Title:
TETRADENTATE DIAMINODIPHOSPHINE LIGAND AND TRANSITION METAL COMPLEX, AND METHOD FOR MANUFACTURING SAME AND APPLICATION FOR SAME
Document Type and Number:
WIPO Patent Application WO/2020/050271
Kind Code:
A1
Abstract:
The present invention relates to: a transition metal complex having a PNNP4 ligand that is easily manufactured and handled and that is relatively inexpensive to procure, and a method for manufacturing the same; a method for performing hydrogenation reduction of ketones, esters, and amides using the transition metal complex as a catalyst and manufacturing corresponding alcohols, aldehydes, hemiacetals, and hemiaminals; a method for oxidizing alcohols, hemiacetals, and hemiaminals using the transition metal complex as a catalyst and manufacturing a corresponding carbonyl compound; and a method for manufacturing alkyl amines by dehydrocondensation of alcohols and amines using the transition metal complex as a catalyst.
Inventors:
FUNANE SHIGERU (JP)
Application Number:
PCT/JP2019/034621
Publication Date:
March 12, 2020
Filing Date:
September 03, 2019
Export Citation:
Assignee:
TAKASAGO PERFUMERY CO LTD (JP)
International Classes:
C07F9/50; B01J31/24; C07C29/149; C07C33/22; C07C45/29; C07C47/54; C07C67/00; C07C69/78; C07C209/24; C07F9/576; C07B61/00; C07F15/00
Domestic Patent References:
| WO1998052551A1 | 1998-11-26 | |||
| WO2015191505A1 | 2015-12-17 | |||
| WO2015163440A1 | 2015-10-29 | |||
| WO2011048727A1 | 2011-04-28 | |||
| WO2012039098A1 | 2012-03-29 | |||
| WO2012144650A1 | 2012-10-26 |
Foreign References:
| US20140288641A1 | 2014-09-25 |
Other References:
MATTHIAS KONRAD ,SUSANNE WUTHE ,FRANC MEYER , ELISABETH KAIFER: "Dinucleating Hybrid Ligands Providing a Soft P N and an Adjacent N Rich Coordination Pocket Controlled Synthesis of Unsymmetric Homodinuclear and Heterodinuclear Complexes", EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 2001, no. 9, 24 July 2001 (2001-07-24), pages 2233 - 2240, XP055788095, DOI: 10.1002/1099-0682(200109)2001:9<2233::AID-EJIC2233>3.0.CO;2-4
CASTILLO IVAN; SANCHEZ-EGUIA BRENDA N; MARTINEZ-ALANIS PAULINA R; UGALDE-SALDIVAR VICTOR M; FLORES-ALAMO MARCOS: "Synthesis, spectroscopic, and structural characterization of mixed thioether-benzimidazole copper complexes", POLYHEDRON, vol. 85, 30 October 2014 (2014-10-30), pages 824 - 829, XP029102069, ISSN: 0277-5387, DOI: 10.1016/j.poly.2014.10.022
SHENG XU; WEI LI; KONG-CHANG CHEN.: "Naphthalimide as highly selective fluorescent sensor for Ag+ ions", CHINESE JOURNAL OF CHEMISTRY, vol. 25, no. 6, 1 June 2007 (2007-06-01), pages 778 - 783, XP055689674, ISSN: 1001-604X, DOI: 10.1002/cjoc.200790143
GUIDO LEIBELING; SERHIY DEMESHKO; SEBASTIAN DECHERT; FRANC MEYER: "Hysteretic magnetic bistability based on a molecular azide switch", ANGEWANDTE CHEMIE, vol. 44, no. 43, 4 November 2005 (2005-11-04), pages 7111 - 7114, XP055689676, ISSN: 1433-7851, DOI: 10.1002/anie.200501987
EDNA A AMBUNDO; MARIE-VERONIQUE DEYDIER; OCHRYMOWYCZ L A; RORABACHER D B: "Kinetics and Mechanism of Copper(II) Complex Formation with Tripodal Aminopolythiaether and Aminopolypyridyl Ligands in Aqueous Solution", INORGANIC CHEMISTRY, vol. 39, no. 6, 1 March 2000 (2000-03-01), pages 1171 - 1179, XP055689681, ISSN: 0020-1669, DOI: 10.1021/ic990904p
JAMES L CORBIN , KENNETH F MILLER , NARAYANAKUTTY PARIYADATH , SCOT WHERLAND , ALICE E BRUCE : "Preparation and properties of tripodal and linear tetradentate nitrogen, sulfur-donor ligands and their complexes containing the dioxomolybdenum(2+) core", INORGANICA CHIMICA ACTA, vol. 90, no. 1, 1 January 1984 (1984-01-01), pages 41 - 51, XP007901246, ISSN: 0020-1693, DOI: :10.1016/S0020-1693(00)80717-3
"Protective Groups in Organic Synthesis", 1991, JOHN WILEY & SONS, INC
See also references of EP 3848378A4
CASTILLO IVAN; SANCHEZ-EGUIA BRENDA N; MARTINEZ-ALANIS PAULINA R; UGALDE-SALDIVAR VICTOR M; FLORES-ALAMO MARCOS: "Synthesis, spectroscopic, and structural characterization of mixed thioether-benzimidazole copper complexes", POLYHEDRON, vol. 85, 30 October 2014 (2014-10-30), pages 824 - 829, XP029102069, ISSN: 0277-5387, DOI: 10.1016/j.poly.2014.10.022
SHENG XU; WEI LI; KONG-CHANG CHEN.: "Naphthalimide as highly selective fluorescent sensor for Ag+ ions", CHINESE JOURNAL OF CHEMISTRY, vol. 25, no. 6, 1 June 2007 (2007-06-01), pages 778 - 783, XP055689674, ISSN: 1001-604X, DOI: 10.1002/cjoc.200790143
GUIDO LEIBELING; SERHIY DEMESHKO; SEBASTIAN DECHERT; FRANC MEYER: "Hysteretic magnetic bistability based on a molecular azide switch", ANGEWANDTE CHEMIE, vol. 44, no. 43, 4 November 2005 (2005-11-04), pages 7111 - 7114, XP055689676, ISSN: 1433-7851, DOI: 10.1002/anie.200501987
EDNA A AMBUNDO; MARIE-VERONIQUE DEYDIER; OCHRYMOWYCZ L A; RORABACHER D B: "Kinetics and Mechanism of Copper(II) Complex Formation with Tripodal Aminopolythiaether and Aminopolypyridyl Ligands in Aqueous Solution", INORGANIC CHEMISTRY, vol. 39, no. 6, 1 March 2000 (2000-03-01), pages 1171 - 1179, XP055689681, ISSN: 0020-1669, DOI: 10.1021/ic990904p
JAMES L CORBIN , KENNETH F MILLER , NARAYANAKUTTY PARIYADATH , SCOT WHERLAND , ALICE E BRUCE : "Preparation and properties of tripodal and linear tetradentate nitrogen, sulfur-donor ligands and their complexes containing the dioxomolybdenum(2+) core", INORGANICA CHIMICA ACTA, vol. 90, no. 1, 1 January 1984 (1984-01-01), pages 41 - 51, XP007901246, ISSN: 0020-1693, DOI: :10.1016/S0020-1693(00)80717-3
"Protective Groups in Organic Synthesis", 1991, JOHN WILEY & SONS, INC
See also references of EP 3848378A4
Attorney, Agent or Firm:
KOBAYASHI Hiroshi et al. (JP)
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