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Title:
HYDROTERPHENYL COMPOUND AND LIQUID CRYSTAL COMPOSITION
Document Type and Number:
Japanese Patent JP2582031
Kind Code:
B2
Abstract:

PURPOSE: To provide the compounds comprising specific hydroterphenyl compounds, suitable to nematic phase compositions as an ingredient at liquid crystal derivative compositions having a wide nematic range and a low viscosity, and used as liquid crystal for electro-optical display elements or the like.
CONSTITUTION: After hydrogenating trans-1-P-hydroxyphenyl-4-propylcyclohexane over PtO2, oxidizing with NaOCl and subjecting the product therefrom to a reaction with a compound represented by the formula C6H5MgBr and subsequently to a dehydration by a strong acid in boiling toluene. The formed product is further hydrogenated over PtO, heating the produced cis-trans mixture at 100°C in DMF by adding K-tert.-butyrate, thereby forming hydroterphenyl compounds of formula I, which are compounded with compounds of formula II (A and E are each substituted phenylene, a cyclohexane ring; G is CH=CH, COO or the like; R6 and R7 are each alkyl or the like) thereby obtaining the object liquid crystal compositions. In formula I, R1 is alkyl; R2 is H, halogen, OH, alkyl or the like Cy is 1,4-cyclohexylene; Ph is 1,4-phenylene.


Inventors:
MIHAERU REMERU
YOAHIMU KURAUZE
RUDORUFU AIDENSHINKU
GEORUKU UEEBERU
Application Number:
JP18861193A
Publication Date:
February 19, 1997
Filing Date:
June 22, 1993
Export Citation:
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Assignee:
MERCK PATENT GMBH
International Classes:
C07C1/00; C07C13/28; C07C17/00; C07C25/18; C07C69/94; C07C27/00; C07C39/17; C07C41/00; C07C43/21; C07C45/46; C07C51/00; C07C63/49; C07C67/00; C07C69/017; C07C69/02; C07C69/157; C07C69/75; C07C69/76; C07C69/773; C07C69/92; C07C253/00; C07C255/49; C07C255/50; C07C255/55; C07C255/57; C09K3/30; C09K19/30; C09K19/42; G02F1/13; (IPC1-7): C09K19/42; C09K19/30; G02F1/13
Domestic Patent References:
JPS5810552A
JPS5764626A
JPS57165328A
JPS5832832A
JPS57114531A
JPS5859930A
Attorney, Agent or Firm:
Kiyokazu Kazuwa (1 person outside)