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Title:
METHOD OF PRODUCING SATURATED ALCOHOL BY HYDROGENATION OF ,-UNSATURATED ALCOHOL
Document Type and Number:
Japanese Patent JP2010126448
Kind Code:
A
Abstract:

To provide a method of selectively hydrogenating an unsaturated bond present on the - position alone in a , -unsaturated alcohol, which reaction is extremely important in the pharmaceutical/agrochemical field.

A saturated alcohol is efficiently produced by carrying out the hydrogenation of a , -unsaturated alcohol using an alcohol as a hydrogen source in the presence of a catalyst constituted of supported ruthenium which is formed by dispersing anatase titania in a solution comprising trivalent ruthenium, and subsequently adding a base thereinto to make pH of the solution equal to or higher than 8.


Inventors:
MIZUNO TETSUTAKA
YAMAGUCHI KAZUYA
ARAI NORIHIDE
TSUJI KATSUYUKI
Application Number:
JP2008299709A
Publication Date:
June 10, 2010
Filing Date:
November 25, 2008
Export Citation:
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Assignee:
SHOWA DENKO KK
International Classes:
C07C29/17; B01J23/46; C07C31/12; C07C31/125; C07C31/135; C07C33/025; C07C33/20; C07B61/00
Domestic Patent References:
JPS5724320A1982-02-08
JPS3911356B1
JPS5212106A1977-01-29
JP2000103751A2000-04-11
JPS5291811A1977-08-02
Foreign References:
WO2006034812A22006-04-06
WO2000014041A12000-03-16
WO2004009526A12004-01-29
WO2010032770A12010-03-25
Other References:
JPN6012056487; Chem.Eur.J 14, 2008, 11480-11487
Attorney, Agent or Firm:
Kunihisa Landlord
Atsushi Hayashi