Title:
トリクロロシランを用いた不飽和有機化合物の還元体の製造方法、及び還元剤
Document Type and Number:
Japanese Patent JP4594533
Kind Code:
B2
Abstract:
A process of reducing unsaturated organic compounds efficiently by using industrially inexpensive and easily handleable trichlorosilane as the reducing agent to thereby obtain the corresponding reductants; and reducing agents. Specifically, a process for the preparation of reductants of unsaturated organic compounds, characterized by conducting the reduction of an unsaturated organic compound by mixing the compound with trichlorosilane in the presence of a compound capable of reacting with trichlorosilane to give a five-coordinate silicon complex, e.g., N-formylated secondary amine having 3 or more carbon atoms; and reducing agents consisting of specific silicon complexes.
Inventors:
Satoshi Iwasaki
Kenji Tanaka
Matsumura Isao
Onomura Osamu
Kenji Tanaka
Matsumura Isao
Onomura Osamu
Application Number:
JP2000603994A
Publication Date:
December 08, 2010
Filing Date:
March 02, 2000
Export Citation:
Assignee:
Tokuyama Corporation
International Classes:
C07C29/14; B01J31/02; C07B31/00; C07C29/143; C07C31/02; C07C31/133; C07C33/18; C07C35/02; C07C35/21; C07C209/52; C07C211/17; C07C211/27; C07C227/06; C07C229/14; C09K3/00; C07B61/00; C07C211/45; C07C211/52
Foreign References:
| US3280195A | 1966-10-18 | |||
| US3280195A | 1966-10-18 |
Other References:
JPN6010023084, ＰＯＬＥＳＨＣＨＵＫ，Ｏ．Ｋ． ｅｔ ａｌ, "Ｅｌｅｃｔｒｏｎ ｄｅｎｓｉｔｙ ｒｅｄｉｓｔｒｉｂｕｔｉｏｎ ｏｎ ｃｏｍｐｌｅｘａｔｉｏｎ ｉｎ ｎｏｎ−ｔｒａｎｓｉｔｉｏｎ ｅｌｅｍｅｎｔ ｃｏｍｐｌｅｘｅｓ", Ｊｏｕｒｎａｌ ｏｆ Ｍｏｌｅｃｕｌａｒ Ｓｔｒｕｃｔｕｒｅ, 1993, Ｖｏｌ．２９７， Ｎｏ．１−３, ｐ．２９５−３１２
Attorney, Agent or Firm:
Naozumi Ono
Sachiko Okunuki
Sachiko Okunuki