Title:
sYCLIC PHENOL SULFIDE-METAL COMPLEXES, CATALYSTS COMPRISING THE SAME AND ANALYTICAL METHODS FOR HYDROGEN PEROXIDE
Document Type and Number:
WIPO Patent Application WO/2000/023435
Kind Code:
A1
Abstract:
Metal complexes which serve as catalysts in various chemical reactions or as materials in the information-electronics industry, exhibit peroxidase-like activities or high hydrolytic activities for phosphoric diesters, and can easily hybridize with base sequence recognition sites; and novel analytical methods for hydrogen peroxide with the complexes exhibiting peroxidase-like activities. The above metal complexes are prepared by bringing a cyclic phenol sulfide represented by general formula (2) into contact with at least one member selected from among Group 8, 1A to 7A, 1B and 3B metals, and are usable as catalysts for the oxidation with hydrogen peroxide or those for the hydrolysis of phosphoric diesters, the hydrolysis catalysts being useful also in the analysis for hydrogen peroxide. In said formula X?1¿ is hydrogen, a hydrocarbon group or the like; Y?1¿ is hydrogen, a hydrocarbon group or the like; Z?1¿ is Sm?1¿ or the like; m?1¿ is an integer of 1 to 7; and n?1¿ is an integer of 4 to 8.
Inventors:
ODO JUNICHI (JP)
KAWAHARA NOBUKO (JP)
AKASHI KOICHI (JP)
MIYANO SOTARO (JP)
IKI NOBUHIKO (JP)
MOROHASHI NAOYA (JP)
TAKEYA HARUHIKO (JP)
MIYANARI SETSUKO (JP)
KUMAGAI HITOSHI (JP)
KAWAHARA NOBUKO (JP)
AKASHI KOICHI (JP)
MIYANO SOTARO (JP)
IKI NOBUHIKO (JP)
MOROHASHI NAOYA (JP)
TAKEYA HARUHIKO (JP)
MIYANARI SETSUKO (JP)
KUMAGAI HITOSHI (JP)
Application Number:
PCT/JP1999/005819
Publication Date:
April 27, 2000
Filing Date:
October 21, 1999
Export Citation:
Assignee:
COSMO SOGO KENKYUSHO KK (JP)
COSMO OIL CO LTD (JP)
ODO JUNICHI (JP)
KAWAHARA NOBUKO (JP)
AKASHI KOICHI (JP)
MIYANO SOTARO (JP)
IKI NOBUHIKO (JP)
MOROHASHI NAOYA (JP)
TAKEYA HARUHIKO (JP)
MIYANARI SETSUKO (JP)
KUMAGAI HITOSHI (JP)
COSMO OIL CO LTD (JP)
ODO JUNICHI (JP)
KAWAHARA NOBUKO (JP)
AKASHI KOICHI (JP)
MIYANO SOTARO (JP)
IKI NOBUHIKO (JP)
MOROHASHI NAOYA (JP)
TAKEYA HARUHIKO (JP)
MIYANARI SETSUKO (JP)
KUMAGAI HITOSHI (JP)
International Classes:
B01J31/22; C07C29/12; C07C201/12; C07C205/22; C07D341/00; C07F3/00; C07F3/02; C07F5/00; C07F15/02; C07F15/06; C09B55/00; G01N21/77; G01N31/00; G01N31/10; (IPC1-7): C07D341/00; B01J31/22; C07B33/00; C07B37/06; C07C201/12; C07C205/22; C07D231/46; G01N21/59
Domestic Patent References:
| WO1999029683A1 | 1999-06-17 |
Foreign References:
| JPH09227553A | 1997-09-02 | |||
| JPH1077282A | 1998-03-24 | |||
| JPH1077281A | 1998-03-24 |
Other References:
IKI N. ET AL.: "High Complexation Ability of Thiacalixarene with Transition Metal Ions. The Effects of Replacing Methylene Bridges of Tetra(p-t-butyl)calix(4)arenetetrol by Epithio Groups", BULL. CHEM. SOC. JPN., vol. 71, no. 7, 1998, pages 1597 - 1603, XP002926115
IKI N. ET AL.: "Selective Oxidation of Thiacalix(4)arenes to the Sulfinyl- and Sulfonylcalix(4)arenes and their Coordination Ability to Metal Ions", TETRAHEDRON LETTERS, vol. 39, no. 41, 1998, pages 7559 - 7562, XP002926116
IKI N. ET AL.: "A New Water-Soluble Host Molecule Derived from Thiacalixarene", CHEMISTRY LETTERS, 1998, pages 625 - 626, XP002926117
See also references of EP 1123930A4
IKI N. ET AL.: "Selective Oxidation of Thiacalix(4)arenes to the Sulfinyl- and Sulfonylcalix(4)arenes and their Coordination Ability to Metal Ions", TETRAHEDRON LETTERS, vol. 39, no. 41, 1998, pages 7559 - 7562, XP002926116
IKI N. ET AL.: "A New Water-Soluble Host Molecule Derived from Thiacalixarene", CHEMISTRY LETTERS, 1998, pages 625 - 626, XP002926117
See also references of EP 1123930A4
Attorney, Agent or Firm:
Hagino, Taira (ARK Mori Building 12-32, Akasaka 1-chome Minato-ku Tokyo, JP)
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