PURPOSE: To provide a method for producting the rhodium carrying solid catalyst in a small rhodium loss, at a low catalyst production cast and excellent in a high ecosromics in the method by depositing a rhodium complex on a pyridine ring containing insoluble resin.
CONSTITUTION: In the producing method for the solid catalyst made by depositing the rhodium complex on the pyridine ring containing insoluble resin, the method is composed of (I) a process to deposit a rhodium cation on the resin by allowing the rhodium cation to react with the pyridine ring containing insoluble resin in a water solvent and (II) a process to deposit the rhodium complex on the resin by allowing the rhodium cation depositing resin to react with carbon monoxide and an alkyl iodide in an organic solvent.
HAMATO KAZUHIKO
SHIMOKAWA KENJI
MINAMI TAKESHI