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Title:
オレフィン類のビシナルジオールへの不斉ジヒドロキシル化のためのオスミウム酸塩と交換された新規な層状複水酸化物の製造
Document Type and Number:
Japanese Patent JP4128738
Kind Code:
B2
Abstract:
Layered double hydroxides exchanged with osmate of the formula [MII(1-x)MIIIx(OH)2] [OsO42-]x/2.zH2O wherein MII is a divalent cation selected from the group consisting of Mg2+, Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+ and Ca2+ and MIII is a trivalent ion selected from the group consisting of Al3+, Cr3+, Mn3+, Fe3+ and Co3+, and x is the mole fraction having a value ranging from 0.2 to 0.33, and z is the number of water molecules ranging from 1 to 4, useful as a catalyst, and a process for the preparation thereof and use thereof to manufacture vicinal diols.

Inventors:
Boyapati Manoran Jean Chowderly
Nidue Three Nibasa Chodali
Manne Paris Laxmi Easy
Kondapulum Vijaya Paguhabang
Cinta Lady Benkat Lady
Application Number:
JP2000364561A
Publication Date:
July 30, 2008
Filing Date:
November 30, 2000
Export Citation:
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Assignee:
Council of Scientific and Industrial Research
International Classes:
C01G55/00; B01J23/46; B01J23/89; C01F7/785; C07B53/00; C07B61/00; C07C29/03; C07C29/48; C07C33/26; C07C41/26; C07C43/23; C07C67/31; C07C69/732
Domestic Patent References:
JP3503885A
JP59027840A
JP2000086245A
JP11505861A
Foreign References:
WO2000064844A1
Other References:
Christian DOBLER et al.,Atom-Efficient Oxidation of Alkenes with Molecular Oxygen: Synthesis of Doils,Angewandte Chemie International Edition,1999年10月18日,Vol.38, No.20,pp.3026-3028
Attorney, Agent or Firm:
Takashi Ishida
Jun Tsuruta
Goji Tasaki
Masaya Nishiyama
Higuchi Souji