . v0 N. i en O h N 00 N N N b O M Oo Oyj N t T w D M O .. o h O, N 0 N N h N thf, N n r h'. lV N N i O !'.-r oi O ,'o W'i vi ! W p r vi N O oo.. r Ov.. i h o0 Wi N Y v Cv r, tV Gv. r.. b M V 1 w Ov M.. y0 M Qpv w b M w N h s00 2 D et M M N D 1 V'V1 r Op h N D Ov h b n T ONO M o0 V Ov 00 V1 n M O w D 1 00 V b. M-n M O n T ? Ut N b V' V n h O N.-yD U V'O w h sf. r M .-n vi oo f OO 00 M ri N ! s N o0 p Ov oC. i N t 00 M h D Vt Vi o0 N Ov N O h.-i.-i v t.' n G h.-i p. Vt Ov sT N 'V'"OC 00 M OO M M.-. M st N. r ? V''t M M O M et N.-i ? st ? ar N M.-n V 7 N N V ? sF ? N M ^ 1 r-n w G O ^ N M V w O O. N M V'w D O ^ N M st w O .-I N M V w C h a0 Ov. r N M V W O h 00 Qw.-i.- N M C w O t Oo Ov. . w N M V W p h a0 v1 D vD D vO O OO D D b D v0 D D O C h t h h h t W h h h h h h t h t a0 a0 a0 o0 00 a0 00 00 00 a0 00 00 00 o0 00 00 O Cv T Ov Ov Ov Ov Ov ., 6, 616 c-i c, 4 Iq c c rl : t- :-1-1 ci N 00 O, V f D O M v1 00 ~ r r S 9-n} 5 _ _ S v ! r t t r r e t t c r r a v t ffi S o a x x S IN O O O. ni M n n n n n b o, o, .......... Ci 16 16 w c c ? 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Io 0 gal 1-1 O O O O O O O O O O O N O O O O h O O O O O N O O O O V O O O O O O O O O N O O O O O O O O NV O O O O O N O lppplpp QP O O O O O O O O C v1 V O O O O O O O O O O O V b V O O O O O O O O O O O V O O O O O O O O O O O h b a0 O O O T h n r OObO00000b0000 00'COOOOO0000000000 V 00000000000000000MO000n0000f000 cli .-i D N O O O O V1 V1 n N M O O Oo Ov T T c0 0 O o0 00 O Ov Ov N N ao oo Ov V1 Y1 h V (V M M M Vt Vt'Y M M M N O N M Yt N M M Ut O O v0 b b T n M M 7 n O 00 O O O M O O v1 n OW O M M N Ov M O T V1 n D DO M M M 00 00 M M M 00 O oR-9 O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9. ci w m c N N vn.-it .-n O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O N N W n vW n n V a V V V h b vbf h O O O O O O O O O O O O O O O O O In 11 M M n n n n 11 In In In In n cl st ? 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O O O C O O O O O O O O G O O O O O O O O O O O O O O O G O O O O O O O O O O O O O G O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O n_ th vnf_ tNf M _ N M r O O O O O O O O O O O O O O O O O O O O O O O O C O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O r H n H n H n N V b N V NO, ao N V b oo N V o O O o o o O O C O C O.. o O o o O O O o o o O O o o C. o O O o o o O o o o O O C o C. O O o o O O o o o O O C O o rn rn n n w b o o oo oo m n n r b O. o O O O.- o O O o O O o o O O o o O O o O O O O O o O O o o o C O o O O o O O O O O C o o O O o o O O O o O o o h n O O o O O O o o O O O O o o O O O o o O O O O O o O O o O o o o o O O O o O O o O O O o O o o O o O O O O O o o o o M N D N o0 M n n T Vt N o0 M V M b D V N 00 n n M n o0 Qv n. 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CD CD 00 (Z> (= CD I C% (7N CYN c (7 o Ch oll ON o r*-r-r-r*-r-r-rl-r-El-t-r-t-t-t-r-W) VI tn kn tt) kn tn kn tn In tn tn kn kn tn cq eq rq Cl el rq rq r-r- (7% c (D% C) N (2N c7N c c ; C% CgN c CN c 11, llzt* o D 110 o 10 o 110 D o D o 10-- r-r t-r r r-t-p ch c r-r,-r-t-r-t-t--t--r--r-i i-t- (D (Z 00 00 00 00 w = w = = = = w"- O O eY 00000 OOOOOOOOOOOOOOOOOOO'OOOOOOOOOOOOO 00000 H ~ _s ~ H H ~ ~ _ ~ ~ H ~ ~ ~ _ ~ ~ H ~ ~ ~ ~ ~ ° ~--z ~ ~ o o _ o o o o c> _ _ o o o o o o _ o o o o o xi O °-° ° ololololololololololxl o o 000000000000000000000000000000000000000000 ( : R IR <R q q t-- : c qlql<RIR C R q IR q ( : = ! 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(Z) CD CD ooooocoooooooo°'°'. o000000000000°°. °°. oooocoooo O O O O O O O O O o O O O O cV N O O O O O O O O O O O O O M M O O O O O O O O O - (= (= cq C, 4 CD, C :. c : CD (m co c) (ZP O m O O O O O O O O O O O O O O o O 00 O O O O O O O O O O O O O O O OO O O O O O O O O O O õ M M M M M M M M M M M M M M M N N N N N N N N N N N N N N N h M M M M M M M M M M M M M O O O O O O O O O O O O O h V1 h h h h h h h h h l tì l xD | o o o + _ o o o _ o _ o _ c o o o o o o o Q o o o o o + c ; _ °1°1°1°1°1°1°1°1°1°l O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O h zon N O O O O O O O O O O O O O O C O O O O O O O O O O O O O O O O O O O O O O O O O O O M M M M M M M M M M M M M M M N N N N N N N N N N N N N N N M M M M M M M M M M M M M M M O O O O O O O O O C O O O O O h [ h h h h I^ h h llq o o o + _ _ o o c _ _ o _ _ o o o o o o o _ o o o o o SLi _ o olololololololololo O O O O O O O O O O O O O O O O O O O O C O O O O O O O O O O O O O O O O O O O O O N N O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O vu h 'n' r r 0 oooooooooooooooooooooooooooooooooooooooooo --i O .-m--n O O O O --n O O O O O O O O.-m--i.-n O O O O.-n O O O O O O O O . 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C=) c : (= CD CRD tn eq C, 4 eq rq O C o O O o o O C O C o C C o O O o C C C C O o O O O O C O C G o C G O C o C o C O V) mn oooo cl N kn tn In Y eh Y eh dwt dwh eh N N N N N N N N N N N N N N N _ t1 m N n ts N XD-£ rn : 90 ç m ; w rv Ch $ rs eE oo ts x rv : ct cel õ t o N n ! Ax b x 1v ; e O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O in r*- O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O C O h N D m tn C) tn C) , c N V) c %. D 00 o \. o 00 cq t-m t-Cl) r \o o'< o oooooooooooo oooooooooesoooooooo ooooooooooo c<) 0000000000000 000000000000000000 00000000000 (3 tn Cf)'n Cf) It'n C= = = (=> m m C, I-= m c : l 4 = rl-tn eq Cf) m q C, 4 m m tr t-kn t*- (3% ON a, CN CN \O CD V, I-q cn t-- : tfi n \. ! t, c, 7, Ci ooo''ooo'-'- ;'- ;'-''- ; ooo'- ; o*'oe ; o'- ; *''- ;'- ;'-'ooo'-o-ooo'-'- ; 0000 ? 0000' ? 000 0000000-OC ? 00' ? 00000 0000000000 O d 01 M 00 O eh d'N 00 N h h o0 00 N OW M.-n M et N M h p h v1 h M N V1 1 eY h c0 C v) 00 N h c0 00 00 GW 1 O N n O t D O 'Qv d N O h M d 00 h o0 I^ N --n O\ M 01 V1 O O\ N.-n O M h h O h.- h el'N t O O o0 00 O --n O h N N.-n O1 h'd Ov 01 V1 O N p -v O1 O M o0 Ofnrrfoooooc'rnfn'ri'<d'0'-'t [oo'ooo\\o.'o'' C O C C O O O C O G G C O O C O C O O O O C O O C O O O C O O C C O O C O C O C M 01 M M N N 00 V1 h pp h h V'1 t M N'd'p O M o't'om') oeo'f'tc'-< oorc- « i oooorot-'-m'-'m''rm T)'- §r- « i ['f<) 't'-t-oooT) OOt) toeeoco'or<) *ot\o\0 fo'-c') 0 [f<) foo [-co [-'-'-HOmo 'o<rT-<Of) [o'-<r<t''ooooooo'-<c' [cc] r-<o'<toc'oce'- (omoo fn\ooocnootoor [-ooot'o'rt'to [t [o') ooo''o't'rt ooooo'oooooooc ! oooooooooooooooooo ooooo ? o<oooo momf<-) r<) r<)'-'ooo\ oa t'''cr'-vo << C-'0''00''c<tcOO'rtOOOOC'000\QC''tOOOOOf.'' ! tO'''C'V) 00 m) OQoCOOO'COOO [OOmOE'-<Qo'''t'OOOt-' [mOOC<tc<) Ot [-'fn*00 0 [<Ot-<Qc'oof't*'-''t't'-'cntoo' (,-fncot''-''DOoofnooooooc') o'* N 'vt Ov 4 ''t N M 0 1 O vD 00 M OO O G1 ' M h eY V1'- N M ( C1 O 00 M j. eY 01 lD N 00 N M v0 O pp N O o0 et N O N O\ h O O M O h.-n pp et 00 Ov h h M O o0 N M O M h lmn M.-i oO O h O rr Qp V1 O O M'd' eY h M h O O V1 M, _., M O e1w--n h O 00 M O O ? 00 O N V p O N Ct M c õ £ Ho x, N o cxh t SY. oo > N N ob to Wo m ~ x t eo co t c> m o b m. õ °xlX vo ~ ~ ~ ~ b ~ rs ~~ ~ ~ ~ ~ F _ ~ cn | c> _ b ~ ~ ~ ~ ~ ~ ~ H l x | x g C.-m--n.-n W v--y v--i w-r w--n -m--y v--n ) n 01 O h w-r.-n H rr 00 v--m--n.-H n 00.-W O..-w--n h O V1 p O M h M N 01 00 V1 V1 M 01 M h rr cr O.-n M M O N h O h 00 h 01 eh N V1 pp h OW-r h M D N eh a0 00 V70 et o0 00 N Qv d' O V1 \ O\ N o0 M t D N v0 M O o0 et ONO N O N h O O'd OMO N T V'1. N O O'ch M 01 Oh0 h 01 d'OM1 VDO O.-n oC ., N . 00 p c ! M M.-, 00 h 00 cV d', _, cr M cV O O M I'Cl 00 T 00 O Qv N el'd. O f'dv 00 N.-n n.--i nj, ,-n n N N N N - --n Oi.-n N --n m--n. a N N N N N.-i W-- N O. r N,.-n N O.-n N M vW O O.-w N M d'V'1 O O ^ N M V1 D h 00 Ow-r e-i..-v., rr'r r-,- N M eh D h 00 ST. e--n W--i.-m--n. r N M d V D h 00 Q.-i. w--i,. w n n n n n n n n n o o o o c o o c o c o c o c h h h h h h h h r h r r h r h h o 0 0 0 0 0 o c o 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0 CD C :) o oc C'CD C :) C ; c :, cp c C :) CD o CD CZ) c : (D C=) c :- c, CD c :- CD 0000000000000 0000000000000 ! ! 0000000000 CN 00 0 0\ (2% C7% ON ON ON CN CN CN CN c : c2N C ; N c c7N (Zl% t-rl-t-rl-t*-r-r-t--tl-tl-r-t-kn W) W) tn In In kn tn tn kn C, 4 C, 4 cq rq eq C, 4 clq r-r-C) (gs CN (Z ON oll CN CN ON CN CN ON o%"0 o D o o o o"0 o \0 00000000000000000000000000000000000000000000 .-n .-w--m-r w-r. r --n w--n .-H O. .-n w-r v-r H.. w--m-r.-m--n.-v.-H.-n O v-r .-r e-i.-w--n..-m--n . r-) frrf) ) c (s) f) r-) <'') cr [-- o\o\<o\o\o\oooocr\co'''f \oo\oooo\o\ooo tttt-tttt-'f-tttroo t-'t-tt'-ttf-ttttf-oo ooooooeoooeoaooooooo 000000000000000 OOOOOOOOOOOOOtt--0000000000 0000000000000000000000000<00000000000000000 f<) CS) 0 0 <000000000000000000000000000000000000000000 0\0000\0\000\0000 tt [tt [ [ [-t [t Tt'D'''''nT) <s) frfrc) c-) rr<s) f< (ccsc0f o\oo\oo\o\o\o\o\o\< ? \o\o\oo \ooooooooo\o c O O O O O O O O O O O O 00 O O O O O O O O O O O O O O O o O O O O O O O O O O O CD N N N N N N N N N N N N N h r O O Q O O O 01 O cT 01 O O O eh t O O O l0 O O O O O D r r r r r r r r r r r r r ov ov r r r r r r r r r r r r r o 0 00 00 00 00 00 00 00 00 00 00 N 0 0 0 0 0 0 0 0 0 0 0 0 oo 0 0 0 0 0 0 0 0 0 0 0 0 o r r o 0 0 0 0 0 0 0 0 0 0 0 0 o c o 0 0 0 0 o c o 0 0 0 0 o d o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 m n N N O O O O O O O O O O O O O C O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O 010 O O O O O O O O O O O O O O O O O O O 101010101010101010101 N N N N N N N N N N N N N N N O O O O 01 O O T O Q 01 O1 01 O O O C D O O O D O O O r r o r h r r r h r r r r r r r r r r r r r r r r h r r r r OO OO OO 00 OO OO 00 00 OO OO O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O C O O O O C C O O O C O O O C C O O O C O O O C C O O O O O O O C C O O N N O O O O O O O O O O O O O O C O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O r o0 dWn r 00 vO N O M N N '01 prp r N O O.-i oO p., O eY O C r M N r O r l0 h eh O O O N C N 01 N O D O O N eY o O O OO r 01 O h O 00, N.-n,--n O M d 00 C1 n M 01 D 01 M V1 et O. O h 00 N r p O M V1 M O1 O O1 N O p OO O r.-V. r V1 N r O N O t*-= In M o-, t m" : t Cn kn Cn C> r-N", I, m W) cs tn c :- o V-cq o"I" O O O O O O O O O O O O O O O , O O O O O O O O O O O O O O O O O O O O O O O O O tn N N N m-t-00 C%-C= C=)'D W , o C% tn M C : l m tn C> eq 1= cl tn N r O V1 CY M O -- et O M eh M n M O r d'N d'M V1 O V1 eh, N O O 01 eh d O et O r N D'd' V N N N M.-n r OO O.-n N N O O O M O D O h M -- O N O.-n.-n 01 00 00 r r M V1 O N O 01 v1 wi CN oo V- : W ; 14 , i, ; c ; c ; o m 1, : ci C ; wi cli t-- : I' c N N N N N N N M N o0 Np tn N O N N N N N N N N N O N M N cV N pM N N N N N N N 00 01 V1 M 01 r D'h Y 01 O O N O M 00 M N '1'p r r 01 Q1 N O N 01 M'ch 01 O M r O\ O\ eY O\ N eY O h N N o0 ,..., h O O O M M o0 O\ h N p d O O N d V1 h N O d N t M.-n N O O r d 01 r M d M O M r O l0 D p 01 O O G 00 00 O eh N r p .-n 01 M O 'ct N M O V1 O 01 M N h 00 r ( l0 O eY O 00 O N h.. H eY O O 00 00 r \O O 00 \O vW-- M h O h 00 00 00 l0 \O'd"O 00 h 000000000000000 ? 0000000000 ? 000000000000000 c] r [r'c [ a c) o'-'t'-< f-'oo f r'-ctr t-t* o'r) t-o\o'fMioo't-'tt-'''-\ooof<) ffof<) Oormooe''°ooo <Dt-'oo [--'froo o'r) <j'0f'-f'''-<ooooo't-or-fn'o%''t''-' ! r) oeoc-)'- croorf*i<D<cN (fnfnQr<r''<- ! fo''* !'- !'mcsr'-o<'f-irn N M r N v1 N r p N N O'd"cY M.- r pp O N et M r N r d r M Ov r Qv.-n N O et D r M r r N. v N 1 O N eh N N Oyp M Ov o0 et -- N O r N Cv N D o m b cr, xD ep m ç cr el-lt b n t t \0 o o cs x cr x cs ts x cr t x x IV) I~ltlXltltltolv 101 01 O V1 O N Ch M M M O D O 00 er O h M O 01'I'd h D o0 N h N N O O N M M W h N M h M eh M eh v'i t7 N p N cV M h M cV ' N V1 M p' N' -- M M e1'cV cV. ^ O N M h M _I rr .-H 01 --m--m--n M Qv n o0 --n O.-H.-n w--n .-W rr v--n n O \O v--n H -r 00 v--m--n.-n r--It c7N r, m m C, 0. tn M- ! p N cn tn c ON cn co o ci I. I % q, o eh N M N.-n d ; M o0 M M O O M O M N O et N, O N eh. M v1 N, n Oy 00 N et d. O eh --n O d ; et O O cn N ts th9 tS cS ~ ~ _ tS cS c ~ QH ts 0 ~ tS N tE ~ ~ 00 H tS ~ ~,-~ ~ ~ | N N N N N N N O.- O --i N O -r N N N --n 00 N.- n.-w--i.-m-n m--n N N N N N N N oooooooooo N M eY O r 00 O.-m-. . r rr. n - m--n N M h U O r 00 01 w--n .-n,--m-r r-V.-n N M 1'V O r 00 01 O O O O O O O O O O 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 O O O 01 Ov O Ov 01 O 01 Ov Ov Ov Ov O1 W--W--n. H W--W r r.-n 00 0 0 0 00 o p o 0 0 0 0 0 o p o 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 ~ _ ~ _, ~ ~ _ {~ ~ ~ ~ _ ~ H ~ H ~ H _ ~ _f ~ ~ ~ _1 ~ ~-'1~ 1°1~ oooooo<ooooooooooe'oooooooooooooooooooooooooooo O00''00000000000000° 0000000000000°°°° OOOO OOOO-tfOOOOOOOOOOOOOOC' OOOOOOOOOOOOOmcl 0 0 O* 0 oo o s 0 000000000000000000000000000000000000000000000 C :) C :) c :, C :) (=) 1= ( : C < : c, (=) o o c :- CD m w-r.--n Ov OO O h h O O O O OO O O O O O O O O O O O O O O O 00 O O O O O O O O O O O O O O O 00 O O O O O <S) C) tN \0 0 0 0000000<OOOOOOOOOOC ! OOOOOOC ! 00000000000000000 kn kn N N N N CD C :) C :. c. = CD c : l CD c. C :) oooooooooooooooooooooooooooooooooooooooooo 'Ti fi T) r r c) 0 0 0 00000<0000000000000000000000000000000000000 W) tu coq N 000000000000000000000000000000000000000000 h h N O G O O O O O O O O O O O O O O O O O O O p O O O O O O O O O O O O O O O O O O O O vW O --n N h h N h D V N v0 N a0 N Ov eY h .-n 00 O\ N M O M pp o0 v0 et 01 vb , _, h OO OO CO h V1 OO M N eY h 01 , O O O O p O rr V1 V1 N h Ov M O1, N G N N M O p CG N h O O n D v1 N h O N O p o0 N t O p O vO o0 h M h M O p 01 N h N O O h h O r-c C, 4 o (7s N tn 00 r-i 00 00 o tn o, N r-cl-In It kn N-tn, d, C ; p, f. O O C O O C O O O O O O O O O O O O C O O O O O G O O O O O O O O O O O O Gi 00 O N O h V1 M N 'V' ! 1 N M h M O h V 00 M M 00 N O M 00 01 h O M d. O h 01 h [ 01 N p O eh h O1 O 00 00 M O O M VW--W d. 00 p N D'd'O O h V1 v1 O 00 O pp V1 O 00'ch O et h M O , L O.- 00 O V1 Qv N D Y CO O h V1,... i 61 N,-W--n 'vt V1 GO V1 O V1 D O IWO . V1 00 O v--n 00 VW--n Oy V1 p O N l0 00 d'00 O 00'G'M O \D O V1 p O :'d' . r-i O 00 O O Kl'h h O D p r-i h V'7 N M O O N ef.-i N N N N N N N N N M N N M.- N N M N N N N N M N N M N N N M N N . (S el ~ b1 tN (y t1 &1 e tN ~ tN/n tN. (y «, ~ tN _ b1 tN tN Xy ¢9 tN _ ¢9 m t1 N | tN | CS ß tN | o D D 00 V1 O Qv M N O V1 01 D N 01 p N N 00 01 h h O O O 00,..., h O 00 h M M i'O O p h.-n ,-y h O 00 00'ct O N V'f O p 00 G Q1 Ov M 01 t'O N 00 O V1 h M p 01 --m--n 01 O h O M.-n tF1 -- et h h O 00 00 h O O'ct h 00 h y--n M O O V1 00 00 00 h l0 e'h 00 h h d : D O l0 00 00 00 p, OOOOOOOOOOOOOOOOOOOOOOOpOOOOpOOOOOOOOOO pp N 00 N ' V M V1 M f'. 01 y M , M N D 00 .-n 00 N 1 M 01 00 01 CO , aO N N et O 00 M N N M eh p O h v0 N M V oO --i p M O\.-W O pp v1 01 h O pp d'V1 O O M h o0 N.- 00 N 00 yp Qv o0 O D, _., 00 O b tN O t tN cr ep crilC>lululxclnlOlsolkolmlnl p 01 n ! I O O V1 G rr V1 O h O N d O N e- tf) N C r. v--W D 00 01 v-r C'h 01 O 00 M D M h M, M 01 N M . _,' p cV M M dv cV N cV eh cV p O : . O p O M cV cV cV. ^n M M fV,-, O O,... ; -i M M M = c, t*--It 00 c. N ON"It a, 1. 0"kn ON N o < =-"1. 0 00 C ; % C> N ON w m r., M m m o'-o M N M t-clq % o It'n'It M 00 cn I-C ; % o M ON"N 4 M W r-1= r-m'Ir = In en O C cn R C : 'I : ! cn r-cl OR c O-I V' O'-R Iq ci"IR 1 : bi Vl _ ~ X N X m O1 g X ZN C> O1 C O el bi O X C ; tN tN tN tN X tXi tN tN C> 1919° l tN 0 HX § tN | tN | tN | N V1 M 00 01 M D O O O M h O h M --n p 00 O O p., d h OO \O V1 d''cY O h 00 d. O h N. . M OO h O C-4 eq N-N--4 C'4 N N NIN I-N Nlcn", Zt I-n 1"0 r4 M-'Zt- rrooooo't ; oc [-- ; '<-jfnoo'oooooot-- ; \o't-- ; oot-- ; *''<t'ooooooooo ? 0000000000<00000 ? 000000000000000 ? 000000000 oo roof'f'Dc)'-'-otm -, fc) ooooo"<oo o'mOooeoo oorMf-'fOt-eomr ffn'foOtOf-E'''''''oo'-'-Qco\0co'oo [o oo'oc''oot)'-<'-<ooro'--ooSooooo-. <oootro''ro\t-oQ'f)'<irSo'< oooc'Oc-<<-tC'cp.'-') ooo- ; toooo, Ofn [, c) Cf o\* <-'ffcr't''f'TtO\)'ffntrt't'cn0m00o\coofc-co'.-<c rif''v V) eo f'''eoorc'f0o « i<o\r<) a\o oo't ! oo'-<'-<'<i'oooo<) o\ !.'t''-'''t'oo00 ()'-<c) [<) oofo\ooor-) f<) r-co'-r'ff) ooroo [oB'mc « i<ff*ioor-. OQ'. [oo't-ooSr-'-' 'rirooofnoo'0 (r-ot : r'-Soooo'-t- [-ooo'<i'-'for-oo. . o'D [-'<. . r*ioor-o foo (oo ! oofocoQooo'ooor'- ! fc- : ) °oooe-r'') < ru Ou ' m o _ o o o o o o o n D o o o o o o s ; o o o o o r _ o o o o o o o o o o o o o o : N N --n 00 O O O O O O O O O O O O O O O O O O O O O O O . O O O O O O O O O O O O O' OOOOOOOOOft-OOOOOOOCSOOOOOO « 1'r) OOOOOOOOOOOOOO Q c Q Q Q Q Q Q Q So °tL Q ° ° ° ° ° SC Q Q Q Q Q Q Q Sc 3tL Q Q Q ° ololololololololololol m z x x x x x > > > 00000000000000000000000000000000000000000000 'Dooooooooooooooeooooooooooooooo [t-- [-- [-t [f [r [- [ [-- [r' [t-ttt- [--ttrr<) t<cm (r (fn<) rfr<) 00oo OOOOOOOOOOOOOTi M 000000000000000000000000000000<000<000<000000 'n Ti < CO _ s Q Q _ Q _ QSt S Q _ Ct St S :. Q S'SC Q _ _ Q Q S° Sz S Q S° _ Q _ °1°1°1°1°1°1°1°1°1°1°l x x x x x x x x x x x x x x x b b b F ooooooooooooooooooooooooooaooo r- [-' [-' [ [-' [-'tt-tt-t-f-t ttt [ [tt [t coccmf () rrmmfmcfc) 00000000000000 ooooooooooo t-<- ;-<-<r-<-<f-' ;-<t-<-< cs) forcoc) <f () f) f0 000000000000000000000000000000000000000000 ' Ti f f< 000000000000000000000000000000000000000000 s 000000000000000000000000000000000000000000 o'-r<)'-'r') c,-ic-iooc')'ocsj.-<oot'-<oo'<i\Ofo'<ioof) o'-<ooc\f) t--t-'DO' ; ffo'-<ri [ c-<oo'-<c) -'GO\ (tooorooo'fcoo<)'-tQO\) OOOooo'd-fOo'-'-cQOft oooooo' ? ooooooooooooooo ? ooooooooooooooo ? ooo oc'-m t''''O'-'rfcnt'-'.-. m ct o\ctrit) t-<c m't'f ooooooorof'-c\oofit-'-<o'<froo't-oop-. f0<) <r) 0\fmooo\ [t- [--'ri'-<o « i)'- f'-'t<n [oofo't'''tDr'-OtrO () Of-o'omcfo'Of<tctDoo< ? 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