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Title:
METHOD FOR CLEAVING ALKYL TERT-ALKYL ETHER TO CORRESPONDING ISOOLEFIN AND ALKANOL
Document Type and Number:
Japanese Patent JP2001316307
Kind Code:
A
Abstract:

To provide a method for cleaving an alkyl tert-alkyl ether in high conversion ratio while suppressing the formation of by-product.

An alkyl tert-alkyl ether is cleaved by reactive distillation in the presence of an acidic catalyst by supplying the alkyl tert-alkyl ether to a reaction zone of a reactive distillation apparatus having a bottom zone, at least one distillation zone and a reaction zone arranged from the bottom upward. The supply of the ether to the reaction zone is carried out in the form of an azeotropic mixture of the alkyl tert-alkyl ether and the corresponding alkanol.


Inventors:
SAKUTH MICHAEL
TUCHLENSKI AXEL
REUSCH DIETER
BECKMANN ANDREAS
Application Number:
JP2001128228A
Publication Date:
November 13, 2001
Filing Date:
April 25, 2001
Export Citation:
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Assignee:
OXENO OLEFINCHEMIE GMBH
International Classes:
C07B61/00; C07C1/20; C07C11/02; C07C11/09; C07C11/10; C07C29/00; C07C29/10; C07C31/02; C07C31/04; C07C31/08; C07C31/10; C07C31/12; (IPC1-7): C07C29/00; C07C1/20; C07C11/02; C07C11/09; C07C11/10; C07C31/02; C07C31/04; C07C31/08; C07C31/10; C07C31/12
Attorney, Agent or Firm:
Toshio Yano (4 outside)