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Title:
レニウムおよびアルミニウムを含む担持触媒、その調製方法およびオレフィンのメタセシスへの適用
Document Type and Number:
Japanese Patent JP4189698
Kind Code:
B2
Abstract:
A catalyst contains at least a porous inorganic support, 0.01-20 wt.% of rhenium in oxide form and 0.01-10 wt.% of aluminium derived from an aluminium compound of formula (RO)qAIR'r, in which R is an alkyl group containing 1-40 C, R' is also an alkyl group containing 1-20 C, q and r = 1 or 2 and q+s = 3. The preparation of the catalyst involves: (a) preparation of a calcined catalyst precursor containing at least an inorganic porous support and rhenium. (b) contacting the precursor with a compound of formula (RO)qAIR'r obtained from reaction between ROH and AIR'3 ; and (c) drying the resulting product. Also claimed is the metathesis of olefins using the above catalyst carried out in gas phase at 0-100 degrees C.

Inventors:
Dominique comroux
Application Number:
JP27468596A
Publication Date:
December 03, 2008
Filing Date:
October 17, 1996
Export Citation:
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Assignee:
ENI S.P.A.
International Classes:
B01J23/36; B01J29/06; B01J31/32; B01J31/14; C07B61/00; C07C6/04; C07C11/02; C07C11/06
Domestic Patent References:
JP4211617A
JP3876350B2
JP7073675B2
JP1135729A
JP63137751A
JP59155333A
JP7309787A
Foreign References:
US4454368
Attorney, Agent or Firm:
Einosuke Kishimoto
Moriichi Kishimoto
Akira Watanabe
Norihiko Hibi