Title:
METHOD FOR PREPARATION OF ALCOHOLS
Document Type and Number:
Japanese Patent JP3410120
Kind Code:
B2
Abstract:
PURPOSE: To prepare alcohols by hydrogenating carbonyl compds. at eleveted temp. and superatmospheric pressure in the presence of a particular homogeneous catalyst.
CONSTITUTION: Carbonyl compds. is hydrogeneted at a temp. of 20-200°C, preferably 50-150°C and a total pressure of 1-80 barr in the presence of a homogeneous catalyst having a source of a Group VII metal compd. (preferably palladium, platinum or rhodium) and a phosphine-based bidentate ligand, preferably a compd. of the formula (wherein R1-R4 are each a substitutable hydrocarbon group, or R1 and R2 and/or R3 and R4are taken together to form a substitutable bivalent hydrocarbon group, provided that at least one of R1-R4 is aliphat. group; X is a bivalent-linking group having 2-8C atoms in its cross-linkage), e.g. 1,3-bis(diisopropylphospino)propane to obtain an alcohol. As a starting carbonyl compd., an aldehyde prepd. by hydroformylating reaction of olefinically unsaturated compd. is preferably used.
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Inventors:
Eight Drent
Application Number:
JP25043392A
Publication Date:
May 26, 2003
Filing Date:
August 27, 1992
Export Citation:
Assignee:
SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BESLOTEN VENNOOTSHAP
International Classes:
B01J31/24; B01J27/185; C07B61/00; C07C29/136; C07C29/141; C07C29/145; C07C31/00; C07C31/02; C07C31/10; C07C31/12; C07C31/125; C07C31/135; C07C33/20; C07C45/50; C07C47/02; C07C47/11; C07C47/228; C07C67/31; C07C69/675; (IPC1-7): C07C31/10; B01J31/24; C07C29/141; C07C29/145; C07C31/12; C07C31/125; C07C31/135; C07C33/20; C07C45/50; C07C47/02; C07C47/11; C07C47/228
Domestic Patent References:
| JP63316742A | ||||
| JP63316744A | ||||
| JP2191289A | ||||
| JP390050A | ||||
| JP53105421A | ||||
| JP60243093A | ||||
| JP6419085A | ||||
| JP1216963A | ||||
| JP570412A | ||||
| JP4210696A | ||||
| JP489493A | ||||
| JP5140029A | ||||
| JP4139192A |
Attorney, Agent or Firm:
Kazuho Kawarada