Yellow Colored Natural Organic Lake Pigment from Immortelle (Helichrysum Italicum) and its Composition

Technical Field

The invention relates to yellow colored natural organic textile, dyeing, textile printing, stationery, wall and wood dyeing pigment composition and production method which is used in textile dyeing, textile printing, wall paints, wood painting, stationery paints, it is of natural organic plant origin, has antibacterial, antifungal, anti-allergic properties, does not contain toxic and heavy metal ions and oxides, is environmentally friendly, in dyeing, which saves energy, labor and water, can be cultivated.

Background of the Invention

Many of the synthetic and inorganic dyes and pigments used today contain toxic, carcinogenic and heavy metal ions. These pigments and dyestuffs are widely used in the textile, stationery, wood and wall paints industry. Immortal grass, which can be grown in many regions of our country, has many known benefits. The stems of immortelle, which has a very bright yellow color, contain chitin-like components. Thanks to these components, immortelle, which can remain for years without spoiling, is grown in many regions of our country. Immortal grass, a member of the daisy family, has six hundred species known throughout the world. Thirty-four species naturally grow in our country. Some of the benefits of immortelle can be listed as follows; - Immortal grass acts on the digestive system and causes an increase in gastric juice. In this way, digestive problems are eliminated.

- It is also very useful in relieving indigestion and stomach bloating felt after meals.

- Dried immortelle has a good diuretic property.

- By affecting the functioning of the gallbladder, kidney and pancreas, it ensures proper secretion.

- Due to its penetration into the digestive organs, it has a serious effect on the removal of kidney stones and stones in the gallbladder.

Immortelle (Helichrysum italicum), which has many benefits for human health, is not a plant that is used too much in traditional textile dyeing. For this reason, it is known that it may have been used in textiles, but it was not used as a natural organic pigment. It is not used as a natural organic pigment in textile printing, stationery, wall paints and wood dyeing.

The dyestuffs used on an industrial scale in existing textile dyestuffs are synthetic dyestuffs. The dyestuffs used in wood, wall paints and stationery are synthetic and pigments are inorganic metal oxides.

Many of them are toxic, carcinogenic and cause environmental pollution.

Today, natural organic herbal-derived immortelle (Helichrysum italicumi) yellow- colored plant-based organic pigment is not used traditionally, nor is it used on an industrial scale and sustainably.

It provides a savings of 75-85% from the water used in dyeing textile fibers with synthetic dyestuffs.

It saves 50-60% of the energy used in dyeing textile fibers with synthetic dyestuffs.

In dyeing textile fibers with synthetic dyestuffs, it saves 50-55% of the dyeing time.

However, the colorants used are not of vegetable origin. The pigments used are usually metal oxides, metal salts or chemical synthetic pigments obtained from petroleum and petroleum derivatives.

These are pigments that generally do not have antibacterial, antifungal, antiviral, anti-inflammatory and anti-allergic properties. The same features apply to wood, stationery and wall painting.

In the literature, in the patent application numbered TR 2019 05092 in the Turkish Patent and Trademark Office records, "The present invention contains propolis and at least one flavonoid-containing plant extract in order to complement the standard treatment in patients suffering from kidney stone disease and to prevent new stone formation in these patients. It's about a composition. The plant extract used in the composition is preferably Sambucus nigra (Elderberry - Elderberry), Vaccinium myrtillius (Bilberry - Blueberry), Helichrysum sp. (Immortele - Immortelle), Scolymus hispanicus (Golden thistle, Spanish salsify - §evketibostan), Vilburnum sp. It is obtained from at least one plant selected from a group consisting of (viburnum plant) and lemon plants.” statements are included.

In the mentioned patent application, the composition including immortelle is used for the treatment of kidney stone disease.

Again, in the European patent numbered EP2730286B1 in the literature, the invention stated "The claimed invention relates to a composition for preventing, treating and alleviating connective tissue diseases. The composition contains the following components: a plant, drone brood, quercetin, dihydroquercetin, and rutin. The plant used can be: burdock, dandelion, marsh cinquefoil, birch, St. John's wort, goldenrod, nettle, mint, liquorice, cinquefoil, tormentil, dog rose, Jacob's Ladder, valerian, maize, cucumaria, milk thistle, oat, agrimony, everlasting, ginseng, sage, chickweed, pumpkin, willow, wild strawberry, chicory, couch grass, Jerusalem artichoke, bilberry, calendula, horseradish, garlic, poplar, knotgrass, common plantain, elecampane, red buckwheat, chamomile flowers, lemon balm, galangal, cornflower, cudweed, bur marigold. The composition is used to alleviate or prevent bone diseases, treat osteoarthritis and osteoporosis, increase bone formation and bone mineral density during bone growth and optimize peak bone mass, stimulate bone regeneration during fracture healing, and reduce bone rarefaction. The composition effectively eliminates joint pain, nourishes the osteoarticular system, promotes the growth and regeneration of connective tissue and does not have side effects.” statements are included.

In the aforementioned patent application, the composition including the immortelle is used for the protection of bone health.

Again, in the US patent application numbered US2022008323 in the literature, " A formulation of oils including, Simmondsia chinensis Seed Oil, Rosa moschata Seed Oil, Daucus carota Stavia Seed Oil, Callophyllum inophyllum Oil, Rosmarinus officinalis Leaf Oil, Boswellia carterii Oil, Pelargonium graveolens Oil, Cymbopogon fleuosus Oil, and Helichrysum italicum Oil. An example of the formulation's product is a cream, which can be applied to an individual's face and/or neck skin to provide benefits thereto.” statements are included.

In the aforementioned patent, the composition containing immortelle fe cy ?) creates a cream that benefits the skin of the face or neck.

As a result, due to the problems described above and the inadequacy of the current use, it was necessary to make an improvement in the relevant technical field. Therefore, there is a need for an invention to overcome these problems.

Disclosure of the Invention

The aim of the invention is related to natural organic pigments to be used in the fields of textile dyeing, textile printing, wall paints, stationery paints and wood paints, which eliminate the above-mentioned disadvantages and bring new advantages to the related technical field. -To reveal the composition of yellow natural organic pigment textile dyeing, textile printing, stationery, wall and wood dyeing obtained from immortelle (Helichrysum italicumi), which does not contain toxic and heavy metal oxides with allergic properties, is environmentally friendly, saves water, time and energy in dyeing

Another aim of the invention is to present a composition that allows the dyeing of yellow color and yellow tones textile products, wood, stationery and walls safer in terms of health, especially for babies and children.

Another aim of the invention is to provide an environmentally friendly structure that provides less water consumption, less time and less energy consumption compared to synthetic dyestuffs and synthetic pigments.

Another aim of the invention is to provide a structure that allows the dyestuff obtained to be used in all textile fibers of protein and cellulose origin, as well as in the dyeing of regenerated and synthetic fibers.

Another aim of the invention is to present a structure that allows the use of wall paints, stationery and wood dyeing on a traditional and industrial scale, as well as dyeing textile fibers.

Another aim of the invention is to present a structure that does not contain toxic, heavy metal oxides with antibacterial, antifungal, antiviral, anti-inflammatory and anti-allergic properties.

Another aim of the invention is to paint in a shorter time, use less labor and provide a more environmentally friendly paint composition.

Another aim of the invention is to present a structure that does not cause any harm as a result of contact with the body by any means.

Another aim of the invention is to provide a structure that does not contain synthetic dyestuffs, chemical solvents and synthetic binders. Another aim of the invention is to present a structure containing natural organic pigments of vegetable origin, in which colors in the color range of tan, light yellow, bright yellow are obtained.

Another aim of the invention is to provide a structure with good sweat fastness, light fastness, washing fastness and friction fastness and easy to supply raw materials in pigment production in textile dyeing, textile printing, stationery, wood and wall dyeing.

Another aim of the invention is to reveal a structure that can be used in textile dyeing of the same color without any pretreatment or purification of the waste water.

Another aim of the invention is to provide a structure containing the most suitable pigment and dyeing method to the dyeing standards of ZDHC (Zero Discharge of Hazardous Chemicals).

Another aim of the invention is to provide a structure that provides surface smoothness in textile dyeing and can be applied easily in dyeing steps.

Another aim of the invention is to provide a structure with high covering properties in wall, stationery and wood dyeing, which can be applied in all textile dyeing machines (jet, scarf, piece dyeing, etc.).

Another aim of the invention is to provide a structure with reproducible standard properties of the produced organic plant origin pigment.

Another aim of the invention is to present a structure that performs at least four separate processes [bio mordant (tanning), mordanting, dyeing and fixation) in a single step in dyeing protein-based, cellulose-based, regenerated and synthetic fabrics or products with natural dyes.

Another aim of the invention is to present a structure that is very simple to use in dyeing and does not contain additional additions. Detailed Description of the Invention

In this detailed explanation, the preferred alternatives of the inventive yellow natural organic textile, paint, textile pigment, stationery, wood and wall paints composition and painting method are explained only for a better understanding of the subject and without any limiting effect.

The invention relates to yellow colored natural organic textile, dyeing, textile printing, stationery, wall and wood dyeing pigment composition and production method which is used in textile dyeing, textile printing, wall paints, wood painting, stationery paints, it is of natural organic plant origin, has antibacterial, antifungal, anti-allergic properties, does not contain toxic and heavy metal ions and oxides, is environmentally friendly, in dyeing, which saves energy, labor and water, can be cultivated characterized in that, comprises 45-55 percent immortelle (Helichrysum italicum) is containing phenolic compounds in the structure of caffeic acid, chlorogenic acid, pinocembrin, quercetin, naringenin, gnaphaliin, ursolic acid, arangenin, tilorizide, myricetin, luteolin and apigenin, the main dyestuffs of the stem, branches, leaves and flowers of the plant, which can grow naturally and can be cultivated, 3-7% myricetin, quercetin and tannin sumac leaves Rush coriaria L.) containing myricetin, quercetin, gallic acid, ellagic acid and its derivatives (tannin), 12-18% natural alum or aluminum sulfate Ah(SO4)3 with the chemical formula of KAI(SC>4)2.12H2O that the aluminum ions in it form a complex with the caffeic acid, chlorogenic acid, pinocembrin, quercetin, naringenin, gnaphaliin, ursolic acid, arranol, tilorizid, myricetin, luteolin and apigenin phenolic compounds contained in the aforementioned immortelle, which dissolves the dyestuffs in the plant [caffeic acid- Al-tannin, chlorogenic acid - Al-tannin, pinocembrin - Al-tannin, quercetin - Al- tannin, naringenin - Al-tannin, gnaphaliin - Al-tannin, ursolic acid - Al-tannin, aranole - Al- tannin, tilorizide - Al-tannin, myricetin -Al- tannin, luteolin - Al-tannin and apigenin - Al-tannin], which increases the color depth and allows it to precipitate in solid form by providing the formation of complexes with phenolic compounds.

With the invention, it is aimed to paint textile products, wood, stationery and walls in yellow colors and yellow tones that are safer in terms of health, especially for babies and children. For this reason, one of the most important yellow colors among plant-based textile dyestuffs is the yellow obtained from plants containing luteolin and apigenin. Immortelle (Helichrysum italicum) contains caffeic acid, chlorogenic acid, pinocembrin, quercetin, naringenin, gnaphaliin, ursolic acid, arranol, tiloriside, luteolin and Ipigenin. Sumac leaves (Rush coriaria L.) contain myricetin, quercetin and tannin.

At the same time the invention is vegetable yellow color is related to the natural organic textile dyeing method has antibacterial, antifungal, antiviral, antiinflammatory and anti-allergic properties, does not contain toxic and heavy metal oxides, is environmentally friendly, saves water, time and energy in dyeing, to be used in the fields of textile, stationery, wood and wall paints, characterized in that, includes method steps of;

- Grinding immortelle (Helichrysum italicum) in the range of 70-90 microns,

- Mixing 2 kilograms of ground immortelle (Helichrysum italicum) in 10 liters of water and 250 grams of sumac leaves (weight of immortelle and sumac leaves plant) ground in the range of 60-90 microns with 16% alum [KAI(SC>4)2.12H2O] or 6% Ah(SO4)3 at room temperature for 12 hours,

- Then the temperature is increased to 75-85 °C and kept at 77-85 °C for 30 minutes and the mixing process continues continuously during the extraction process,

- Allowing the extraction to cool and filtering at room temperature to extract the plant pulp,

- By adding Na2COs or K2CO3 to the filtrate, adding and mixing until the pH of the medium is 8.0-9.5 and waiting at room temperature for 12 hours,

- Filtering the complex of solid precipitated dyestuffs [caffeic acid- Al- tannin, chlorogenic acid - Al-tannin, pinocembrin - Al-tannin, quercetin - Al-tannin, naringenin - Al-tannin, gnaphaliin - Al-tannin, ursolic acid - Al- tannin, aranole - Al- tannin, tilorizide - Al-tannin, myricetin -Al-tannin, luteolin - Al-tannin and apigenin - Al-tannin] through three-stage filters of 120 mesh, then 150 mesh, and finally 180 mesh, and rinsing three times with 30 0C water by removing the solid pigment,

- mentioned [caffeic acid- Al-tannin, chlorogenic acid - Al-tannin, pinocembrin - Al-tannin, quercetin - Al-tannin, naringenin - Al-tannin, gnaphaliin - Al-tannin, ursolic acid - Al-tannin, aranole - Al -tannin, tilorizide - Al-tannin, myricetin -Al-tannin, luteolin - Al-tannin and apigenin

- Al-tannin] drying at 50-60 0C,

- grinding the dried solid [caffeic acid- Al-tannin, chlorogenic acid - Al- tannin, pinocembrin - Al-tannin, quercetin - Al-tannin, naringenin - Al- tannin, gnaphaliin - Al-tannin, ursolic acid - Al-tannin, aranole - Al- tannin, tilorizide - Al-tannin, myricetin -Al-tannin, luteolin - Al-tannin and apigenin

- Al-tannin] between 3 microns and 30 microns into powder form,

- Adding oxalic acid as much as the amount of dyestuff in powder form and providing a homogeneous distribution by mixing,

- Homogeneous distribution by adding ground alum [KAI(SC>4)2.12H2O] equal to the total amount of dyestuff and oxalic acid or Ah(SO4)3 equivalent to the aluminum element in the added alum.

The parts of the ground immortelle (Helichrysum italicum) (stem, branches, leaves and flowers) are extracted with water together with sumac leaves (Rush coriaria L.) and the extract (the dyestuffs and active substances it contains) is turned into pigment in solid powder form. It enables the use of natural organic pigment of plant origin in the textile dyeing and printing industry, as well as in pastel paints, wall and wood dyeing.

The dyestuff in the powder forum [caffeic acid- Al-tannin, chlorogenic acid - Al- tannin, pinocembrin - Al-tannin, quercetin - Al-tannin, naringenin - Al-tannin, gnaphaliin - Al-tannin, ursolic acid - Al-tannin, aranole - Al- tannin, thilorizide - Al- tannin, myricetin -Al-tannin, luteolin - Al-tannin and apigenin - Al-tannin], which is the subject of the invention;comprises oxalic acid or citric acid, Ah (SC or alum [KAI(SO ₄ ).12H ₂ O].

It behaves like a single compound in dyeing and dissolves homogeneously in water. The yellow dyestuff that is the subject of the invention is given below with its weight ratios;

The main dyestuffs of the stem, branches, leaves and flowers of the immortelle (Helichrysum italicum) plant, which can be grown naturally and which can also be cultivated, are caffeic acid, chlorogenic acid, pinocembrin, quercetin, naringenin, gnaphaliin, ursolic acid, ardanol, tilorizide, myricetin, luteolin and apigenin in the structure, contain phenolic compounds. Natural organic pigments obtained from the stem, branches, leaves and flowers of this plant provide the formation of tan, light yellow, yellow and bright yellow color tones.

Alum chemical formula is KAI(SC>4)2.12H2O, aluminum ions in natural alum or aluminum ions in aluminum sulfate Ah(SO4)3 are caffeic acid, chlorogenic acid, pinocembrin, quercetin, naringenin, gnaphaliin, ursolic acid, arranol, tilorizide, myricetin contained in the evergreen herb. , luteolin and apigenin form complexes with phenolic compounds and dissolve the dyestuffs in the plant; provides the formation of complexes with phenolic compounds [caffeic acid- Al-tannin, chlorogenic acid - Al-tannin, pinocembrin - Al-tannin, quercetin - Al-tannin, naringenin - Al-tannin, gnaphaliin - Al-tannin, ursolic acid - Al-tannin, aranole - Al- tannin, tilorizide - Al-tannin, myricetin -Al-tannin, luteolin - Al-tannin and apigenin - Al-tannin], increases the color depth and precipitates in solid form.

Sumac leaves contain myricetin, quercetin, gallic acid, ellagic acid and its derivatives (tannin), [caffeic acid- Al-tannin, chlorogenic acid - Al-tannin, pinocembrin - Al-tannin, quercetin - Al-tannin, naringenin - Al-tannin, gnaphaliin - Al-tanni n , ursolic acid - Al-tannin, aranole - Al- tannin, tilorizide - Al-tannin, myricetin - Al-tannin, luteolin - Al-tannin and apigenin - Al-tannin] complexes.

The gallic acid in the pigment provides antibacterial, anti-microbial and anti-fungal 5 properties.

Sodium carbonate or potassium carbonate allows the compounds in the extracted plant to precipitate in the form of aluminum complexes.

10 Natural organic pigment of yellow color obtained in powder form; [caffeic acid- Al- tannin, chlorogenic acid - Al-tannin, pinocembrin - Al-tannin, quercetin - Al-tannin, naringenin - Al-tannin, gnaphaliin - Al-tannin, ursolic acid - Al-tannin, aranole - Al- tannin, tylorizide - Al-tannin, myricetin -Al-tannin, luteolin - Al-tannin and apigenin - Al-tannin] KAI(SO4)2.12H2O, oxalic acid.

15

The % amounts of phenolic compounds of vegetable origin in the solid powder form obtained are given below.

20 The % amounts of the elements contained in the solid powder form product obtained are given below.

The production method of the invention is as follows; a) Immortelle (Helichrysum italicum) in the range of 70-90 microns is ground, 2 25 kilograms of ground immortelle in 10 liters of water and 250 grams of sumac leaves ground in the range of 60-90 microns (of the weight of the immortelle and sumac leaves plant) 45% natural alum [KAI] (SC>4)2.12H2O] is mixed for 3 hours at room temperature, then the temperature is increased to 75-85 °C and stirred at 75-85 °C for 30 minutes. b) Extraction is filtered and extracted from plant pulp. c) Na2CC>3 is added to the filtrate until the pH of the medium reaches 8, 0-9.5, and it is mixed at 85 °C for 30 minutes. d) Solid precipitated [caffeic acid- Al-tannin, chlorogenic acid - Al-tannin, pinocembrin - Al-tannin, quercetin - Al-tannin, naringenin - Al-tannin, gnaphaliin - Al-tannin, ursolic acid - Al-tannin , aranol - Al-tannin, thilorizide - Al-tannin, myricetin - Al- tannin, luteolin - Al-tannin and apigenin - Al-tannin] complex is filtered through 120 mesh, then 150 mesh and finally 180 mesh filters, and the solid pigment is removed and rinsed three times with 30 °C water. e) Solid pigment [caffeic acid- Al-tannin, chlorogenic acid - Al-tannin, pinocembrin - Al-tannin, quercetin - Al-tannin, naringenin - Al-tannin, gnaphaliin - Al-tannin, ursolic acid - Al-tannin, Arranol - Al-tannin, thylorizide - Al-tannin, myricetin - Al-tannin, luteolin - Al-tannin and apigenin - Al-tannin] complex is dried at 50-60 °C. f) Dried solid dyestuffs [caffeic acid- Al-tannin, chlorogenic acid - Al-tannin, pinocembrin - Al-tannin, quercetin - Al-tannin, naringenin - Al-tannin, gnaphaliin - Al-tannin, ursolic acid - Al-tannin , arranol - Al-tannin, thylorizide - Al-tannin, myricetin - Al-tannin, luteolin - Al-tannin and apigenin - Al-tannin] are ground in the range of 3 microns to 15 microns and brought into powder form. g) Oxalic acid is added as much as the amount of pigment in powder form and a homogeneous mixture is obtained by mixing thoroughly. h) Obtained pigment is used for textile dyeing, textile printing, stationery, wood and wall dyeing.