To provide footwear which can be expected of highly physiological effect by tourmaline at a low cost and with comfort to wear.

A shoe is composed of exterior members 3 such as a vamp 1 and an outsole 2, and interior members 6 such as a liner 4 and an insole 5. The exterior members 3 and the interior members 6 are laminated together by a natural rubber latex 7 mixed with tourmaline powder of 200-400 micron by 5-40 wt.%. The latex 7 comprises natural rubber by 40-60 wt.%, water by 30-50 wt.%, and ammonium by 10-30 wt.%. A breathable material is employed for the liner 4.