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Title:
METHOD FOR MANUFACTURING ETHYLENE LOW POLYMER
Document Type and Number:
Japanese Patent JP2008178873
Kind Code:
A
Abstract:

To provide a method for manufacturing an ethylene low polymer by using a chromium-based catalyst, the method for recovering a decen, under the condition that a decomposition product of the chromium-based catalyst or the like is hardly produced, from a high boiler in which an ethylene low polymer is separated.

An ethylene low polymer and a high boiler, which contains a chromium-based catalyst, a decen, a tetradecen and a by-product polymer are separated by distillation from a reaction liquid which contains the ethylene low polymer obtained by an ethylene low polymerization reaction using the chromium-based catalyst. Then, the high boiler is concentrated with an evaporation separator 70 and a liquid storage tank 80 so that the concentration of the tetradecen may be at least 5 wt.%, and the decen is separated by evaporation so that the following general formula (1) may be satisfied: /1.2 EXP(850/T)1 (1), wherein T is a temperature of a remaining solution in the evaporation separator 70, and is resident time of the remaining solution in the evaporation separator 70.


Inventors:
YOKOYAMA KAZUYUKI
EMOTO HIROKI
Application Number:
JP2007341323A
Publication Date:
August 07, 2008
Filing Date:
December 28, 2007
Export Citation:
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Assignee:
MITSUBISHI CHEM CORP
International Classes:
B01J31/14; C07B61/00; C07C2/26; C07C7/04; C07C11/02; C07C11/107; C08F4/78; C08F6/06
Domestic Patent References:
JPH1045833A1998-02-17
JPH0347138A1991-02-28
JPH09176210A1997-07-08
JPH05201884A1993-08-10
Attorney, Agent or Firm:
Takeshi Senda
Jiro Kobe