To contain a trapping center with a lower density than before conversion, by depositing an Si3N4 covering with a specific thickness in an STI structure by the low-pressure chemical vapor deposition method, performing speedy heat annealing under specific conditions immediately after depositing the covering, and converting Si3N4 from amorphous to a crystal material.
After a shallow trench is etched, a thin thermal oxide with a thickness of approximately 10nm is grown to eliminate an etching damage. Then, an Si3N4 covering with a thickness of 5-10nm is deposited on the upper surface of an oxide layer in amorphous state at a temperature of 720-780°C in a shallow trench isolation structure(STI). Then, immediately after the covering is deposited, a high-speed heat annealing is executed nearly for 60 seconds at 1,050-1,150°C in pure nitrogen or ammonium and the Si3N4 covering is converted from the amorphous state to the crystal material state of a low- temperature-hexagonal (d) Si3N4 phase.
HAMMERL ERWIN
DOBUZINSKY DAVID M
PALM J HERBERT
FUGARDI STEPHEN
AJMERA ATUL
MOSEMAN JAMES F
RAMAC SAMUEL C
IBM (US)
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